Infrared spectroscopic and X-ray diffraction characterization of the nature of adsorbed arsenate on ferrihydrite

Fourier transformed infrared (FTIR) spectroscopy was used to characterize arsenate-ferrihydrite sorption solids synthesized at pH 3-8. The speciation of sorbed arsenate was determined based on the As-O stretching vibration bands located at 650-950 cm⁻¹ and O-H stretching vibration bands at 3000-3500 cm⁻¹. The positions of the As-O and O-H stretching vibration bands changed with pH indicating that the nature of surface arsenate species on ferrihydrite was strongly pH dependent. Sorption density and synthesis media (sulfate vs. nitrate) had no appreciable effect. At acidic pH (3, 4), ferric arsenate surface precipitate formed on ferrihydrite and constituted the predominant surface arsenate species. X-ray diffraction (XRD) analyses of he sorption solids synthesized at elevated temperature (75 °C), pH 3 clearly showed the development of crystalline ferric arsenate (i.e. scorodite). In neutral and alkaline media (pH 7, 8), arsenate sorbed as a bidentate surface complex (in both protonated FeO₂As(O)(OH)⁻ and unprotonated forms). For the sorption systems in slightly acidic media (pH 5, 6), both ferric arsenate and surface complex were probably present on ferrihydrite. It was further determined that the incorporated sulfate in ferrihydrite during synthesis was substituted by arsenate and was more easily exchangeable with increasing pH.     

鄂尔多斯盆地庆城地区延长组7段致密油特征及油源分析

鄂尔多斯盆地三叠系延长组7段(长7段)半深湖—深湖相优质油源岩是油气的重要来源,包括黑色页岩和暗色泥岩,作为盆地重要的供烃源岩一直是研究的热点。为了明确不同烃源岩的贡献及油气来源,通过对庆城地区长7段致密油特征进行分析,对原油进行精细划分,并对源岩有效性进行分析,进一步明确油源对应关系,研究表明,庆城地区长7段黑色页岩和暗色泥岩均对油气成藏有贡献,其中黑色页岩贡献最大,长7₃段暗色泥岩次之,长7₂和长7₁段暗色泥岩贡献较小;原油为低密度、中—低黏度和低凝固点的轻质油。根据生标物特征将原油划分为3类,A类原油具有低C₃₀重排藿烷/C₂₉藿烷、低C₂₉Ts/C₂₉藿烷、低Ts/Tm的特征,由黑色页岩贡献,主要分布于长7₁段;C类原油具有高C₃₀重排藿烷/C₂₉藿烷、高C₂₉Ts/C₂₉藿烷、高Ts/Tm的特征,主要由暗色泥岩贡献,...     

Phosphorus speciation in surface sediments of a hypertrophic lake,Southwestern China: insights from fractionation and 31P NMR

Acta Geochimica - Phosphorus (P) species in surface sediments from a shallow, hypertrophic lake, Lake Dianchi, China, were investigated by P fractionation and 31P nuclear magnetic resonance (NMR)...     

Beiya Gold Deposit,Heqing County,Yunnan——One of China's Ten Biggest Gold Deposits

<正>The Beiya gold polymetallic ore district covers an area of 22.06 km2 and is located 47.5 km away in the direction 172°from Heqing county seat of northwestern Yunnan.Its geographical coordinates are 100°11′15″–100°13′00″E and6°07′30″–26°10′30″N.Since its discovery in 1999 until November 31st 2013,it has had accumulative proven(111b+122b+331+332+333)gold metal amounts of 258.475t at an average grade of 2.61 g/t.This deposit contains 88.98million tons of paragenetic and associated iron ores,with TFe grade varying from 9%to 36%;metal amounts are:gold     

Characteristics and Main Controlling Factors of Tight Oil Reservoir in the Jimsar Sag of Junggar Basin

<正>1 Introduction Jimsar sag covers about 1278 km2 in the south of the eastern uplift of Junggar basin.It is a half graben depression area in which the west,south and north is controlled by faults(Fig.1),and is tilting uplift to the east.It deposited Permian,Triassic,Jurassic,the Cretaceous and Cenozoic strata chronologically.The thickness of Lucaogou Formation is about 200 m to 350 m,it is the     

China Has Discovered Super-Large Big Flake Graphite Ores

<正>The Geological Mineral Exploration Institute No.8 in Inner Mongolia,China has recently discovered a new super-large big flake graphite ore deposit named the Chahanmuhulu graphite deposit.A total of eleven graphite orebodies were delineated in the deposit,with orebodies No.III and IV being dominant.The orebodies extend 85–1630 m along the strike,and have an oblique depth of 563     

中南部非洲的地质构造演化与矿产分布规律

中南部非洲优势矿产资源有金、铜、铁、铬、金刚石,锰、铀、镍、钒、钴、铂、锑的储量也居世界前列。主要的矿产集中分布于前寒武纪地体内,中南部非洲前寒武纪地体的形成演化决定了矿产的种类和主要成矿类型。文章总结了中南部非洲的地质构造演化以及其主要矿产资源的成矿类型和分布规律,并划分成矿区带至三级。探讨了部分主要成矿区带的成矿规律:太古宙的矿产主要与花岗-绿岩地体有关;古元古代的矿产主要分布于陆缘盆地,与岩浆作用有关;中元古代的矿产主要与岩浆作用有关,次为沉积变质作用;新元古代的矿产主要与沉积变质作用有关,次为岩浆作用。     

中南部非洲纳米比亚三级成矿区带划分

纳米比亚矿产资源丰富,是非洲第四大矿产国,现已发现矿产30多种,主要生产金刚石、铀、铜、金、银、铅、锌等,其外汇收入的一半以上来自矿产品。文章在查阅文献资料的基础上,详细研究了该国区域成矿地质背景、矿产资源分布特征,结合成矿理论和成矿规律研究的新成果,对纳米比亚成矿规律进行了研究,提出三级成矿区带划分方案,全区共划分8个Ⅲ级成矿区带,对进一步圈定重要找矿远景区提供了依据。     

一种沟灌累积入渗量简化计算方法

为简化沟灌二维累积入渗量的数值计算,采用理论分析和数值模拟相结合的方法,研究分析了土壤初始含水率、入渗水深、沟底宽、边坡系数、土壤质地和容重等因素对沟灌边界效应和拟合系数γ的影响,并建立了系数γ与主要影响因素间的函数关系式,提出了沟灌累积入渗量简化计算方法.结果表明,土壤初始含水率、沟底宽和边坡系数对沟灌边界效应的影响较小,而入渗水深、土壤质地和容重对沟灌边界效应的影响显著;拟合系数γ主要与入渗水深的变化有关,随入渗水深的增大呈现减小趋势,但对初始含水率、沟底宽、边坡系数、土壤质地和容重等因素变化的敏感性较低,可忽略其影响;建立了估算拟合系数γ的计算式,结合已有文献资料对其可靠性进行了验证,结果表明黏壤土和砂壤土不同入渗时间内,其沟灌累积入渗量计算值与实测值和HYDRUS软件模拟值具有高的一致性,说明文中所建公式估算拟合系数γ值可靠.研究结果可为简化沟灌累积入渗量的数值计算提供理论依据和技术支撑.