A quantitative reconstruction of organic matter and nutrient diagenesis in Mediterranean Sea sediments over the Holocene

A multicomponent diagenetic model was developed and applied to reconstruct the conditions under which the most recent sapropel, S1, was deposited in the eastern Mediterranean Sea. Simulations demonstrate that bottom waters must have been anoxic and sulphidic during the formation of S1 and that organic matter deposition was approximately three times higher than at present. Nevertheless, most present day sediment and pore water profiles — with the exception of pyrite, iron oxyhydroxides, iron-bound phosphorus and phosphate — can be reproduced under a wide range of redox conditions during formation of S1 by varying the depositional flux of organic carbon. As a result, paleoredox indicators (e.g., C_org:S ratio, C_org:P_org ratio, trace metals) are needed when assessing the contribution of oxygen-depletion and enhanced primary production to the formation of organic-rich layers in the geological record. Furthermore, simulations show that the organic carbon concentration in sediments is a direct proxy for export production under anoxic bottom waters.The model is also used to examine the post-depositional alteration of the organic-rich layer focussing on nitrogen, phosphorus, and organic carbon dynamics. After sapropel formation, remineralisation is dominated by aerobic respiration at a rate that is inversely proportional to the time since bottom waters became oxic once again. A sensitivity analysis was undertaken to identify the most pertinent parameters in regulating the oxidation of sapropels, demonstrating that variations in sedimentation rate, depositional flux of organic carbon during sapropel formation, bottom water oxygen concentration, and porosity have the largest impact. Simulations reveal that sedimentary nutrient cycling was markedly different during the formation of S1, as well as after reoxygenation of bottom waters. Accumulation of organic nitrogen in sediments doubled during sapropel deposition, representing a significant nitrogen sink. Following reventilation of deep waters, N₂ production by denitrification was almost 12 times greater than present day values. Phosphorus cycling also exhibits a strong redox sensitivity. The benthic efflux of phosphate was up to 3.5 times higher during the formation of S1 than at present due to elevated depositional fluxes of organic matter coupled with enhanced remineralisation of organic phosphorus. Reoxygenation of bottom waters leads to a large phosphate pulse to the water column that declines rapidly with time due to rapid oxidation of organic material. The oxidation of pyrite at the redox front forms iron oxyhydroxides that bind phosphorus and, thus, attenuate the benthic phosphate efflux. These results underscore the contrasting effects of oxygen-depletion on sedimentary nitrogen and phosphorus cycling. The simulations also confirm that the current conceptual paradigm of sapropel formation and oxidation is valid and quantitatively coherent.     

Packing states of ideal reservoir sands: Insights from simulation of porosity reduction by grain rearrangement

The question being tackled in this study is to which extent grain rearrangement contributes to porosity reduction in very well sorted quartzose sands (ideal reservoir sands). A numerical model, RAMPAGE (an acronym of random packing generator), has been developed to address this long-standing problem. RAMPAGE represents a synthesis of various algorithms designed to simulate packing of equal-sized spheres, which have been used to represent ideal solids, liquids, and gases, as well as natural porous media. The results of RAMPAGE simulations compare favourably to theoretical and experimental data from various disciplines and allow delineation of the field of gravitationally stable random packing of equal-sized spheres in the 2-D state space of porosity (P) versus mean coordination number (N). Three end-member packing states have been identified: random loose packing (RLP: P = 45.4%, N = 5.2), random close packing (RCP: P = 36.3%, N = 7.0), and bridged random close packing (Bridged RCP: P = 39.5%, N = 5.2). Unlike previously proposed models, RAMPAGE can simulate the transition from RLP to any other point in the stability field. The RLP state is fully consistent with wet-packed porosities of synthetic sands with lognormal mass-size distributions reported in the literature. The much higher in-situ porosity values reported for modern (air-packed) sands are unlikely to be preserved at depth on geological time scales. Data on the relation between intergranular volume and burial depth indicate that the observed intergranular volume reduction in the upper ~ 800 m of the sediment column corresponds to the evolution of RLP to RCP, and is thus fully explained by non-destructive grain rearrangement.     

Effect of ENSO events on sediment production in a large coastal basin in northern Peru

Although the importance of ENSO on hydrological anomalies has been recognized, variations in sediment fluxes caused by these extreme events are poorly documented. The effect of ENSO is not limited to changes in sediment mobilization. Since ENSO events can affect terrestrial ecosystems, they may have important effects on sediment production and transport in river basins over time spans that are longer than the duration of the event itself. The Catamayo‐Chira basin is an interesting casestudy for investigating these geomorphic implications. The objectives were: (i) to study the effect of ENSO on stream flow and sediment yields in the basin, (ii) to investigate if ENSO events affect sediment yields in the post‐ENSO period and (iii) to understand which factors control the ENSO and post‐ENSO basin response. During strong negative ENSO periods, mean annual stream flow discharge at the inlet of the Poechos reservoir in the lower basin was 5.4 times higher than normal annual discharges, while average sediment fluxes exceeded those of normal years by a factor of about 11. In two heavily affected periods, 45.9% of the total sediment yield in the 29 years observation period was generated. Sediment fluxes in the post‐ENSO period are lower than expected, which proves post‐ENSO event dynamics are significantly different from pre‐event dynamics. Our analysis indicates the increase of vegetation growth in the lower basin is not the main reason explaining considerable sediment flux decrease in post‐ENSO periods. During strong ENSO events, sediment in alluvial stores in the lower part of the basin is removed due to enlarging and deepening of channels. In post‐ENSO periods, normal discharges and persisting sediment supplies from the middle/upper basin lead to river aggradation and storage of large amounts of sediment in alluvial plains. The decrease in sediment export will last for several years until the equilibrium is re‐established. Copyright © 2011 John Wiley & Sons, Ltd.     

Antenna data storage concept for phased array radio astronomical instruments

Low frequency Radio Astronomy instruments like LOFAR and SKA-LOW use arrays of dipole antennas for the collection of radio signals from the sky. Due to the large number of antennas involved, the total data rate produced by all the antennas is enormous. Storage of the antenna data is both economically and technologically infeasible using the current state of the art storage technology. Therefore, real-time processing of the antenna voltage data using beam forming and correlation is applied to achieve a data reduction throughout the signal chain. However, most science could equally well be performed using an archive of raw antenna voltage data coming straight from the A/D converters instead of capturing and processing the antenna data in real time over and over again. Trends on storage and computing technology make such an approach feasible on a time scale of approximately 10 years. The benefits of such a system approach are more science output and a higher flexibility with respect to the science operations. In this paper we present a radically new system concept for a radio telescope based on storage of raw antenna data. LOFAR is used as an example for such a future instrument.     

Possible diagenetic mobilization of barium in sapropelic sediment from the eastern Mediterranean

In the last few years it has frequently been suggested that Ba is a useful indicator of paleoproductivity. The formation of some sapropels in the Eastern Mediterranean is considered to be related to, or to coincide with, periods of enhanced productivity. A high-resolution sampling study has been undertaken in order to investigate whether the Ba distribution in sapropels reflects a primary input signal or whether it has been altered by diagenetic processes.

On the basis of our results we suggest that three diagenetic stages determine the distribution of Ba. During deposition of the sapropel (stage 1) Ba is mobilized as anoxic conditions prograde. After deposition of the sapropel (stage 2), a progressive oxidation front develops. This front induces the formation of Mn and Fe enrichments and barite precipitation at the oxic/anoxic boundary. Barite precipitation is believed to be caused mainly by a rise in the porewater sulphate concentration after sulphides have been oxidized by the front.

Upon burial (stage 3), suboxic conditions develop as the oxygen becomes exhausted again. In contrast to Fe- and Mn-oxyhydroxides which dissolve and reprecipitate at higher levels, barite is preserved because dissolved sulphate is not depleted.

The interpretation of the Ba distribution in organic-rich sediment is not straightforward. Diagenetic reallocation of a primary Ba signal will possibly disturb the relationship between Ba and organic production. Consequently, one must be very cautious when invoking Ba as a paleoproductivity indicator.     

Geochemistry of eastern Mediterranean sediments: Primary sediment composition and diagenetic alterations

Two cores recovered in the eastern Mediterranean were analysed for major, minor and trace elements. The primary chemical composition of the sediment is different at each location, probably because the lithological sources and the relative biogenic contributions differ.

Carbonates are important for the concentration of Ca, Mg and Sr, whereas aluminosilicates determine the concentration of Si, Al, K, Li, Y and Be, and to a lesser extent that of Fe, Cr, Ti, Mg, Zn and Zr. In sapropels, organic carbon and sulphur seem to be closely related. Bromine, Mo, P, Fe, V, Cu, Zn, Co, Ni and Cr are closely associated with organic and sulphidic compounds. The concentration versus depth profile for organic carbon in two sapropels points to a rapid establishment of conditions that gave rise to sapropel formation, followed by a gradual transition back to “normal” conditions.

The primary composition is overprinted by diagenetic processes. Sulphate-reducing conditions occurred during and just after sapropel deposition. A progressive oxidation front mechanism, which became active after sapropel deposition, is responsible for additional major geochemical changes. This diagenetic phenomenon has strong implications for the chemistry of Fe, Mn, Ni, Co, Zn, Cu, Cr, V, U, As and Sb.     

Changing hillslope and fluvial Holocene sediment dynamics in a Belgian loess catchment

Floodplain deposition is an essential part of the Holocene sediment dynamics of many catchments and a thorough dating control of these floodplain deposits is therefore essential to understand the driving forces of these sediment dynamics. In this paper we date floodplain and colluvial deposition in the Belgian Dijle catchment using accelerator mass spectrometric radiocarbon and optical stimulated luminescence dating. Relative mass accumulation curves for the Holocene were constructed for three colluvial sites and 12 alluvial sites. A database was constructed of all available radiocarbon ages of the catchment and this database was analysed using relative sediment mass accumulation rates and cumulative probability functions of ages and site‐specific sedimentation curves. Cumulative probability functions of ages were split into different depositional environments representing stable phases and phases of accelerated clastic deposition. The results indicate that there is an important variation between the different dated sites. After an initial stable early and middle Holocene phase with mainly peat growth in the floodplains, clastic sedimentation rates increased from 4000 BC on. This first phase was more pronounced and started somewhat earlier for colluvial deposits then for alluvial deposits. The main part of the Holocene deposits, both in colluvial and alluvial valleys, was deposited during the last 1 ka. The sedimentation pattern of the individual dated sites and the catchment‐wide pattern indicate that land use changes are responsible for the main variations in the Holocene sediment dynamics of this catchment, while the field data do not provide indications for a climatological influence on the sediment dynamics. Copyright © 2011 John Wiley & Sons, Ltd.     

Modelling mean annual sediment yield using a distributed approach

In this paper a spatially distributed model for the calculation of sediment delivery to river channels is presented (SEDEM: SEdiment DElivery Model). The model consists of two components: (1) the calculation of a spatial pattern of mean annual soil erosion rates in the catchment using a RUSLE (Revised Soil Erosion Equation) approach; and (2) the routing of the eroded sediment to the river channel network taking into account the transport capacity of each spatial unit. If the amount of routed sediment exceeds the local transport capacity, sediment deposition occurs. An existing dataset on sediment yield for 24 catchments in central Belgium was used to calibrate the transport capacity parameters of the model. A validation of the model results shows that the sediment yield for small and medium sized catchments (10–5000 ha) can be predicted with an average accuracy of 41 per cent. The predicted sediment yield values with SEDEM are significantly more accurate than the predictions using a lumped regression model. Moreover a spatially distributed approach allows simulation of the effect of different land use scenarios and soil conservation techniques. Copyright © 2001 John Wiley & Sons, Ltd.     

Phase relations of a simplified Marly rock system with application to the Western Hohe Tauern (Austria)

The regional distribution of metamorphic mineral assemblages in Mesozoic carbonate rocks of the Western Hohe Tauern allows the mapping of isograds based on the appearance of biotite+calcite and biotite+zoisite+calcite. The latter isograd corresponds approximately to the thermal maximum of the alpidic metamorphism in the central part of this area. An estimate of P, T, X _fluid conditions can be obtained from phase relations among muscovite, biotite, chlorite, margarite, tremolite, zoisite, anorthite, quartz, calcite, and dolomite in the system K₂O-CaO-MgO-Al₂O₃-SiO₂-H₂O-CO₂ which approximates the composition of marls. Calculations based on various experimental and thermodynamic data have been made with emphasis on phase relations pertinent to a group of carbonate rocks with very low Fe and Na contents in non-opaque minerals. Significant and opposite deviations from the phase relations for stochiometric end member mineral compositions are due to the substitutions F-OH and Mg+Si-2Al. Consistency of observed and calculated phase relations is favoured by high F-contents. For the majority of carbonate rocks in the high metamorphic zone, maximum temperatures around 550° C, minimum pressures of 4–6 kb, and relatively low XCO₂ values within the stability field of zoisite and of biotite+calcite+quartz are indicated.