Groundwater metering: revisiting a ubiquitous ‘best practice’

Hydrogeology Journal - It is often taken for granted that metering is an unarguable ‘best practice’ when it comes to the quantitative management of groundwater resources. This paper...     

The effect of cement material properties on the fracture patterns developing within cement-covered brittle sphere under impact

Acta Geotechnica - Dynamic loading experiments of single glass bead cement-covered by epoxy resins of different compositions demonstrate the existence of diverse fracture patterns under similar...     

Evaluation of site conditions for the Ankara Basin of Turkey based on seismic site characterization of near-surface geologic materials

Regional site conditions relevant for seismic hazard studies can be derived from various geologic, seismologic, and geotechnical sources. In this study, site conditions are derived for the Ankara Basin in Turkey by merging in-situ seismic measurements of dynamic properties, geologic information, and some geotechnical boring information. Field seismic refraction surveys were performed at 259 sites in the project area to classify and characterize Plio–Pleistocene fluvial deposits and Quaternary alluvial and terrace deposits. The shear-wave velocity profiles of the near-surface geologic units are used to characterize site classes according to the International Building Code [International Code Council, ICC. International Building Code. Structural and fire- and life-safety provisions (seismic, wind, accessibility, egress, occupancy and roof codes), 2006. Whittier, CA.] and the Turkish Seismic Code [Ministry of Public Works and Settlement, 1998. Turkish Seismic Code, Specification for Structures to be Built in Disaster Areas, Ankara, Turkey], and to develop a regional model for the average shear-wave velocity in the top 30 m. The resulting maps of site class indicate that the classification system for the Turkish Seismic Code results in a significant portion of the Ankara Basin being classified as Z4, the softest site class. The International Building Code site classification system results in most of the Ankara Basin being classified as D, stiff soil. These differences are caused by the Turkish Seismic Code incorporating information from only the surface layer, while the International Building Code incorporates information from the top 30 m.     

Sedimentary archives of the French Atlantic coast (inner Bay of Vilaine,south Brittany): Depositional history and late Holocene climatic and environmental signals

The late Holocene is of particular interest to our understanding of the evolution of coastal sedimentary systems because this period encompasses warmer and cooler periods, and rising sea level in northern Europe. Based on an approach combining AMS ¹⁴C, sedimentological and rock magnetic analyses on sediment cores complemented with seismic data collected in the macrotidal Bay of Vilaine (south Brittany), we document the depositional history of the inner bay coeval to the mid- to late-Holocene transgression in south Brittany. Correlation between sedimentary archives revealed the main sedimentary infilling phases during the last 6000 years. Four units (U1–U4) are recognized in the coastal sediment wedge of the system, corresponding to the stepwise marine invasion of the bay. We show that (1) marine inundation, due to the steep morphology of the bedrock, is diachronous between distal and proximal records. A time lag of ～1000 years is inferred over a distance of less than 5 km; (2) in the outer areas, the sedimentation has been condensed since 3000 years; (3) proximal estuarine archives offer the best record of sedimentary processes covering the last 2000 years, including the Medieval Warm Period (MWP).Correlations in proximal records in the Bay of Vilaine assess the connection between coastal sedimentary dynamics, climatic conditions and anthropogenic activities during the MWP. We match the preservation of clay deposits to increased river-borne suspended matter transported to the estuary probably as a result of accelerated land-use development (higher soil erosion) in the catchment area between ca. 880 and 1050 AD. Because the preservation of estuarine sedimentary successions is favoured when coastal wave sediment reworking is minimal, it is proposed that the prevailing climatic regime in south Brittany during the MWP likely resembled to that of the preferred negative phase of the North Atlantic Oscillation (NAO). Our data are fairly consistent with other late Holocene records from northern Europe including the Atlantic seaboard. However, they outline the difficulty in interpreting climatic and anthropogenic signatures in coastal sedimentary records where high-resolution chronologies required to unravel their respective influences are still missing.     

Parametric analysis of liquid storage tanks base isolated by curved surface sliding bearings

Curved surface sliding bearings, which are usually called as friction pendulum system (FPS) are commonly used for base isolation of liquid storage tanks since the period of the isolation system is independent of the storage level. However the restoring force and the damping at the isolation system are functions of axial load which changes during an earthquake excitation. This change might be in appreciable amounts especially for the tanks with high aspect ratios. The present paper focuses on earthquake performances of both broad and slender tanks base isolated by FPS bearings. The effects of overturning moment and vertical acceleration on axial load variation at the bearings are considered. The efficiency of the isolation system is investigated by analyzing the effects of various parameters such as; (i) isolation period, (ii) tank aspect ratio and (iii) coefficient of friction. The Haroun and Housner's three-degrees-of-freedom lumped mass model was used to solve the governing equations of motion in which convective, impulsive and rigid masses were included. A number of selected ground motions were considered and the results were compared to those of non-isolated cases.As a result, base isolation was found to be effective in reducing the base shear values for both broad and slender tanks without significantly affecting the sloshing displacements of the broad ones. The efficiency was even more pronounced for slender tanks subjected to near fault ground motions for isolation periods above 3 s. This specific value of isolation period also eliminated possible design problems arising from under-estimation of base shear values (up to 40%) due to ignoring the effects of axial load variation in lower isolation periods. Overturning effects should not be ignored especially for tanks with high aspect ratios (S) and being subjected to near fault ground motion.     

Description de deux nouvelles Cyclotelles (Bacillariophyceae) de milieux alcalins et eutrophes:Cyclotella costei nov. sp. etCyclotella wuethrichiana nov. sp.

Two new species of the genus Cyclotella are presented which have been discovered during ecological and paleoecological research studies in the littoral zone of two small alkaline eutrophic lakes in France (Lake Paladru) and in Switzerland (Lake Le Loclat). These new species are namedCyclotella costei nov. sp. andCyclotella wuethrichiana nov. sp.     

Effects of F,B2O3 and P2O5 on the solubility of water in haplogranite melts compared to natural silicate melts

The effects of F, B₂O₃ and P₂O₅ on the H₂O solubility in a haplogranite liquid (36 wt. % SiO₂, 39 wt. % NaAlSi₃O₈, 25 wt. % KAlSi₃O₈) have been determined at 0.5, 1, 2, and 3 kb and 800, 850, and 900°C. The H₂O solubility increases with increasing F and B content of the melt. The H₂O solubility increase in more important at high pressure (2 and 3 kb) than at low pressure (0.5 kb). At 2 kb and 800°C, the H₂O solubility increases from 5.94 to 8.22 wt. % H₂O with increasing F content in the melt from 0 to 4.55 wt. %, corresponding to a linear H₂O solubility increase of 0.53 mol H₂O/mol F. With addition of 4.35 wt. % B₂O₃, the H₂O solubility increases up to 6.86 wt. % H₂O at 2 kb and 800°C, corresponding to a linear increase of 1.05 mol H₂O/mol B₂O₃. The results allow to define the individual effects of fluorine and boron on H₂O solubility in haplogranitic melts with compositions close to that of H₂O-saturated thermal minima (at 0.5–3 kb). Although P has a dramatic effect on the phase relations in the haplogranite system, its effect on the H₂O solubility was found to be negligible in natural melt compositions. The concominant increase in H₂O solubility and F can not be interpreted on the basis of the available spectroscopic data (existence of hydrated aluminofluoride complexes or not). In contrast, hydrated borates or more probably boroxol complexes have been demonstrated in B-bearing hydrous melts.     

3D chemical model for geological macromolecules

This study defines a chemical representation of the kerogen macromolecule based on data from physicochemical analyses. The model should permit: creation of various schematic drawings representing an average macromolecule; future integration of new analytical results (for instance on structures of biomarkers or biopolymers); and determination of the distribution of chemical bonds.The models developed in this study can be represented in a 3D space, using classical chemical symbols, in the form of cyclic groups linked to each other by aliphatic chains. One cyclic group is a connected set of aromatic, naphthenoaromatic or naphthenic rings. These cyclic groups are constructed using basic elements such as atoms and bonds defined by their length and direction.Modeling of kerogen is done in three successive steps. A library is first created to define atoms, bonds and cyclic groups. Secondly, starting from a set of equations describing the analytical results, cyclic and aliphatic groups are chosen in the appropriate stoechiometric amount to match the analytical data. Finally the construction is done: cyclic groups are placed randomly in a 3D space, connections are made by aliphatic chains, and functional groups are added.The molecular modeling software Xmol^TM can be operated on APOLLO stations. It allows the creation of libraries, the calculation of chemical bonds corresponding to the analyses and the construction of macromolecules. An example is given for a type III kerogen at the beginning of diagenesis.     

Volatile fluxes from volcanoes

Volatile fluxes from Mid Ocean Ridge (MOR) and subaerial volcanism have been estimated or re-evaluated using several natural tracers-³He, ²¹⁰Po, SO₂-and chemical ratios of volatile species in lavas and volcanic gases.
These estimates confirm the net predominance of anthropogenic fluxes over volcanic fluxes for CO₂, SO₂ and trace metals.
They also suggest that, while most of the volatiles transferred during MOR volcanism come from the mantle, volatiles stored at the surface of the Earth supply an appreciable fraction of subaerial fluxes and can be the dominant source for some of them.
The surface inventory of volatile species cannot result from steady-state degassing with constant rate and needs much greater fluxes in the past or other volatile supply processes. This inventory is the result of several of the following processes: capture of the solar nebula and its subsequent partial escape, impact degassing of accreting bodies, and, from Archean to present mantle, degasssing through volcanism and associated phenomena, with recycling into the mantle through subduction.