试论大火成岩省与成矿作用

根据组成大火成岩省的岩浆类型不同,大火成岩省可以分为两类,一是以基性火成岩为主的镁铁质大火成岩省（MLIPs）,二是以酸性火成岩为主的长英质大火成岩省（SLIPs）。它们都是由于在异常高的地幔热流参与下导致地幔或地壳大规模熔融形成的。大火成岩省独特的巨量岩浆活动是引起多层次物质和能量交换的重要场 所。成矿物质的聚集导致成矿作用和矿床的形成是必然的,因此大火成岩省本身就是一个大成矿系统。在这个成矿系统中,由于物源、成分、温度、压力、流体和氧逸度等条件的差异性,形成不同种类的矿化和矿床,并构成一定的成矿系列。镁铁质大火成岩省中形成的矿床类型有岩浆硫化物型Cr-Cu-Ni-PGE矿床和Ti-Fe 氧化物型V-Ti-Fe 矿床,热液型的Cu-Pb-Zn-Au-Ag矿床,以及远程低温热液矿床等。长英质大火成岩省形成的矿床类型为岩浆和交代型、热液型Cu-Pb-Zn-Au-Ag,W-Sn,U-Th-REE矿床,以及Sb-As矿床等。加强对大火成岩省及其成矿机理的研究,有望形成新的成矿理论和加速超大型矿床的发现。     

The Evolution of HII Regions

Here we review some recent results on the observed properties of UCH IIregions, and on the new class of Super-ultra-compact H II regions, and describe the theoretical scheme for H II region expansion, from star-forming cloud cores to the more diffuse external medium. High-pressure cores can stop the expansion on relatively short time scales, of the order of 3× 10⁴ yr, and the resulting pressure equilibrium UCH II regions have small sizes and large ion densities. If the ionization front enters into the decreasing density gradient of the cloud core, the expansion is accelerated and the H II region“pops” out of the core and becomes a “blister”-like region. The properties of the outflows depend on the cloud density structure, and a variety of different shocks can be formed. Density inhomogeneities inside photoionized regions are smoothed out on short time scales, but new clumps are continuously created at the cool shell generated by the shock front. Instabilities in both the ionization and shock fronts cause the fragmentation of the shell, maintaining the presence of clumps during the whole evolution. This revised version was published online in July 2006 with corrections to the Cover Date.     

Three-dimensional VP and VP /VS models of the upper crust in the Friuli area (northeastern Italy)

3-D images of P velocity and P - to S -velocity ratio have been produced for the upper crust of the Friuli area (northeastern Italy) using local earthquake tomography. The data consist of 2565 P and 930 S arrival times of high quality. The best-fitting V _P and V _P / V _S 1-D models were computed before the 3-D inversion. V _P was measured on two rock samples representative of the investigated upper layers of the Friuli crust. The tomographic V _P model was used for modelling the gravity anomalies, by converting the velocity values into densities along three vertical cross-sections. The computed gravity anomalies were optimized with respect to the observed gravity anomalies. The crust investigated is characterized by sharp lateral and deep V _P and V _P / V _S anomalies that are associated with the complex geological structure. High V _P / V _S values are associated with highly fractured zones related to the main faulting pattern. The relocated seismicity is generally associated with sharp variations in the V _P / V _S anomalies. The V _P images show a high-velocity body below 6 km depth in the central part of the Friuli area, marked also by strong V _P / V _S heterogeneities, and this is interpreted as a tectonic wedge. Comparison with the distribution of earthquakes supports the hypothesis that the tectonic wedge controls most of the seismicity and can be considered to be the main seismogenic zone in the Friuli area.     

Biochemical alterations in juvenile carp (Cyprinus carpio) exposed to zinc: glutathione reductase as a target

The aim of this study was to investigate biochemical changes in juvenile carp (Cyprinus carpio) exposed to zinc chloride (10, 30 and 100 microM) for a period of 48 h. Zinc exposure caused a concentration-dependent reduction in glutathione reductase (GR) activity in gills, liver and brain. Gill glutathione S-transferase (GST) was reduced when animals were exposed to the highest concentration of 100 microM zinc. The phosphorylation of p38(MAPK) increased in the brain of fish exposed to zinc 100 microM, while phosphorylation of the extracellular signal-regulated protein kinase 1/2 (ERK1/2) and c-Jun N-terminal protein kinase 1/2 (JNK1/2) remained unchanged. Expression of proteins HSP60 and HSP70 were not affected by zinc exposure. Considering the significant concentration-dependent inhibition of GR in all tissues analyzed, this enzyme could be a potential biomarker of exposure to zinc, which has to be confirmed.     

Coastal and estuarine habitat mapping, using LIDAR height and intensity and multi-spectral imagery

The airborne laser scanning LIDAR (LIght Detection And Ranging) provides high-resolution Digital Terrain Models (DTM) that have been applied recently to the characterization, quantification and monitoring of coastal environments. This study assesses the contribution of LIDAR altimetry and intensity data, topographically-derived features (slope and aspect), and multi-spectral imagery (three visible and a near-infrared band), to map coastal habitats in the Bidasoa estuary and its adjacent coastal area (Basque Country, northern Spain). The performance of high-resolution data sources was individually and jointly tested, with the maximum likelihood algorithm classifier in a rocky shore and a wetland zone; thus, including some of the most extended Cantabrian Sea littoral habitats, within the Bay of Biscay. The results show that reliability of coastal habitat classification was more enhanced with LIDAR-based DTM, compared with the other data sources: slope, aspect, intensity or near-infrared band. The addition of the DTM, to the three visible bands, produced gains of between 10% and 27% in the agreement measures, between the mapped and validation data (i.e. mean producer's and user's accuracy) for the two test sites. Raw LIDAR intensity images are only of limited value here, since they appeared heterogeneous and speckled. However, the enhanced Lee smoothing filter, applied to the LIDAR intensity, improved the overall accuracy measurements of the habitat classification, especially in the wetland zone; here, there were gains up to 7.9% in mean producer's and 11.6% in mean user's accuracy. This suggests that LIDAR can be useful for habitat mapping, when few data sources are available. The synergy between the LIDAR data, with multi-spectral bands, produced high accurate classifications (mean producer's accuracy: 92% for the 16 rocky habitats and 88% for the 11 wetland habitats). Fusion of the data enabled discrimination of intertidal communities, such as Corallina elongata, barnacles (Chthamalus spp.), and stands of Spartina alterniflora and Phragmites australis, which presented misclassification when conventional visible bands were used alone. All of these results were corroborated by the kappa coefficient of agreement. The high classification accuracy found here, selecting data sources, highlights the value of integrating LIDAR data with multi-spectral imagery for habitat mapping in the intertidal complex fringe.     

Prototype measurements and small-scale model tests of wave overtopping at shallow rubble-mound breakwaters: the Ostia-Rome yacht harbour case

The paper presents the comparison between the results of small-scale model tests and prototype measurements of wave overtopping at a rubble-mound breakwater. The specific structure investigated is the west breakwater of the yacht harbour of Rome at Ostia (Italy) and is characterized by a gentle seaward slope (1/4) and by a long, shallow foreshore. The laboratory tests firstly aimed at carefully reproducing two measured storms in which overtopping occurred and was measured. The tests have been carried out in two independent laboratories, in a wave flume and in a wave basin, hence using a two-dimensional (2-D) and a three-dimensional (3-D) setup. In the 2-D laboratory tests no overtopping occurred during the storm reproductions; in the 3-D case discharges five to ten times smaller than those observed in prototype have been measured. This indicates the existence of model and scale effects. These effects have been discussed on the basis of the results of several parametric tests, which have been carried out in both laboratories, in addition to the storm reproductions, varying wave and water level characteristics. Final comparison of all the performed tests with 86 prototype measurements still suggests the existence of scale and model effects that induce strong underestimation of overtopping discharge at small scale. The scale reproduction of wave breaking on the foreshore, together with the 3-D features of the prototype conditions and the absence of wind stress in the laboratory measurements, have been individuated as the main sources of scale and model effects. The paper also provides a comparison between the data and a largely used formula for wave overtopping discharges in the presence of structures similar to the one at hand. The suitable value of a roughness factor that appears in that formula is investigated and good agreement is found with other recent researches on rubble-mound breakwaters.     

The Shanggong gold deposit, Eastern Qinling Orogen, China: Isotope geochemistry and implications for ore genesis

The Shanggong Au deposit in the Xiong’er Terrane, East Qinling, China, has resources of about 30 ton Au, making it one of the largest orogenic-mesothermal Au deposits hosted in volcanic rocks of the Mesoproterozoic Xiong’er Group. Three stages of hydrothermal activity are recognized (early, middle and late), of which two (early and middle) were ore producing and characterized by quartz–pyrite and polymetallic sulfides, respectively. The third and late stage is represented by a carbonate–quartz assemblage. Hydrogen, oxygen and carbon isotope systematics of the Shanggong deposit from a previous work suggest that the early stage fluids were derived from magmatic and/or metamorphic devolatilization of sedimentary rocks at depth. This is supported by new C, S and published Sr and Pb isotopic data, presented in this paper. These new data, δ¹³C values ranging from 1.5 ‰ for early stage ankerite to −2.2 ‰ for late stage ankerite, negative δ³⁴S values for sulfides from the middle stage (–19.2 to –6.3 ‰), suggest a contribution from organic matter and that the ore fluid evolved from deeply sourced to shallowly sourced, with those of the middle stage representing a mixture of these two fluid systems. The comparison of the hydrogen–oxygen–carbon–sulfur–lead–strontium isotope systematics between the Shanggong deposit and the main lithologies in the Xiong’er Terrane, shows that neither these nor the underlying lower crust and mantle, or combinations thereof, could be considered as the source of ore fluids for the Shanggong Au deposit. A likely source was a carbonaceous carbonate, sandstone, shale, chert sequence in the underthrusted Guandaokou and Luanchuan Groups, exposed south of the Xiong’er Terrane.Ar–Ar and Rb–Sr isochron ages for mineral phases of the early, middle and late stages, together with geological field data, constrain the timing of the hydrothermal activity and Au metallogenesis at 242 ± 10, 167 ± 7 and 112 ± 7 Ma, respectively. This metallogenesis and associated granitic magmatism, can be related to the continental collision between the Yangtze and North China Cratons that resulted in the formation of the Qinling Orogen, led to the different hydrothermal systems that were responsible for the three stages that formed the Shanggong Au deposit, over a period of about 130 Myrs.     

Neo-deterministic definition of seismic input for residential seismically isolated buildings

This paper deals with the neo-deterministic definition of the seismic input in the municipality of Nimis (Italy), aimed at the design of residential seismically isolated buildings. The seismic input is defined by the computation of realistic synthetic seismograms considering different levels of detail for the earthquake source, both for a bedrock model and taking into account the specific site conditions. The horizontal response spectrum, calculated in the centre of the municipality by modelling the most dangerous source, advises against the construction of a building with a fixed base, but it is compatible with the seismic isolation, and it has been, therefore, used for the design of a residential seismically isolated building. The maximum displacement for the isolation system has been estimated about 17 cm, a value much lower than that provided by the code design response spectrum (28 cm). The importance of the realistic modelling, which permits the generalization of empirical observations by means of, physically sound, theoretical considerations, is evident, as it allows for the optimisation of the structural design with respect to the site of interest.     

Petrogenesis of Al–silicate-bearing trondhjemitic migmatites from NE Sardinia, Italy

The migmatites from Punta Sirenella (NE Sardinia) are layered rocks containing 3–5 vol.% of centimeter-sized stromatic leucosomes which are mainly trondhjemitic and only rarely granitic in composition. They underwent three deformation phases, from D₁ to D₃. The D₁ deformation shows a top to the NW shear component followed by a top to the NE/SE component along the XZ plane of the S₂ schistosity. Migmatization started early, during the compressional and crustal thickening stage of Variscan orogeny and was still in progress during the following extensional stage of unroofing and exhumation.

The trondhjemitic leucosomes, mainly consisting of quartz, plagioclase, biotite ± garnet ± kyanite ± fibrolite, retrograde muscovite and rare K-feldspar, are locally bordered by millimeter-sized biotite-rich melanosomes. The rare granitic leucosomes differ from trondhjemitic ones only in the increase in modal content of K-feldspar, up to 25%. Partial melting started in the kyanite field at about 700–720 °C and 0.8–0.9 GPa, and was followed by re-equilibration at 650–670 °C and 0.4–0.6 GPa, producing fibrolite–biotite intergrowth and coarse-grained muscovite.

The leucosomes have higher SiO₂, CaO, Na₂O, Sr and lower Al₂O₃, Fe₂O₃, MgO, TiO₂, K₂O, P₂O₅, Rb, Ba, Cr, V, Zr, Nb, Zn and REE content with respect to proximal hosts and pelitic metagreywackes. Sporadic anomalous high content of calcium and ferromagnesian elements in some leucosomes is due to entrainment of significant amounts of restitic plagioclase, biotite and accessory phases. The rare granitic leucosomes reveal peritectic K-feldspar produced by muscovite-dehydration melting. Most leucosomes show low REE content, moderately fractionated REE patterns and marked positive Eu anomaly. Proximal hosts and pelitic metagraywackes are characterized by higher REE content, more fractionated REE patterns and slightly negative Eu anomaly.

The trondhjemitic leucosomes were generated by H₂O-fluxed melting at 700 °C of a greywacke to pelitic–greywacke metasedimentary source-rock. The disequilibrium melting process is the most reliable melting model for Punta Sirenella leucosomes.     

Mineralogy,chemistry, and grain size composition of recent sediments in the northern Tyrrhenian Sea: Contribution to the study of sediment transport and distribution

As a contribution to an environmental study on Tuscany's marine shelf, textural, mineralogical, and chemical characteristics of recent sediments in the northern Tyrrhenian Sea between Elba Island and Livorno have been analyzed. The data provide clear information on sediment sources and movement patterns. The main sediment source appears to be the Cecina River; very subordinate is the contribution of the Fine River. As to sediment movement patterns, the surveyed basin appears to be divided into two subbasins: (1) a greater, southern subbasin, bounded by Tuscany mainland, Elba Island and Elba Ridge, and Capraia Isle, and Vada Shoals; and (2) a smaller, northern subbasin, enclosed between Vada Shoals and Meloria Shoals (off Livorno port).In the former the coarse-grade Cecina River sediments are transported southward along most of the mainland coast by littoral drift and coastal current; a northward flowing countercurrent seems to be active only in the southernmost part. Silts and clays are distributed in concentric belts around basin's central part, being transported mainly by slow circular water movements. In the marginal western zone, very little terrigenous influx is coupled with a high biologic productivity, and biogenic debris sedimentation prevails there.In the northern subbasin the sediment contribution from Fine River is more appreciable. Here the environmental energies are very low and the coarse sediments are restricted to a few small pocket beaches where they are deposited by local creeks. Most of the subbasin area is occupied by sapropelitic muds, again distributed by slow small-scale gyres.