Mechanical behaviour and failure of cohesive granular materials

We investigate the stress–strain behaviour and failure of a cohesive granular material both by experiments and numerical simulations. The material is an assembly of aluminium rods glued together by means of an epoxy resin. The behaviour of cohesive bonds (force–displacement relationship, failure conditions) is characterized by performing simple loading tests (tension/compression, shear…) on a couple of rods. Then, this local behaviour is introduced in a numerical code based on a discrete element method in order to perform numerical compression tests on large samples. The validation of this approach was the main goal of the present investigation that is essentially achieved by a direct comparison between the numerical results and similar experimental tests. As a basic application, we derive the macroscopic cohesion and friction characteristics of random cohesive materials by systematic numerical simulations in a biaxial geometry. Copyright © 2004 John Wiley & Sons, Ltd.     

Rhone River flood deposits in Lake Le Bourget: a proxy for Holocene environmental changes in the NW Alps, France

The Holocene evolution of Rhone River clastic sediment supply in Lake Le Bourget is documented by sub-bottom seismic profiling and multidisciplinary analysis of well-dated sediment cores. Six high-amplitude reflectors within the lacustrine drape can be correlated to periods of enhanced inter- and underflow deposition in sediment cores. Based on the synthesis of major environmental changes in the NW Alps and on the age-depth model covering the past 7500 years in Lake Le Bourget, periods of enhanced Rhone River flood events in the lake can be related to abrupt climate changes and/or to increasing land use since c. 2700 cal. yr BP. For example, significant land use under rather stable climate conditions during the Roman Empire may be responsible for large flood deposits in the northern part of Lake Le Bourget between AD 966 and 1093. However, during the Little Ice Age (LIA), well-documented major environmental changes in the catchment area essentially resulted from climate change and formed basin-wide major flood deposits in Lake Le Bourget. Up to five 'LIA-like' Holocene cold periods developing enhanced Rhone River flooding activity in Lake Le Bourget are documented at c. 7200, 5200, 2800, 1600 and 200 cal. yr BP. These abrupt climate changes were associated in the NW Alps with Mont Blanc glacier advances, enhanced glaciofluvial regimes and high lake levels. Correlations with European lake level fluctuations and winter precipitation regimes inferred from glacier fluctuations in western Norway suggest that these five Holocene cooling events at 45°N were associated with enhanced westerlies, possibly resulting from a persistent negative mode of the North Atlantic Oscillation.     

MODIS Derived Equilibrium Line Altitude Estimates for Purogangri Ice Cap,Tibetan Plateau,and their Relation to Climatic Predictors (2001–2012)

The variation of the equilibrium line altitude can be used as an indicator for glacier mass balance variability. Snow lines at the end of the ablation period are suitable proxies for the annual equilibrium line altitude on glaciers. We investigate snow lines at Purogangri ice cap on the central Plateau in order to study the interannual variability of glacier mass balance. Datasets of the daily Moderate Resolution Imaging Spectroradiometer snow product MOD10A1 were used to infer transient snow line variability during 2001–2012 and to derive regional‐scale, annual equilibrium line altitude. The Moderate Resolution Imaging Spectroradiometer snow albedo embedded within the snow product was compared with high‐resolution Landsat imagery. An albedo threshold was established to differentiate between ice and snow and the 13th percentile of the altitudes of snow‐covered pixels was chosen to represent the snow line altitude. The second maximum of the snow line altitudes in the ablation period was taken as a proxy for the annual equilibrium line altitude. A linear correlation analysis was carried out (1) between interannual variability of the equilibrium line altitude at Purogangri ice cap and various climate elements derived from the High Asia Reanalysis, and (2) between interannual variability of the equilibrium line altitude and the circulation indices North Atlantic Oscillation and Indian Summer Monsoon. Results suggest that air temperature and meridional wind speed above ground in July, as well as the lower tropospheric zonal wind in June and August play a crucial role in the development of the annual equilibrium line altitude.     

Particle fluxes and recent sediment accumulation on the Aquitanian margin of Bay of Biscay

As a part of the ANR-Forclim experiment, particle mass fluxes and sedimentation processes were investigated on the slope of Aquitanian margin of the Bay of Biscay, between the canyons of Cap-Breton and Cap-Ferret. Interface sediments were collected along a depth transect from 145 to 2000 m; simultaneously a mooring line was deployed at the deepest station (WH, 2000 m) with two traps (800 and 1700 m) for a 16-month period (June 2006–November 2007). ²¹⁰Pb activities of settling particles and of interface sediments were determined to study transport processes of particles. Sediment and mass accumulation rates, calculated from excess ²¹⁰Pb profiles in the sediment column, show the expected decreasing trend with depth, as usually observed on margins. Mean particulate mass fluxes at 800 and 1700-m depth at site WH are, respectively, 27 and 70 g m^?2 a^?1.The ²¹⁰Pb budget points out events of temporary high lateral input of particles. The comparison of mass and ²¹⁰Pb fluxes between the water column and the seabed indicates that lateral transport plays an important role in particle accumulation on the Aquitanian margin. Regarding the objectives of the ANR-Forclim program, which aims to improve significantly the interpretation of fossil foraminifera signals, as a proxy for hydrological changes in the North Atlantic ocean, these results highlight advection processes must be considered when interpreting fluxes of foraminifers on the Aquitanian margin.     

Ionic surfactants adsorption on heterogeneous surfacesAdsorption de tensioactifs ioniques sur les surfaces hétérogènes

The adsorption of surfactants from aqueous solution is a phenomenon of major importance in applications ranging from ore flotation and paint technology to enhanced oil recovery. As this paper will illustrate, the process is very complex and of high scientific interest; its results can be extended to the retention of organic compounds (humic and fulvic acids, pollutants...) on solids in the biosphere. For a good understanding of the mechanisms involved in surfactants adsorption at the hydrophilic solid–aqueous solution interface, thermodynamic models have to take into account: (i) the physical chemistry of the surfactant in aqueous solution for choosing the appropriate reference phase, (ii) the surface heterogeneity of the adsorbing solid, (iii) the intensity of normal adsorbate–adsorbent bonds responsible for adsorption, (iv) the intensity of lateral bonds that favour the formation of surface aggregates through cooperative process and finally, (v) suitable theoretical models to describe adsorption phenomena. Once this has been achieved, two systems can be discussed: systems characterised by strong normal adsorbate–adsorbent bonds, currently used in ore flotation, which lead, in the case of heterogeneous surfaces, to the formation of lamellar aggregates at monolayer concentration and bilayer formation for higher concentrations. Systems characterised by weak normal adsorbate–adsorbent bonds, currently used in enhanced oil recovery and hydrocarbon (bio)remediation, which correspond to: (i) formation of globular micelles at the solid surface near the CMC when the temperature is higher than the Krafft point, (ii) formation of bilayered lamellar aggregates in the opposite case, (iii) three-dimensional condensation on substrate (T<T_Krafft) if the ionic surfactant interacts with cations in the bulk. To cite this article: J.-M. Cases et al., C. R. Geoscience 334 (2002) 675–688.     

Effects of different crystal faces on the surface charge of colloidal goethite (α-FeOOH) particles: an experimental and modeling study

The surface charge of colloidal particles is usually determined by potentiometric titration. These acid-base titrations make it possible to measure the pH of point-of-zero charge (pzc) for oxide minerals. This macroscopic property is the most important parameter used in surface complexation modeling to reproduce experimental data. The pzc values of goethite reported in the literature vary between 7.0 and 9.5. Carbonate adsorption and/or surface morphology are thought to account for this wide range.We demonstrate a procedure for the removal of the carbonate ions that initially adsorb on goethite and strongly affect the titration curves and pzc determination. We also investigated the crystal-face-specific reactivity of two morphologically different goethites. The z-profiles obtained from atomic force microscopy (AFM) images showed that the goethite with the smallest specific surface area (S = 49 m²/g, denoted G49) exhibits 70% of the (001) face, whereas this value is only 30% for the goethite with largest specific surface area (S = 95 m²/g, denoted G95). This morphologic difference results in slightly different pzc values: 9.0 for G49 goethite and 9.1 for G95 geothite. These experimental pzc values have been correlated with multisite complexation calculations using both the full-site and the 1-pK approaches. We used the full-site approach to consider all of the configurations of hydrogen bond interactions with surface site. The resulting mean charges gave estimated pzc values of 8.9 and 9.2 for the (001) and (101) faces, respectively. Considering these theoretical pzc values for individual faces and the face distributions obtained from AFM analysis, the calculated pzc values are in full agreement with the experimental pzc values. However, this morphologic difference is more expressed in surface charge values than in the pzc values. Indeed, the surface charge of G49 goethite is much higher than that of G95 goethite, and the 1-pK calculations make it possible to fit the titration data satisfactorily.     

A red algal bloom in the aftermath of the Marinoan Snowball Earth

Organic matter from the cap dolostones overlying the Marinoan‐age glacigenic diamictites of the Araras Group, Amazon craton, has been studied to reconstruct the post‐glacial ecosystem. Molecular fossils indicate that the post‐Marinoan ecosystem was marked by an apparent decline in marine algal diversity. The proliferation of red algae may be explained by environmental changes, such as a massive nutrient input accompanying continental weathering after the ice thaw and a dimer light penetrating sea water due to the drowning of the platform. In addition, the presence of green sulphur bacteria indicates that sea water was stratified with an anoxic (possibly euxinic, i.e. sulphidic) layer at the water–sediment interface. Sulphur cycling probably occurred at the redox boundary as suggested by the recognition of active sulphate reduction. This observation supports a microbially induced model for the formation of the cap dolostones.     

Regional Flow and Deformation Analysis of Basin‐Fill Aquifer Systems Using Stress‐Dependent Parameters

Changes in effective stress due to water pressure variations modify the intrinsic hydrodynamic properties of aquifers and aquitards. Overexploited groundwater systems, such as basins with heavy pumping, are subject to nonrecoverable modifications. This results in loss of permeability, porosity, and specific storage due to system consolidation. This paper presents (1) the analytical development of model functions relating effective stress to hydrodynamic parameters for aquifers and aquitards constituted of unconsolidated granular sediments, and (2) a modeling approach for the analysis of aquifer systems affected by effective stress variations, taking into account the aforementioned dependency. The stress‐dependent functions were fit to laboratory data, and used in the suggested modeling approach. Based on only few unknowns, this approach is computationally simple, efficiently captures the hydromechanical processes that are active in regional aquifer systems under stress, and readily provides an estimate of their consolidation.     

Interferometry basics in practice: Exercises

The following exercises aim to learn the link between the object intensity distribution and the corresponding visibility curves of a long-baseline optical interferometer. They are also intended to show the additional constraints on observability that an interferometer has.This practical session is meant to be carried out with the ASPRO software, from the Jean-Marie Mariotti Center, but can also be done using other observation preparation software, such as viscalc from ESO.There are two main parts with series of exercises and the exercises corrections. The first one aims at understanding the visibility and its properties by practicing with simple examples, and the second one is about UV coverage.     

Regional flow simulation in fractured aquifers using stress-dependent parameters

A model function relating effective stress to fracture permeability is developed from Hooke's law, implemented in the tensorial form of Darcy's law, and used to evaluate discharge rates and pressure distributions at regional scales. The model takes into account elastic and statistical fracture parameters, and is able to simulate real stress-dependent permeabilities from laboratory to field studies. This modeling approach gains in phenomenology in comparison to the classical ones because the permeability tensors may vary in both strength and principal directions according to effective stresses. Moreover this method allows evaluation of the fracture porosity changes, which are then translated into consolidation of the medium.