缓变型地球化学灾害:特征、模型和应用

“缓变型地球化学灾害”是通过长期积累而存在于土壤或沉积物中的包括重金属和有机污染物在内的环境污染物,因环境物理化学条件(例如温度、pH值、湿度、有机质含量等)的改变减小了环境容量,某种或某些形态的污染物大量地被重新活化和突然释放出来并造成严重生态和环境损害的灾害现象。这种灾害具有明显的特征,其定量数学模型可较完整地概括出环境系统从“干净”到“污染”再到“灾害”的整个过程,可以用于灾害的风险概率评估、预测、灾害爆发轨迹等方面的研究,为土壤污染防治和灾害预警提供了定量研究工具和可供实际采用的基本手段,对当前国土资源调查中的“生态环境地球化学评价”具有重要的借鉴意义。     

用人工神经网络进行空间不完备数据的插补

在地学研究中,特别是区域性资料处理过程中,常常遇到“不完备数据”的问题,即所谓的“数据不全”。在尽量减小估计误差的条件下对缺失数据进行预测或插补,对于充分利用历史资料和已知信息,提高预测质量具有重要意义。利用径向基人工神经网络(RBF)同时具有自组织神经网络和回归网络的优点,可以对缺失数据进行预测。实际区域地球化学数据处理的结果表明,RBF网络对空间不完备数据的建模和预测具有优异的效果。     

SHORT COMMUNICATION DYNAMIC HEADSPACE ANALYSIS:OPTIMIZATION OF TITRATION BY EXPERIMENTAL DESIGN

The dynamic headspace titration of the volatile constituents of the black truffle(Tuber Melanosporum)isplanned to be carried out with the new gas chromatographic device DCI using Tenax trapping.In thispaper the necessary optimization of the experimental factors which influence the desorption of thevolatiles from the sample and the adsorption on the trap is carried out by experimental design.The studyof the isoresponse curves makes it possible to determine the optimum conditions for a rapid titration ofhighest sensitivity and reproducibility,avoiding water trapping.     

Stable Nitrogen Isotopes in Fish: Literature Synthesis on the Influence of Ecotonal Coupling

Stable nitrogen isotopes have customarily been used to delineate trophic position with only infrequent regard to source variability. A compilation of literature data supports a previous tentative hypothesis that marine fish are enriched in¹⁵N relative to those inhabiting freshwaters. Estuarine and anadromous fish were also confirmed to have intermediate δ¹⁵N values depending on their respective time spent feeding in either fresh- or salt water. The use of fish δ¹⁵N as a measure of continental-marine coupling in complex coastal environments will therefore provide additional support for analyses based on the more traditionally utilized isotopes δ³⁴S or δ¹³C.     

Chemical Indicator of Spinel During Partial Melting and Subsolidus Equilibration of Mantle Peridotite:Experimental Study and Application to Natural Rocks

Systematic experimental studies on partial melting and subsolidus equilibration of three reconstituted spinel-peridotites have been carried out at temperatures ranging from 1000 to 1380℃ and pressures of 1.0 and 1.5 GPa. The results shows (1) during partial melting, Mg# [=Mg/(Mg+Fe)]and Cr# [=Cr/(Cr-Al)]of spinel increase with an increase in degrees of melting) (2) during subsolidus equilibration, with increasing temperatures, Mg# of spinel increases but Cr# of spinel remains almost unchanged in dunite and increases slightly in Iherzolite and harzburgite. The negative and quasi-linear Mg# -Cr# correlation of spinel represents an isotherm of total non-equilibrium. The same results have been obtained by means of mathematical modelling. It is also proved by Mg# -Cr# correlation of spinel in natural peridotites. As a result of the spinel subsolidus equilibration, only variation of Cr# of spinel is limited, and then Cr# of spinel can be used to estimate the relative degree of melting undergone by host rocks     

巢湖北部地区海相地层黏土矿物特征及其地质意义

对巢湖北部地区以碳酸盐岩为主的寒武系—下三叠统海相地层的黏土矿物分析及伊利石结晶度测定的结果表明:伊利石是本区海相地层的主体矿物,平均体积分数为73%。黏土矿物的成岩转化特征表现为蒙皂石的伊利石化。按照伊利石结晶度的成岩-浅变质程度划分,本区寒武系—下三叠统的成岩作用已达到最高成岩阶段。伊利石结晶度的纵向变化总体上可分为上、下两部分:下部寒武系至志留系的结晶度为0.41～0.60°Δ2θ,结晶度与埋深具有一定的相关性,成岩作用是下部地层黏土矿物特征的主控因素;上部泥盆系至下三叠统的结晶度为0.45～0.77°Δ2θ,呈波动变化,蒙皂石连续出现,地层没有被显著埋藏,沉积因素是上部地层黏土矿物特征的主控因素。下三叠统地层中蒙皂石的分布特征以及上泥盆统五通组顶部高岭石的普遍富集具有重要的古气候研究意义。     

First XMM-Newton observations of strongly magnetic cataclysmic variables – I. Spectral studies of DP Leo and WW Hor

We present an analysis of the X-ray spectra of two strongly magnetic cataclysmic variables, DP Leo and WW Hor, made using XMM-Newton . Both systems were in intermediate levels of accretion. Hard optically thin X-ray emission from the shocked accreting gas was detected from both systems, while a soft blackbody X-ray component from the heated surface was detected only in DP Leo. We suggest that the lack of a soft X-ray component in WW Hor is owing to the fact that the accretion area is larger than in previous observations with a resulting lower temperature for the re-processed hard X-rays. Using a multi-temperature model of the post-shock flow, we estimate that the white dwarf in both systems has a mass greater than 1 M_⊙. The implications of this result are discussed. We demonstrate that the 'soft X-ray excess' observed in many magnetic cataclysmic variables can be partially attributed to using an inappropriate model for the hard X-ray emission.