荡子山白榴霓霞岩包体中强烈的流体活动证据

荡子山火山岩隶属黑龙江嫩江县境内的科洛火山岩群,岩性白榴苦橄岩,见有白榴霓霞岩岩浆型包体.     

北祁连东段景泰地区下古生界两套砂岩微量元素和稀土元素特征及其构造意义

早奥陶世和早志留世是北祁连加里东造山带构造演化和盆地转变的关键时期。在造山带东段景泰地区,下奥陶统阴沟组和下志留统肮脏沟组两套砂岩的微量元素和稀土元素特征显示,阴沟组杂砂岩样品（Cj1和Cj3）具有最小的Eu/Eu*及最大的Th/Sc和REE,肮脏沟组杂砂岩具有较小的Eu/Eu*和较大的Th/Sc及REE;阴沟组岩屑砂岩样品（Cj13、Cj15和Cj18）具有最大的Eu/Eu*及最小的Th/Sc、REE和La/Yb。多个物源、构造背景判别图解和多元素蛛网图分析表明,阴沟组杂砂岩样品具大陆边缘的构造背景,主要物源为大陆上地壳再旋回沉积物和长英质岩石;岩屑砂岩样品为岛弧构造背景,以中基性安山质岩石为主要物源,可能受陆源物质的微弱影响。肮脏沟组杂砂岩构造背景复杂,表现出大陆岛弧、活动陆缘和被动陆缘三种环境共存的特点,受中基性火山弧物质、长英质岩石和再旋回沉积岩的混合物源的影响。两套砂岩的元素特征表明二者可能具有相似的源区。阴沟组杂砂岩源区可能为阿拉善地块南缘海原群变沉积岩或其他相似的陆源再旋回沉积物,砂岩碎屑以来自初始火山弧物质为主,以石灰沟岛弧型中基性火山岩作为其源岩最合适。阴沟组形成于初始弧后盆地环境,是岛弧活动的直接记录。肮脏沟组可能的源岩为阿拉善地块南缘海原群变沉积岩和中高等成熟度的石灰沟岛弧型火山岩及海原群岛弧型变火山岩,沉积于弧后前陆盆地,对构造环境的反映存在滞后性。     

鲁23井“动水位”观测的分析

本文介绍了鲁23井“动水位”观测情况。提出了一个分析有泄流的“动水位”的新方法,即把流量换算成水位,以等效静水位来表示“动水位”与流量。由于把“动水位”与流量用一个量来计算,从而为“动水位”观测定量的、统一的分析研究提供了新的方法。这对提高“动水位”井的监测预报地震能力起一定的作用。 本文还以鲁23井“动水位”观测资料为例,利用新方法进行处理的观测分析结果与理论研究结果是一致的。     

Theoretical infrared spectra of some model polycyclic aromatic hydrocarbons: effect of ionization

In order to test the hypothesis of ionized polycyclic aromatic hydrocarbons (PAHs) as possible carriers of the UIR bands, we realized a computational exploration on selected PAHs of small dimension in order to identify which changes ionization would induce on their IR spectra. In this study we performed ab initio calculations of the spectra of neutral and positively ionized naphthalene, anthracene, and pyrene. The results are significantly important. The frequencies in the cations are slightly shifted with respect to the neutral species, but no general conclusion can be reached from the three molecules considered. By contrast, the relative intensities of most vibrations are strongly affected by ionization, leading to a much better agreement between the calculated CH/CC vibration intensity ratios and those deduced from observations.     

浙东晚白垩世小雄破火山中火山-侵入杂岩的岩石成因

破火山内出露的火山岩与浅成侵入岩为硅质岩浆演化研究提供了一个重要窗口，从而备受关注。小雄破火山内的火山-侵入杂岩是中国东南沿海晚白垩世岩浆活动的典型代表，包括小雄组火山岩（K₂x）与两类侵入岩（花岗斑岩、正长斑岩）。本文以小雄火山-侵入杂岩为研究对象，开展了系统的锆石U-Pb年代学、岩石学和地球化学研究，旨在深入探讨破火山内火山岩与侵入岩之间的成因联系和岩浆演化过程。系统的LA-ICP-MS 锆石U-Pb年代学研究表明，小雄组火山岩形成于98~88Ma，并具有多期次喷发的特点，可分为下段、中段和上段，年龄分别为98~96Ma（K₂x¹）、95~92Ma（K₂x²）、~ 88Ma（K₂x³）。小雄花岗斑岩形成年龄为90Ma；正长斑岩形成稍晚，约88Ma。与下段流纹质玻屑凝灰岩的Nd-Hf同位素组成[ε_Nd（t）=-8.3~-7.2， ε_Hf（t）=-11.8~-7.2]相比，中段流纹岩要更为亏损[ε_Nd（t）=-5.84~-5.32， ε_Hf（t）=-10.1~-0.5]。研究表明，小雄组流纹质火山岩的母岩浆可能起源于发生在深部岩浆房中渐进的壳幔相互作用，中段流纹岩的源区混入了更多的亏损幔源组分。中段流纹岩与花岗斑岩具有相似的Nd-Hf同位素组成，以及 "互补"的微量元素地球化学特征，由发生在浅部岩浆房的分离结晶作用和堆晶作用所制约。值得注意的是，正长斑岩与花岗斑岩并不存在直接的成因演化关系，两者应是不同的起源。不同的正长斑岩岩株具有高度一致的结晶年龄、微量元素特征以及Nd-Hf同位素组成，以上特征均表明小雄破火山内的正长斑岩具有相同的起源。正长斑岩母岩浆起源于富集岩石圈地幔的部分熔融，岩浆源区混入了来自亏损的软流圈地幔组分，其地球化学成分变化主要受"普通辉石+磷灰石+钛铁矿"的分离结晶所控制。     

Interstellar water in meteorites?

D/H ratios of two meteorites (Renazzo CR and Semarkona LL3), which are known to exhibit the largest departures from the terrestrial hydrogen isotopic ratios, have been determined with the CRPG Nancy ion microprobe. Correlations between the D/H ratios and the chemical compositions (H2O, K, Si, C/H) of plausible hydrogen carriers were observed. From these correlations, it is possible to show that, contrary to previous interpretations, phyllosilicates are the carriers of the deuterium-rich hydrogen in Semarkona and Renazzo: 870 x 10(-6) > or = D/H > or = 670 x 10(-6) (+4600 > or = deltaD > or = 3300%) and > or = 320 x 10(-6) (deltaD > or = 1050%), respectively. Hydrogen is also present in the chondrules of these two deuterium-rich meteorites. The large differences in D/H ratios between matrix (up to 700 x 10(-6), deltaD up to +3500%) and chondrules (from 120 x 10(-6) (deltaD = -230%) to 230 x 10(-6) (deltaD = +475%)) show that hydrogen in chondrules cannot originate from the matrix by simple contamination or diffusion processes. The high D/H ratios measured in water-bearing minerals could not have been produced thermally within a dense solar nebula. Chemical reactions (i.e., involving ions or radicals), taking place in interstellar space or in the outer regions of the nebula at 110-140K are presently the only conceivable mechanisms capable of yielding such isotopic enrichments. Water in these meteorites should no longer be considered as a simple product of nebular condensation under equilibrium thermodynamic conditions at T > or = 160K.     

Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed

The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline.     

Numerical simulation of the general circulation of the atmosphere of Titan

The atmospheric circulation of Titan is investigated with a general circulation model. The representation of the large-scale dynamics is based on a grid point model developed and used at Laboratoire de Météorologie Dynamique for climate studies. The code also includes an accurate representation of radiative heating and cooling by molecular gases and haze as well as a parametrization of the vertical turbulent mixing of momentum and potential temperature. Long-term simulations of the atmospheric circulation are presented. Starting from a state of rest, the model spontaneously produces a strong superrotation with prograde equatorial winds (i.e., in the same sense as the assumed rotation of the solid body) increasing from the surface to reach 100 m sec-1 near the 1-mbar pressure level. Those equatorial winds are in very good agreement with some indirect observations, especially those of the 1989 occultation of Star 28-Sgr by Titan. On the other hand, the model simulates latitudinal temperature contrasts in the stratosphere that are significantly weaker than those observed by Voyager 1 which, we suggest, may be partly due to the nonrepresentation of the spatial and temporal variations of the abundances of molecular species and haze. We present diagnostics of the simulated atmospheric circulation underlying the importance of the seasonal cycle and a tentative explanation for the creation and maintenance of the atmospheric superrotation based on a careful angular momentum budget.     

矿物标型六性及其在胶东金矿中的应用

目前矿物标型研究和应用已进入一个新的阶段。作者从哲学的高度,把国内外矿物标型特征的分散研究加以集中概括和总结,提出了“矿物标型六性”的普遍规律,即普遍性、特殊性、变化性、相应性、继承性和分带性,对矿物标型特征研究具重要的指导意义。这些规律在胶东金矿中得到广泛应用,并已取得良好效果。     

张家口市湿地资源现状、问题与保护对策

张家口地区有丰富的湿地资源,张家口的河流、湖淖等湿地对京津地区的水资源供应与调节、生物多样性保护、生态环境的平衡与区域可持续发展关系重大,本文对该区域主要湿地现状、导致其退化的主要原因与问题进行了探讨,并提出了当前湿地保护的建议与对策。