Environmental monitoring of magnetic iron phases of urban water reservoir lake sediments (Taiaçupeba Lake,metropolitan region of São Paulo,Brazil) by using Mössbauer spectroscopy

In the present work, we investigate the iron oxides and oxyhydroxides behavior and evolution, related to the geochemical behavior of some metals, which could be retained as solid phases in the sediments from an urban water reservoir lake, placed in Taiaçupeba, Great São Paulo, Brazil. These tasks were performed by the establishment of a proceduring setting for environmental monitoring analysis through Mössbauer spectroscopy measurements associated to hysteresis loops measurements and chemical analysis [X-ray fluorescence (XRF)]. We inferred the possibility of goethite occurrence in broad particle size distribution (5–50 nm), and related to ferrihydrite, and small grain-size hematite (about 8 nm). The magnetometry results pointed to the paramagnetic/superparamagnetic behavior of the magnetic phases present in the samples and also suggested the occurrence of small grain-size magnetite. We also verified the presence of clay minerals related to Fe, as well as the occurrence of Fe³⁺ and/or Fe²⁺ in short-range structural order. Through a straight correlation among Mössbauer spectra data gained at T = 77 K and Al-metal, metal-Fe molar ratios, provided through XRF data, we found remarkable indications of interference on meta-stable phases evolution to its final products. Such results can be pointing for evidences about the possible isomorphic replacing and/or adsorption of Al and other metals in goethite and hematite.     

Metazoan/microbial biostalactites from present‐day submarine caves in the Mediterranean Sea

Biostalactites formed by metazoan–microbialite associations from three submerged marine caves in the Plemmirio Peninsula (south of Syracuse, Ionian Sea) are randomly distributed and show different sizes and morphologies, as well as variations in surface roughness/smoothness. The biostalactites consist of crusts a few centimeters thick of small serpulids and other metazoans, associated with fine‐grained carbonate; the larger ones often include a nucleus of serpulid tubes (Protula). The metazoans include mainly serpuloideans, sponges, bryozoans and foraminifers but microbial carbonates are also significant components. The composition of both the living communities and thanatocoenoses on the outer surfaces, as well as the composition and fabric of the internal framework, were analysed and used to reconstruct the history of the caves. All of the identified sessile faunas mainly consist of cryptic and sciaphilic dwellers that reflect cave conditions and their variations through time. The distribution pattern, composition and abundance of the present‐day dwellers largely depend on the degree of roughness of the biostalactite surfaces and their positions within the caves. It has been suggested that the Protula specimens in the nuclei represent pioneer populations that formed aggregates during the early cave colonization phase, in response to relatively high food supply from seawater inflow and intruding continental waters. By contrast, the outer metazoan–microbialite carbonates reflect more confined conditions in the caves caused by Holocene sea‐level rises. Hypotheses are proposed for biostalactite growth, taking into account information about the growth rates of some constituents, and evidence of dissolution effects. Similarities and differences between these biostalactites and other Holocene deposits previously described from submarine caves in the Mediterranean Sea and in tropical reefs are discussed.     

Evaluation of forecast strategies for seasonal and decadal forecasts in presence of systematic model errors

This study discusses and compares three different strategies used to deal with model error in seasonal and decadal forecasts. The strategies discussed are the so-called full initialisation, anomaly initialisation and flux correction. In the full initialisation the coupled model is initialised to a state close to the real-world attractor and after initialisation the model drifts towards its own attractor, giving rise to model bias. The anomaly initialisation aims to initialise the model close to its own attractor, by initialising only the anomalies. The flux correction strategy aims to keep the model trajectory close to the real-world attractor by adding empirical corrections. These three strategies have been implemented in the ECMWF coupled model, and are evaluated at seasonal and decadal time-scales. The practical implications of the different strategies are also discussed. Results show that full initialisation results in a clear model drift towards a colder climate. The anomaly initialisation is able to reduce the drift, by initialising around the model mean state. However, the erroneous model mean state results in degraded seasonal forecast skill. The best results on the seasonal time-scale are obtained using momentum-flux correction, mainly because it avoids the positive feedback responsible for a strong cold bias in the tropical Pacific. It is likely that these results are model dependent: the coupled model used here shows a strong cold bias in the Central Pacific, resulting from a positive coupled feedback between winds and SST. At decadal time-scales it is difficult to determine whether any of the strategies is superior to the others.     

Decadal interactions between the western tropical Pacific and the North Atlantic Oscillation

The relationship between interdecadal variations of tropical sea surface temperature (SST) in the last 120 years and circulation anomalies related to the North Atlantic Oscillation (NAO) is investigated in this study. Using an atmospheric general circulation model (AGCM), we confirm observational evidence that variations in the SST gradient in the western tropical Pacific are related to the NAO anomalies on decadal timescale, and may be contributing to the shift towards the positive NAO phase observed in the late 20th century. The role played by the Indian Ocean-NAO teleconnection, advocated in recent studies focused on the last 50 years, is also assessed in the context of the 120-year long record. It is suggested that a positive feedback between the Pacific SST and the hemispheric circulation pattern embedding the decadal NAO signal may act to enhance the internal variability of the coupled ocean–atmosphere system, and justify the stronger teleconnection found in observational data than in SST-forced AGCM experiments.

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Strömgren 4-Color Photometry of Very Metal-Poor Stars

Strömgren uvby photometry has been observed for an additional 140 very metal-poor stars from the survey of Beers et al. (1992). These Galactic stars of very-low metallicity provide crucial information for the investigation of the formation and evolution of the Galaxy, as well as on the nature of the early Universe. The Strömgren uvby-β system allows the measurement of stellar atmospheric parameters as a prelude to detailed abundance studies which will make use of high-resolution spectroscopy and the new generation of large telescopes. The photometric techniques developed by Schuster et al. (1996) are used not only to classify these very metal-poor stars but also to derive effective temperatures, surface gravities, and improved estimates for their interstellar reddenings. In particular, photometric diagrams such as [c ₁], [m ₁] and c ₀, (b-y)₀ are used to classify these stars, especially those near the main-sequence turnoff, where contamination from slightly-evolved subgiants, lower surface-gravity horizontal-branch stars, and even a few supergiant or AGB candidates is found.