Supportive elements to the decision-making process in the emergency planning of the Angra dos Reis Nuclear Power Complex,Brazil

Accidents in nuclear power plants are problems of great complexity, mainly due to their consequences, such as the population evacuation from the enterprise influence area. The decision-making and emergency plans must be well articulated and require good local geographic space knowledge and the interactions of their environments. This study is a contribution to the emergency plans for the Almirante Álvaro Alberto Nuclear Power Plant, currently the only nuclear complex in Brazil, located in Angra dos Reis, Rio de Janeiro. The study confirmed the region’s main geoenvironmental aspects as winds and rainfall, landslides and population density were evaluated as important elements in the local emergency process. Their integrated analysis supported scenario identification and critical regional points and highlighted population evacuation escape routes. These important results characterized the support to local emergency management actions and guidelines. Furthermore, the geographic information systems was configured as an integrated spatial and temporal analysis platform to associate meteorological, geological/geomorphological and socio-economic data, playing a key role to support the evacuation planning in the event of nuclear power plant accidents.     

The European Marine Strategy: Contribution and challenges from a Portuguese perspective

The EU Marine Strategy Framework Directive (MSFD) is considered to be the environmental pillar of the EU Integrated Maritime Policy, establishing a framework within which member states must take the necessary measures to achieve, or maintain, good environmental status in their marine waters. This study presents Portugal's contributions to the Directive development, describes the Portuguese institutional framework within the MSFD and, finally, highlights the opportunities and threats to the success of the MSFD implementation in Portugal. The latter entails an analysis of the Directive's long term adequacy in its link to (1) marine spatial planning, (2) climate change and (3) the economic/financial crisis. With one of Europe's largest exclusive economic zones. Portugal's interest in the MSFD is paramount. Efforts towards the approval of the final document were assured during the Portuguese presidency of the European Council of Ministers, in 2007, while chairing a thorough discussion between the Council and the European Parliament. In the Portuguese context, the Directive implementation will rely on the Water Institute as the authoritative entity, which will be responsible for coordinating all necessary efforts at the national level. The success of such process depends on a close cooperation among the institutions involved as well as on how approved measures account for long term issues. In addition, the MSFD implementation must be built on lessons learned within the Water Framework Directive, in order to be successful. Although it poses a methodological challenge to Portugal, the MSFD implementation is expected to contribute significantly to the improvement of coastal/marine conservation and management at the national level.     

Deposition and tectonic setting of the Palaeoproterozoic Castelo dos Sonhos metasedimentary formation,Tapajós Gold Province,Amazonian Craton,Brazil: age and isotopic constraints

The Castelo dos Sonhos Formation (CSF) represents a relic of a sedimentary basin located in the southeastern Tapajós Gold Province (TGP), at its boundary with the Iriri–Xingu Domain (IX), south of the Amazonian Craton. The formation comprises mature, coarse-grained metasandstones (quartz-arenites) intercalated with auriferous metaconglomerates with clasts of quartz and subordinately of banded iron formation, quartzite, schist, and felsic metavolcanic rocks. Lithology, planar, channelled, and large-scale cross-bedding suggest deposition in continental setting by the braided fluvial system associated with alluvial fans and subordinate aeolian dunes. The rocks underwent very low metamorphism and gently synformal folding, and were intruded by andesites and granitoids (2011–1918 Ma). U–Pb LA-ICP-MS zircon data indicate maximum depositional ages of 2050 Ma (metaconglomerate) and 2074, 2088, and 2104 Ma (metasandstones). Hence, deposition occurred at 2050–2011 Ma, slightly preceding or being coeval with the onset of the orogenic phase in TGP (2030–1956 Ma). The quartz-arenite composition, zircon U–Pb data, and negative εHf (?1.3 to ?13.0) and εNd (?2.9 to ?5.3) values indicate: (1) quartzose provenance, (2) prolonged transport and recycling of sedimentary sources, (3) multiple age peaks (2050–3700 Ma), with predominant sources of 2100 and 2750 Ma, and (4) long crustal residence time for the source rocks. Source areas were Rhyacian–Siderian orogenic belts to Mesoarchaean terranes of the Amazonian Craton located to the east, southeast, and northeast of TGP, along with Palaeoarchaean and Eoarchaean detrital zircons recycled from older sedimentary rocks. We interpret CSF as part of a larger foreland system related to the evolution of Rhyacian orogens, currently represented by the Bacajá and Santana do Araguaia domains. The present location of CSF in the easternmost TGP, close to its boundary with IX, is due to rifting (1.89–1.80 Ga) that produced the Uatumã Silicic Large Igneous Province (Uatumã SLIP), and the juxtaposition of the crustal domains is supported by gravity data.     

QuakeIST<Superscript>®</Superscript> earthquake scenario simulator using interdependencies

Earthquakes are a permanent threat to urban environments worldwide. The communication of the related risk demands accurate damage model simulations and an interactive visualization of results. The aim of this paper is to provide a realistic problem-solving environment for earthquake discussions among decision makers, stakeholders, and the general public. QuakeIST^® is an integrated earthquake simulator developed by Instituto Superior Técnico (Lisbon University), oriented towards the performance of risk calculations concerning damage propagations that use the Disruption Index concept. This software imports data stored in a GIS environment, handles different ground motion scenarios, and deals with a complex situation of different soils and vulnerabilities of various layers of civil structures (buildings, lifelines, and other urban structures). It models interdependencies between several infrastructures and between infrastructures and the urban tissue. The computer programme is very versatile, written in separate modules, allowing an experimented user to incorporate new formulations. Results can be treated with any statistical application and most common GIS commercial environments can produced their geographic visualization. Current progress and new upcoming are briefly described at the end of the paper.     

Forest Fire Alert System: a Geo Web GIS prioritization model considering land susceptibility and hotspots – a case study in the Carajás National Forest,Brazilian Amazon

To increase the monitoring potential of forest fires, an alert classification methodology using satellite-mapped hotspots has been established to help forest managers in the prioritization of which hotspot to be verified in the field, thus potentially improving the distribution of fire-fighting resources. A computer application was developed based on web-distributed geographical information technology whose main function is to interact automatically generated satellite hotspots and risk areas indicated in fire-susceptibility maps and classify them into five alert levels. The location of the hotspots is available continuously every 4 h, and a susceptibility map is produced daily through map algebra algorithm, which uses static (topography, vegetation and land use) and dynamic (weather) variables. Every process runs through automated geoprocessing routines. The methodology was tested during the dry period of 2007 in the Carajás National Forest, in the Brazilian Amazon, within an area of 400,000 ha. It is a critical area constantly threatened by fires caused by invasions and deforestation owing to intense agribusiness advances and mining activities in its surroundings. This situation results in observations of many hotspots inside the study area for the same day and almost the same time period, in places of extreme opposites, demanding complex rapid analysis and hindering the decision of the displacement of fire-fighting teams. Further, a major mining company operates within the National Forest area, maintaining actions of protection as part of its environmental mining license. Results are presented under three aspects: (i) the credibility of the daily susceptibility map (algorithm), which showed strong correlation between areas of greatest risks and the confirmed forest fires; (ii) the reliability of hotspots (alert levels), confirming 71% of fires; (iii) accuracy in the decision of which hotspot to be checked, which revealed the same number of verifications at different alert levels, 82% confirmed alert 5 hotspots (maximum) and only 50% from alert 1 (minimum), resulting in faster fire-fighting actions, minimizing burned areas and, in some cases, allowing fire control before its spreading. Therefore, the methodology demonstrated that GIS routines are able to determine the relationship between a reality-based, interpreted susceptibility map of the area and satellite-generated hotspots, highlighting the ones of highest hazard level through the alert classification, becoming an important tool to help decisions from the fire-control center, especially for high-risk regions. The methodology may be extrapolated to other forested areas.     

Geochemistry of granites and metasediments of the urban area of Vila Real (northern Portugal) and correlative radon risk

Radon concentration was evaluated in dwellings of the urban area of Vila Real (Northern Portugal). The area is mainly composed of Hercynian granites and Cambrian metasediments, and CR-39 passive detectors (n = 112) were used for the purpose. The results obtained in winter conditions suggest that the most productive geological unit is the Hercynian granite G1 (geometric mean of 364 Bq/m³), while Cambrian metasediments of the Douro Group show the lowest average indoor radon concentration (236 Bq/m³). The geological, geochemical and radiological data obtained suggest that the most effective control on the radon concentrations of the area is related with the uranium content of the rocks; indeed, the highest contents were observed in granite G1 (21 ppm) and the lowest in the metasediments (3 ppm). This is also confirmed by the results obtained for groundwater, where granites present the highest concentrations of dissolved radon (up to 938 Bq/l), uranium (5–18 ppb) and gross α activities (0.47–0.92 Bq/l). No important radiometric anomalies were found in relation with geological structures such as faults, veins and contacts, but a moderate increase of the uranium content can occur locally in such structures. Petrographic observations and SEM studies show that uranium is mainly contained within the rock in heavy accessory minerals (apatite, zircon, monazite, xenotime), which reduces radon emanation. Notwithstanding, due to the high U contents granites show a significant potential to induce indoor radon concentrations in dwellings in excess of the recommended value of 400 Bq/m³. Overall, we can conclude that the region of Vila Real presents a moderate to high radon risk in dwellings and groundwater.     

Removal of Copper,Nickel and Zinc Ions from Aqueous Solution by Chitosan‐8‐Hydroxyquinoline Beads

In this work, 8‐hydroxyquinoline is used as the active sites in cross‐linked chitosan beads with epichlorohydrin (CT‐8HQ). The CT‐8HQ material was shaped in bead form and used for heavy metal removal from aqueous solution. The study was carried out at pH 5.0 with both batch and column methods and the maximum adsorption capacity of metal ions by the CT‐8HQ was attained in 4 h in the batch experiment. The adsorption capacity order was: Cu²⁺ > Ni²⁺ > Zn²⁺ for both mono‐ and multi‐component systems with batch conditions. From breakthrough curves with column conditions, the adsorption capacity followed the order Cu²⁺ > Zn²⁺ > Ni²⁺ for both mono‐ and multi‐component systems. The CT‐8HQ beads maintained good metal adsorption capacity for all five cycles with absorbent restoration achieved with the use of 1.0 mol L^–1 HCl solution, with 90% regeneration.     

A new multiscale scheme for computing statistical moments in single phase flow in heterogeneous porous media

In this work we develop a new multiscale procedure to compute numerically the statistical moments of the stochastic variables which govern single phase flow in heterogeneous porous media. The technique explores the properties of the log-normally distributed hydraulic conductivity, characterized by power-law or exponential covariances, which shows invariance in its statistical structure upon a simultaneous change of the scale of observation and strength of heterogeneity. We construct a family of equivalent stochastic hydrodynamic variables satisfying the same flow equations at different scales and strengths of heterogeneity or correlation lengths. Within the new procedure the governing equations are solved in a scaled geology and the numerical results are mapped onto the original medium at coarser scales by a straightforward rescaling. The new procedure is implemented numerically within the Monte Carlo algorithm and also in conjunction with the discretization of the low-order effective equations derived from perturbation analysis. Numerical results obtained by the finite element method show the accuracy of the new procedure to approximated the two first moments of the pressure and velocity along with its potential in reducing drastically the computational cost involved in the numerical modeling of both power-law and exponential covariance functions.