Concentration and subcellular distribution of trace elements in liver of small cetaceans incidentally caught along the Brazilian coast

Concentrations of trace elements (V, Cr, Mn, Fe, Co, Cu, Zn, Ga, As, Se, Rb, Sr, Mo, Ag, Cd, Sb, Cs, Ba, T-Hg, Org-Hg, Tl and Pb) were determined in liver samples of estuarine dolphin (Sotalia guianensis; n = 20), Franciscana dolphin (Pontoporia blainvillei; n = 23), Atlantic spotted dolphin (Stenella frontalis; n = 2), common dolphin (Delphinus capensis; n = 1) and striped dolphin (Stenella coeruleoalba; n = 1) incidentally caught along the coast of Sao Paulo State and Parana State, Brazil, from 1997 to 1999. The hepatic concentrations of trace elements in the Brazilian cetaceans were comparable to the data available in literature on marine mammals from Northern Hemisphere. Concentrations of V, Se, Mo, Cd, T-Hg and Org-Hg increased with increasing age in liver of both estuarine and Franciscana dolphins. Very high concentrations of Cu (range, 262-1970 microg/g dry wt.) and Zn (range, 242-369 microg/g dry wt.) were observed in liver of sucklings of estuarine dolphin. Hepatic concentrations of V, Se, T-Hg, Org-Hg and Pb were significantly higher in estuarine dolphin, whereas Franciscana dolphin showed higher concentrations of Mn, Co, As and Rb. Ratio of Org-Hg to T-Hg in liver was significantly higher in Franciscana dolphin than estuarine dolphin, suggesting that demethylation ability of methyl Hg might be lower in liver of Franciscana than estuarine dolphins. High hepatic concentrations of Ag were found in some specimens of Franciscana dolphin (maximum, 20 microg/g dry wt.), and 17% of Franciscana showed higher concentrations of Ag than Hg. These samples with high Ag concentration also exhibited elevated hepatic Se concentration, implying that Ag might be detoxified by Se in the liver. Higher correlation coefficient between (Hg+0.5 Ag) and Se than between Hg and Se and the large distribution of Ag in non-soluble fraction in nuclear and mitochondrial fraction of the liver also suggests that Ag might be detoxified by Se via formation of Ag2Se in the liver of Franciscana dolphin.     

Calibration of Local Magnitude M<Subscript>L</Subscript> in the Azores Archipelago Based on Recent Digital Recordings

—The development of the digital seismic network in the Azores Archipelago during recent years made it possible to obtain the amplitudes (waveform) of recorded motion in a large set of stations. With this new data, maximum amplitudes of the Wood Anderson seismograph are computed, for each station/component, which, together with epicentral distances, allows for the estimation of local magnitude M _L . We used data recorded in 8 digital permanent three-component stations, with inter-stations distances up to 300 km, in the period June 1998 – June 2000, corresponding to a set of 1315 events with magnitude (M _L or M _D ) 2<M<5.8 and epicenters located in the Azores region, to estimate the coefficients of the equation to compute M _L , as well as to determine the corrections to be applied to each station. The new set of parameters, formed by attenuation coefficients and station corrections, were introduced in the calculations of the M _L , leading to smaller dispersions in the analyzed dataset. We also conclude that the attenuation in the first 150 km is similar to the California values, although higher for longer distances.     

Characteristics of chaotic pulse trains generated by lightning flashes

Pulse trains of irregular pulse characteristics and erratic amplitudes are observed in lightning flashes. These are termed “chaotic pulse trains” in this study. The average width of the individual pulses of these pulse trains is in the range of a few microseconds, with the lower limit of individual measurements extending into the sub-microsecond region. The typical pulse separation lies in the range of 2–. The pulse duration shows a consistent distribution with the most probable value at 400–. Chaotic pulse trains occur most often immediately prior to subsequent strokes. However, they occur also a few milliseconds to several tens of milliseconds prior to return strokes and sometimes do not precede return strokes at all. Twenty-six percent of the total subsequent strokes recorded in this study were preceded by chaotic pulse trains. A few of these pulse trains have occurred in a sequence of several tens of millisecond intervals in between return strokes. We have also found them to occur within very intense cloud flashes. These chaotic pulse trains have features that are different from those of other known pulse trains reported in the lightning literature. Hence, they may be caused by a physical process that has not yet been identified.     

Geological and SHRIMP II U-Pb constraints on the age and origin of the Breves Cu-Au-(W-Bi-Sn) deposit,Carajás,Brazil

The Breves deposit in the Carajás Copper-Gold Belt, Brazil, a member of the Cu-Au-(W-Bi-Sn) group of deposits, contains about 50 Mt of 1.22% Cu, 0.75 g/t Au, 2.4 g/t Ag, 1,200 g/t W, 70 g/t Sn, 175 g/t Mo and 75 g/t Bi. It is hosted by sandstones and siltstones of the Águas Claras Formation (minimum age of 2,681±5 Ma) in the roof zone of a complex, highly altered granite intrusion. The mineralisation is disseminated in a greisenized zone, resulting from alteration of probable monzogranites and syenogranites. The ore-bearing greisen contains abundant xenomorphic quartz in association with Fe-chlorite and muscovite. The gangue assemblage also includes fluorite, tourmaline, and minor amounts of monazite, xenotime, chlorapatite, thorite, zircon, calcite, siderite and bastnäesite. Copper mineralisation is dominated by chalcopyrite associated with pyrite, arsenopyrite, pyrrhotite and molybdenite. Gold particles, in equilibrium with native bismuth, are common as inclusions in chalcopyrite. The greisen contains sub-economic concentrations of tungsten and niobium that are related to the presence of ferberite, qitianlingite and Nb-rutile. SHRIMP II zircon dating of the host granites gives ²⁰⁷Pb/²⁰⁶Pb ages of 1,878±8 and 1,880±9 Ma for two phases, and a combined age of 1,879±6 Ma. SHRIMP II dating of monazite and xenotime grains in late- to post-mineralisation veins gives a combined ²⁰⁷Pb/²⁰⁶Pb age of 1,872±7 Ma, indistinguishable from the ages of the granites. This provides a genetic connection between the Breves deposit and the ca. 1.88 Ga A-type granite magmatism that typifies the Carajás Belt as part of a much larger, intracratonic magmatic province that extends over much of the Amazonian Craton. The recognition of this association has exploration implications, not only for the geophysical signature of the granite roof zones, but also for likely geochemical dispersion around the deposits of this type.Editorial handling: G. Beaudoin     

Effects of the number of stations and time resolution on derivation

For at least 30 years now it has been well known that the Dst index can be modelled using the solar wind as input. Since then, many attempts have been made to improve the predictability of Dst using different approaches. These attempts are useful, for instance, to understand which features of the solar wind–magnetosphere interactions are most important in producing magnetospheric activity and how the Dst index would improve the space weather forecast. The Dst index is by far the most reliable and simple indication that a magnetic storm is in progress. In this work, the effect of using more than four magnetic stations and shorter time intervals than the hourly averages used in Sugiura's procedures is evaluated. The discussion is based on the results presented by Burton in 1975 and Feldstein in 1984 considering 4 or 12 magnetic stations and time averages of 2.5 min for a magnetic disturbed period that occurred from February 7–28, 1967, including two geomagnetic storms. The analysis has shown that the global representation of a magnetic storm by the standard Dst (Sugiura) is well preserved either using 4, 6, 12 magnetic stations or using 1 h, 2.5 min 1 min averages. A brief review of the current understanding of Dst has been included to support the discussions. The analysis performed has shown that a more refined Dst index (time and number of stations>4) would be useful to investigate the intrinsic processes and the different current systems involved in the ring current development during magnetic storms; the standard Dst, as it is conceived, is quite adequate to monitor geomagnetic storms and identify their overall features; concerning the magnetic stations normally considered, the inclusion of higher magnetic latitude stations (>35) may underestimate the observed Dst.     

The crystal chemistry of lithium and Fe3+ in synthetic orthopyroxene

Lithian ferrian enstatite with Li₂O = 1.39 wt% and Fe₂O₃ 7.54 wt% was synthesised in the (MgO–Li₂O–FeO–SiO₂–H₂O) system at P = 0.3 GPa, T = 1,000°C, fO₂ = +2 Pbca, and a = 18.2113(7), b = 8.8172(3), c = 5.2050(2) Å, V = 835.79(9) Å³. The composition of the orthopyroxene was determined combining EMP, LA-ICP-MS and single-crystal XRD analysis, yielding the unit formula ^M2(Mg_0.59Fe _0.21 ²⁺ Li_0.20) ^M1(Mg_0.74Fe _0.20 ³⁺ Fe _0.06 ²⁺ ) Si₂O₆. Structure refinements done on crystals obtained from synthesis runs with variable Mg-content show that the orthopyroxene is virtually constant in composition and hence in structure, whereas coexisting clinopyroxenes occurring both as individual grains or thin rims around the orthopyroxene crystals have variable amounts of Li, Fe³⁺ and Mg contents. Structure refinement shows that Li is ordered at the M2 site and Fe³⁺ is ordered at the M1 site of the orthopyroxene, whereas Mg (and Fe²⁺) distributes over both octahedral sites. The main geometrical variations observed for Li-rich samples are actually due to the presence of Fe³⁺, which affects significantly the geometry of the M1 site; changes in the geometry of the M2 site due to the lower coordination of Li are likely to affect both the degree and the kinetics of the non-convergent Fe²⁺-Mg ordering process in octahedral sites.     

Real-time cycle slip detection in triple-frequency GNSS

The modernization of the global positioning system and the advent of the European project Galileo will lead to a multifrequency global navigation satellite system (GNSS). The presence of new frequencies introduces more degrees of freedom in the GNSS data combination. We define linear combinations of GNSS observations with the aim to detect and correct cycle slips in real time. In particular, the detection is based on five geometry-free linear combinations used in three cascading steps. Most of the jumps are detected in the first step using three minimum-noise combinations of phase and code observations. The remaining jumps with very small amplitude are detected in the other two steps by means of two-tailored linear combinations of phase observations. Once the epoch of the slip has been detected, its amplitude is estimated using other linear combinations of phase observations. These combinations are defined with the aim of discriminating between the possible combinations of jump amplitudes in the three carriers. The method has been tested on simulated data and 1-second triple-frequency undifferenced GPS data coming from a friendly multipath environment. Results show that the proposed method is able to detect and repair all combinations of cycle slips in the three carriers.     

Future regional projections of extreme temperatures in Europe: a nonstationary seasonal approach

This paper analyzes changes of maximum temperatures in Europe, which are evaluated using two state-of-the-art regional climate models from the EU ENSEMBLES project. Extremes are expressed in terms of return values using a time-dependent generalized extreme value (GEV) model fitted to monthly maxima. Unlike the standard GEV method, this approach allows analyzing return periods at different time scales (monthly, seasonal, annual, etc). The study focuses on the end of the 20th century (1961?C2000), used as a calibration/validation period, and assesses the changes projected for the period 2061?C2100 considering the A1B emission scenario. The performance of the regional models is evaluated for each season of the calibration period against the high-resolution gridded E-OBS dataset, showing a similar South-North gradient with larger values over the Mediterranean basin. The inter-RCM changes in the bias pattern with respect to the E-OBS are larger than the bias resulting from a change in the boundary conditions from ERA-40 to ECHAM5 20c3m. The maximum temperature response to increased green house gases, as projected by the A1B scenario, is consistent for both RCMs. Under that scenario, results indicate that the increments for extremes (e.g. 40-year return values) will be two or three times higher than those for the mean seasonal temperatures, particularly during Spring and Summer in Southern Europe.     

Coral reef ecosystems protect shore from high-energy waves under climate change scenarios

Coral reefs and other coastal ecosystems such as seagrasses and mangroves are widely recognized to provide protection against the devastating effects of strong waves associated with tsunamis and storms. The predicted warming climate brings to fore the role of these ecosystems in providing protection against stronger typhoons that can result in more devastating waves of greater amplitude. We performed a model simulation of storm generated waves on a Philippine reef, which is located along the path of tropical storms, i.e., at least 10 typhoons on the average pass through the study site yearly. A model to simulate wave propagation was developed using Simulating Waves Nearshore (SWAN) and DELFT3D-WAVE computer simulation software. Scenarios involving local monsoonal wind forcing and storm conditions were simulated. In addition, as climate change may also result to increased relative sea level, a 0.3 m and 1 m rise in sea level scenarios were also used in the wave model simulations. Results showed that the extensive reef system in the site helped dissipate wave energy that in turn reduced wave run-up on land. A significant reduction in wave energy was observed in both climate change, i.e., stronger wind and higher sea level, and non-climate change scenarios. This present study was conducted in a reef whose coral cover is in excellent condition (i.e., 50 to 80% coral cover). Estimates of coral reef growth are in the same order of magnitude as estimates of relative sea level rise based on tide gauge and satellite altimeter data, thus it is possible that the role of reefs in attenuating wave energy may be maintained if coral reef growth can keep up with the change in sea level. Nonetheless, to maintain reef growth, it is imperative to manage coral reef ecosystems sustainably and to eliminate the stressors that are within human control. Minimizing activities such as illegal and destructive blast and poison fishing methods, pollution and siltation, is crucial to minimize the impacts of high-energy waves that may increase with climate change.