Tidal evolution of hierarchical and inclined systems

We investigate the dynamical evolution of hierarchical three-body systems under the effect of tides, when the ratio of the orbital semi-major axes is small and the mutual inclination is relatively large (greater than 20°). Using the quadrupolar non-restricted approximation for the gravitational interactions and the viscous linear model for tides, we derive the averaged equations of motion in a vectorial formalism which is suitable to model the long-term evolution of a large variety of exoplanetary systems in very eccentric and inclined orbits. In particular, it can be used to derive constraints for stellar spin-orbit misalignment, capture in Cassini states, tidal-Kozai migration, or damping of the mutual inclination. Because our model is valid for the non-restricted problem, it can be used to study systems of identical mass or for the outer restricted problem, such as the evolution of a planet around a binary of stars. Here, we apply our model to various situations in the HD 11964, HD 80606, and HD 98800 systems.     

Experimental constraints on ultrapotassic magmatism from the Bohemian Massif (durbachite series, Czech Republic)

The equilibrium phase relations of a mafic durbachite (53 wt.% SiO₂) from the Třebíč pluton, representative of the Variscan ultrapotassic magmatism of the Bohemian Massif (338–335 Ma), have been determined as a function of temperature (900–1,100°C), pressure (100–200 MPa), and H₂O activity (1.1–6.1 wt.% H₂O in the melt). Two oxygen fugacity ranges were investigated: close to the Ni–NiO (NNO) buffer and 2.6 log unit above NNO buffer (∆NNO + 2.6). At 1,100°C, olivine is the liquidus phase and co-crystallized with phlogopite and augite at 1,000°C for the whole range of investigated pressure and water content in the melt. At 900°C, the mineral assemblage consists of augite and phlogopite, whereas olivine is not stable. The stability field of both alkali feldspar and plagioclase is restricted to low pressure (100 MPa) at nearly water-saturated conditions (<3–4 wt.% H₂O) and T < 900°C. A comparison between experimental products and natural minerals indicates that mafic durbachites have a near-liquidus assemblage of olivine, augite, Ti-rich phlogopite, apatite and zircon, followed by alkali feldspar and plagioclase, similar to the mineral assemblage of minette magma. Natural amphibole, diopside and orthopyroxene were not reproduced experimentally and probably result from sub-solidus reactions, whereas biotite re-equilibrated at low temperature. The crystallization sequence olivine followed by phlogopite and augite reproduces the sequence inferred in many mica-lamprophyre rocks. The similar fractionation trends observed for durbachites and minettes indicate that mafic durbachites are probably the plutonic equivalents of minettes and that K- and Mg-rich magmas in the Bohemian Massif may have been generated from partial melting of a phlogopite–clinopyroxene-bearing metasomatized peridotite. Experimental melt compositions also suggest that felsic durbachites can be generated by simple fractionation of a more mafic parent and mixing with mantle-derived components at mid crustal pressures.     

Mineralogy and major-trace element geochemistry of the Haymana manganese mineralizations,Ankara, Turkey

The study area comprises Çayirli, Harapa?illari and Ortabel (ÇHO) districts in the Haymana town 25 km SW of the Ankara city. In this study, geologic setting, mineralogical and geochemical characteristics of manganese mineralizations are examined and their origin is discussed. Data were obtained from field observations, various polished and thin section determinations and chemical analyses of 25 ore samples. Major and trace element analyses were conducted with ICP-ES and ICP-MS methods at ACME Laboratories (Canada). ÇHO manganese ores are found in reddish radiolarites and partly interbedded marls of the Ankara ophiolitic melange of lower Cretaceous-upper Senonian age. In these extremely folded rocks, manganese is observed as band and lenses. All samples are composed of pyrolusite and quartz. Circular pyrolusites around the gangue form a ring texture and radiolarite ores yield spherical sections. In addition, breccia-like texture is observed between pyrolusite and quartz. Geologic setting, mineralogical and textural data indicate an exogene environment. Major and trace element abundances and correlation among them imply that ÇHO mineralizations are of hydrothermal origin and linked to the same source. Evaluation of all these data shows that ÇHO manganese mineralizations are of hydrothermal type sedimentary mineralization and they were deposited in distal part of the source.     

Mg isotope constraints on soil pore-fluid chemistry: Evidence from Santa Cruz, California

Mg isotope ratios (²⁶Mg/²⁴Mg) are reported in soil pore-fluids, rain and seawater, grass and smectite from a 90 kyr old soil, developed on an uplifted marine terrace from Santa Cruz, California. Rain water has an invariant ²⁶Mg/²⁴Mg ratio (expressed as δ²⁶Mg) at −0.79 ± 0.05‰, identical to seawater δ²⁶Mg. Detrital smectite (from the base of the soil profile, and therefore unweathered) has a δ²⁶Mg value of 0.11‰, potentially enriched in ²⁶Mg by up to 0.3‰ compared to the bulk silicate Earth Mg isotope composition (although within the range of all terrestrial silicates). The soil pore-waters show a continuous profile with depth for δ²⁶Mg, ranging from −0.99‰ near the surface to −0.43‰ at the base of the profile. Shallow pore-waters (<1 m) have δ²⁶Mg values that are similar to, or slightly lower than the rain waters. This implies that the degree of biological cycling of Mg in the pore-waters is relatively small and is quantified as <32%, calculated using the average Mg isotope enrichment factor between grass and rain (δ²⁶Mg_grass-δ²⁶Mg_rain) of 0.21‰. The deep pore-waters (1-15 m deep) have δ²⁶Mg values that are intermediate between the smectite and rain, ranging from −0.76‰ to −0.43‰, and show a similar trend with depth compared to Sr isotope ratios. The similarity between Sr and Mg isotope ratios confirms that the Mg in the pore-waters can be explained by a mixture between rain and smectite derived Mg, despite the fact that Mg and Sr concentrations may be buffered by the exchangeable reservoir. However, whilst Sr isotope ratios in the pore-waters span almost the complete range between mineral and rain inputs, Mg isotopes compositions are much closer to the rain inputs. If Mg and Sr isotope ratios are controlled uniquely by a mixture, the data can be used to estimate the mineral weathering inputs to the pore-waters, by correcting for the rain inputs. This isotopic correction is compared to the commonly used chloride correction for precipitation inputs. A consistent interpretation is only possible if Mg isotope ratios are fractionated either by the precipitation of a secondary Mg bearing phase, not detected by conventional methods, or selective leaching of ²⁴Mg from smectite. There is therefore dual control on the Mg isotopic composition of the pore-waters, mixing of two inputs with distinct isotopic compositions, modified by fractionation. The data provide (1) further evidence for Mg isotope fractionation at the surface of the Earth and (2) the first field evidence of Mg isotope fractionation during uptake by natural plants. The coherent behaviour of Mg isotope ratios in soil environments is encouraging for the development of Mg isotope ratios as a quantitative tracer of both weathering inputs of Mg to waters, and the physicochemical processes that cycle Mg, a major cation linked to the carbon cycle, during continental weathering.     

Field evidences of secondary surface ruptures occurred during the 20 February 1956 Eskişehir earthquake in the NW Anatolia

Surface rupture and source fault of the 20 February 1956 Eskişehir earthquake have been a matter of debate that potentially contributes towards the understanding of the active deformation and seismic risk in the highly populated NW Anatolia. Field observations on the two fault segments (namely Kavacık and Uludere faults) in the north of the Eskişehir graben revealed evidences of co-seismic surface rupture and mass movements during the Eskişehir earthquake. Surface rupture was observed as a 2.5m wide, a 100m long and ca. 20 cm deep asymmetric depression in the Gümüşlü valley, 2 km east of the Uludere village. A trench dug on this depression confirms a prominent high-angle south dipping fault (dominantly left lateral strike slip) and two faint north-dipping antithetics as clear noticeable shear zones in organic-rich thick soil. Mass failures are particularly observed in spring depressions filled with loose torrent and carbonaceous material in front of the fault scarp. Some rock slides of several tens of meters in size that obviously require significantly high ground shaking were also developed on steep fault scarps. The orientation of the principal stress tensor as deduced from the surface rupture of the Eskişehir earthquake displays clear inconsistency with the geometry of prominent faults in the area. We concluded that this disagreement may be explained by a curved surface rupture. The western and eastern tips of this rupture are EW trending and the probable NW-running part in the middle would correspond to the bounding zone between two right-stepping faults.     

Developing the ability to model acid-rock interactions and mineral dissolution during the RMA stimulation test performed at the Soultz-sous-Forêts EGS site,France

The Soultz Enhanced Geothermal System (EGS) reservoir's response to chemical stimulation is assessed by numerical simulation of coupled thermo-hydraulic-chemical processes. To assess chemical interactions between host rocks and a mixture of HCl and HF as well as its potential effects on the Soultz EGS reservoir, new modelling efforts using the FRACHEM code have been initiated. This article presents the model calibration and results. Simulations consider realistic conditions with available data sets from the EGS system at Soultz. Results indicate that the predicted amount of fracture sealing minerals dissolved by injection of a mixture of acids Regular Mud Acid (RMA) was consistent with the estimated amount from the test performed on GPK4 well at Soultz EGS site. Consequently reservoir porosity and permeability can be enhanced especially near the injection well by acidizing treatment.     

Evaluating the fitness for use of spatial data sets to promote quality in ecological assessment and monitoring

This article proposes and illustrates a practical methodological framework to evaluate the fitness for use of spatial data sets for environmental and ecological applications, focusing on user requirements for specified application contexts. The methodology is based on the use of metadata to analyze similarity between the data characteristics and the user’s needs or expectations for several quality indicators. Additionally, the concept of ‘critical factors’ is introduced in this framework, allowing users to define which quality indicators have greater importance given their own requirements or expectations and the specified application contexts. The proposed methodology further allows integrating and interconnecting the spatial data quality (SDQ) evaluation methodology with metadata geoportals in WebGIS platforms, facilitating its operation by users from non-spatial disciplines and with often limited expertise on this subject. Examples of the evaluation of fitness for use for specific application contexts within the project BIO_SOS (‘Biodiversity Multi-SOurce Monitoring System: From Space To Species’ FP7 project) are presented. By providing a prompt and straightforward evaluation tool, the proposed methodology can encourage the implementation of SDQ evaluation routines in ecological assessment and monitoring programs, promoting a more adequate use of geospatial data and ultimately contributing to well-supported policy and management decisions.     

Seasonal to yearly assessment of temperature and precipitation trends in the North Western Mediterranean Basin by dynamical downscaling of climate scenarios at high resolution (1971–2050)

The complex topography and high climatic variability of the North Western Mediterranean Basin (NWMB) require a detailed assessment of climate change projections at high resolution. ECHAM5/MPIOM global climate projections for mid-21st century and three different emission scenarios are downscaled at 10 km resolution over the NWMB, using the WRF-ARW regional model. High resolution improves the spatial distribution of temperature and precipitation climatologies, with Pearson's correlation against observation being higher for WRF-ARW (0.98 for temperature and 0.81 for precipitation) when compared to the ERA40 reanalysis (0.69 and 0.53, respectively). However, downscaled results slightly underestimate mean temperature (≈1.3 K) and overestimate the precipitation field (≈400 mm/year). Temperature is expected to raise in the NWMB in all considered scenarios (up to 1.4 K for the annual mean), and particularly during summertime and at high altitude areas. Annual mean precipitation is likely to decrease (around ?5 % to ?13 % for the most extreme scenarios). The climate signal for seasonal precipitation is not so clear, as it is highly influenced by the driving GCM simulation. All scenarios suggest statistically significant decreases of precipitation for mountain ranges in winter and autumn. High resolution simulations of regional climate are potentially useful to decision makers. Nevertheless, uncertainties related to seasonal precipitation projections still persist and have to be addressed.     

Basement lithostratigraphy of the Adula nappe: implications for Palaeozoic evolution and Alpine kinematics

The Adula nappe belongs to the Lower Penninic domain of the Central Swiss Alps. It consists mostly of pre-Triassic basement lithologies occurring as strongly folded and sheared gneisses of various types with mafic boudins. We propose a new lithostratigraphy for the northern Adula nappe basement that is supported by detailed field investigations, U–Pb zircon geochronology, and whole-rock geochemistry. The following units have been identified: Cambrian clastic metasediments with abundant carbonate lenses and minor bimodal magmatism (Salahorn Formation); Ordovician metapelites associated with amphibolite boudins with abundant eclogite relicts representing oceanic metabasalts (Trescolmen Formation); Ordovician peraluminous metagranites of calc-alkaline affinity ascribed to subduction-related magmatism (Garenstock Augengneiss); Ordovician metamorphic volcanic–sedimentary deposits (Heinisch Stafel Formation); Early Permian post-collisional granites recording only Alpine orogenic events (Zervreila orthogneiss). All basement lithologies except the Permian granites record a Variscan + Alpine polyorogenic metamorphic history. They document a complex Paleozoic geotectonic evolution consistent with the broader picture given by the pre-Mesozoic basement framework in the Alps. The internal consistency of the Adula basement lithologies and the stratigraphic coherence of the overlying Triassic sediments suggest that most tectonic contacts within the Adula nappe are pre-Alpine in age. Consequently, mélange models for the Tertiary emplacement of the Adula nappe are not consistent and must be rejected. The present-day structural complexity of the Adula nappe is the result of the intense Alpine ductile deformation of a pre-structured entity.