Volatile loss from melt inclusions in pyroclasts of differing sizes

We have investigated the loss of H₂O from olivine-hosted melt inclusions (MIs) by designing an experiment using tephra samples that cooled at different rates owing to their different sizes: ash, lapilli, and bomb samples that were deposited on the same day (10/17/74) of the sub-Plinian eruption of Volcán de Fuego in Guatemala. Ion microprobe, laser ablation-ICPMS, and electron probe analyses show that MIs from ash and lapilli record the highest H₂O contents, up to 4.4 wt%. On the other hand, MIs from bombs indicate up to 30 % lower H₂O contents (loss of ~1 wt% H₂O) and 10 % post-entrapment crystallization of olivine. This evidence is consistent with the longer cooling time available for a bomb-sized clast, up to 10 min for a 3–4-cm radius bomb, assuming conductive cooling and the fastest H diffusivities measured in olivine (D~10^?9 to 10^?10 m²/s). On the other hand, several lines of evidence point to some water loss prior to eruption, during magma ascent and degassing in the conduit. Thus, results point to both slower post-eruptive cooling and slower magma ascent affecting MIs from bombs, leading to H₂O loss over the timescale of minutes to hours. The important implication of this study is that a significant portion of the published data on H₂O concentrations in olivine-hosted MIs may reflect unrecognized H₂O loss via diffusion. This work highlights the importance of reporting clast and MI sizes in order to assess diffusive effects and the potential benefit of using water loss as a chronometer of magma ascent.     

Spectral Irradiance, Phytoplankton Community Composition and Primary Productivity in a Salt Marsh Estuary, North Inlet, South Carolina, USA

We investigated spatial and temporal changes in spectral irradiance, phytoplankton community composition, and primary productivity in North Inlet Estuary, South Carolina, USA. High concentrations of colored dissolved organic matter (CDOM) were responsible for up to 84 % of the attenuation of photosynthetically available radiation (PAR). Green-yellow wavelengths were the predominant colors of light available at the two sampling sites: Clam Bank Creek and Oyster Landing. Vertical attenuation coefficients of PAR were 0.7–2.1 m^?1 with corresponding euphotic zone depths of 1.5–6.7 m. Phytoplankton biomass (as chlorophyll a [chl a]) varied seasonally with a summer maximum of 16 μg chl a l^?1 and a winter minimum of 1.4 μg chl a l^?1. The phytoplankton community consisted mainly of diatoms, prasinophytes, cryptophytes and haptophytes, with diatoms and prasinophytes accounting for up to 67 % of total chl a. Changes in phytoplankton community composition showed strongest correlations with temperature. Light-saturated chl a-specific rates of photosynthesis and daily primary productivity varied with season and ranged from 1.6 to 14 mg C (mg chl a) ^?1?h^?1 (32–803 mg C m^?3?day^?1). Calculated daily rates added up to an annual carbon fixation rate of 84 g C m^?3?year^?1. Overall, changes in phytoplankton community composition and primary productivity in North Inlet showed a strong dependence on temperature, with PAR and spectral irradiance playing a relatively minor role due to short residence times, strong tidal forcing and vertical mixing.     

Introduction to hydromechanical well tests in fractured rock aquifers

This article introduces hydromechanical well tests as a viable field method for characterizing fractured rock aquifers. These tests involve measuring and analyzing small displacements along with pressure transients. Recent developments in equipment and analyses have simplified hydromechanical well tests, and this article describes initial field results and interpretations during slug and constant-rate pumping tests conducted at a site underlain by fractured biotite gneiss in South Carolina. The field data are characterized by displacements of 0.3 μm to more than 10 μm during head changes up to 10 m. Displacements are a hysteretic function of hydraulic head in the wellbore, with displacements late in a well test always exceeding those at similar wellbore pressures early in the test. Displacement measurements show that hydraulic aperture changes during well tests, and both scaling analyses and field data suggest that T changed by a few percent per meter of drawdown during slug and pumping tests at our field site. Preliminary analyses suggest that displacement data can be used to improve estimates of storativity and to reduce nonuniqueness during hydraulic well tests involving single wells.     

A local model for analysis of pump and treat systems with vertical barrier walls

We present a mathematical model of local, steady groundwater flow near a vertical barrier wall. Flow features represented in the model include an impermeable arc-shaped barrier wall and multiple wells; distant boundary conditions are not included explicitly, but their effects on the local flow field are modelled by specifying a uniform flow at infinity and a constant areal recharge within a local domain. We develop an explicit closed-form solution to the boundary-value problem using the analytic element method. The solution is an extension of a harmonic solution presented by Anderson and Mesa [Anderson EI, Mesa E. The effects of vertical barrier walls on the hydraulic control of contaminated groundwater. Adv Water Resourc 2006;29(1):89–98] which does not include the effects of recharge. We demonstrate that the general solution with recharge consists of the harmonic solution superposed on a special case of the harmonic solution along with two elementary one-dimensional flow solutions. The results are used to investigate the effects of areal recharge on the capture zone envelopes of the pumping wells and on the reduction in discharge that can be achieved by including a barrier wall in a pump and treat design. We find that the benefits of including an open barrier wall in a design, measured as a reduction in the pumping rate required to contain a plume, increase for higher recharge rates. Dimensionless plots of capture zone envelopes are presented for a practical well and barrier wall configuration.     

Wave-induced steady streaming,mass transport and net sediment transport in rough turbulent ocean bottom boundary layers

The interaction between two important mechanisms which causes streaming has been investigated by numerical simulations of the seabed boundary layer beneath both sinusoidal waves and Stokes second order waves, as well as horizontally uniform bottom boundary layers with asymmetric forcing. These two mechanisms are streaming caused by turbulence asymmetry in successive wave half-cycles (beneath asymmetric forcing), and streaming caused by the presence of a vertical wave velocity within the seabed boundary layer as earlier explained by Longuet-Higgins. The effect of wave asymmetry, wave length to water depth ratio, and bottom roughness have been investigated for realistic physical situations. The streaming induced sediment dynamics near the ocean bottom has been investigated; both the resulting suspended load and bedload are presented. Finally, the mass transport (wave-averaged Lagrangian velocity) has been studied for a range of wave conditions. The streaming velocities beneath sinusoidal waves (Longuet-Higgins streaming) is always in the direction of wave propagation, while the streaming velocities in horizontally uniform boundary layers with asymmetric forcing are always negative. Thus the effect of asymmetry in second order Stokes waves is either to reduce the streaming velocity in the direction of wave propagation, or, for long waves relative to the water depth, to induce a streaming velocity against the direction of wave propagation. It appears that the Longuet-Higgins streaming decreases as the wave length increases for a given water depth, and the effect of wave asymmetry can dominate, leading to a steady streaming against the wave propagation. Furthermore, the asymmetry of second order Stokes waves reduces the mass transport (wave-averaged Lagrangian velocity) as compared with sinusoidal waves. The boundary layer streaming leads to a wave-averaged transport of suspended sediments and bedload in the direction of wave propagation.     

International co-operation on Rhine water quality 1945-2008: An example to follow?

The management of the Rhine is often seen as an exemplary case of international river basin management. In the Rhine basin, countries that went to war with each other twice in the last century have managed to reach agreements on many issues and water quality has improved considerably. The improvement in water quality is often attributed to the activities of the International Commission for the Protection of the Rhine and in particular to its Rhine Action Plan. In order to test this assertion, this paper describes and analyzes the development of international co-operation on the water quality of the Rhine since 1945. It concludes that water quality improvement cannot be attributed to any single factor. Instead, a whole array of interrelated factors are at play, including the European Union, other international fora such as the North Sea Ministerial Conferences, domestic legislation, the activities of environmental NGOs and waterworks, growing environmental awareness, and the changing structure of the industry in the basin. Because of the importance of contextual factors, the Rhine experiences cannot simply be applied to basins with a different context. In many cases, international river basin management may be promoted most effectively by promoting co-operation at the river basin level. In many other cases, however, it may be more effective to identify and then work on the contextual factors that (1) have the biggest leverage effect in the specific case and (2) can be influenced most effectively.     

Lithium isotope systematics of lavas from the Cook–Austral Islands: Constraints on the origin of HIMU mantle

Radiogenic isotope variations in lavas from the Cook–Austral volcanic chain have delineated three distinct mantle sources: a HIMU component, a depleted component (DM), and an enriched component (EM). To better constrain the mantle sources for South Pacific hot spot volcanism, we determined lithium isotopic compositions of lavas from Raivavae, Rapa, Mangaia and Tubuai of the volcanic chain. The study includes whole rock and mineral analyses. In general, δ⁷Li of most olivines resemble bulk rock composition whereas clinopyroxenes are variably lighter. This implies that clinopyroxene is more susceptible to diffusion-induced fractionation, in agreement with previous studies. Olivine δ⁷Li values span a narrower range than whole rock values, and do not extend to the very heavy compositions previously reported in HIMU bulk lavas. This discrepancy likely reflects alteration of bulk lavas, and suggests that Li-isotope analyses of bulk lavas should be interpreted with caution. Olivines from HIMU lavas have heavy δ⁷Li values (up to 6.2‰), and extend beyond the range reported for fresh MORB. Correlations between Li-isotopes and radiogenic isotopes suggest that the heavy δ⁷Li values in HIMU olivines are a source characteristic and not the result of post-magmatic alteration. Although the Li-isotope composition of recycled, dehydrated oceanic crust is currently under debate, our results suggest that HIMU lavas derive from a source containing recycled dehydrated oceanic crust, and that the “heavy” Li-isotope signature of altered oceanic crust is partially preserved during passage through the subduction factory.     

High-precision stellar abundances of the elements: methods and applications

Efficient spectrographs at large telescopes have made it possible to obtain high-resolution spectra of stars with high signal-to-noise ratio and advances in model atmosphere analyses have enabled estimates of high-precision differential abundances of the elements from these spectra, i.e. with errors in the range 0.01–0.03 dex for F, G, and K stars. Methods to determine such high-precision abundances together with precise values of effective temperatures and surface gravities from equivalent widths of spectral lines or by spectrum synthesis techniques are outlined, and effects on abundance determinations from using a 3D non-LTE analysis instead of a classical 1D LTE analysis are considered. The determination of high-precision stellar abundances of the elements has led to the discovery of unexpected phenomena and relations with important bearings on the astrophysics of galaxies, stars, and planets, i.e. (i) Existence of discrete stellar populations within each of the main Galactic components (disk, halo, and bulge) providing new constraints on models for the formation of the Milky Way. (ii) Differences in the relation between abundances and elemental condensation temperature for the Sun and solar twins suggesting dust-cleansing effects in proto-planetary disks and/or engulfment of planets by stars; (iii) Differences in chemical composition between binary star components and between members of open or globular clusters showing that star- and cluster-formation processes are more complicated than previously thought; (iv) Tight relations between some abundance ratios and age for solar-like stars providing new constraints on nucleosynthesis and Galactic chemical evolution models as well as the composition of terrestrial exoplanets. We conclude that if stellar abundances with precisions of 0.01–0.03 dex can be achieved in studies of more distant stars and stars on the giant and supergiant branches, many more interesting future applications, of great relevance to stellar and galaxy evolution, are probable. Hence, in planning abundance surveys, it is important to carefully balance the need for large samples of stars against the spectral resolution and signal-to-noise ratio needed to obtain high-precision abundances. Furthermore, it is an advantage to work differentially on stars with similar atmospheric parameters, because then a simple 1D LTE analysis of stellar spectra may be sufficient. However, when determining high-precision absolute abundances or differential abundance between stars having more widely different parameters, e.g. metal-poor stars compared to the Sun or giants to dwarfs, then 3D non-LTE effects must be taken into account.     

Economic gains of liberalising access to fishing quotas within the European Union

This paper analyses the extent to which specialisation gains can be achieved by liberalising access to fishing quotas within the European Union (EU). Fishing quotas are today exchanged between EU member states at a rate of 4% of total turnover in EU fisheries. Germany, Belgium, Denmark and the Netherlands are the most active. Only one fourth of these exchanges are permanent. With the management systems in EU fisheries differing among countries, comparative advantages in fisheries exist in member states with the best management practices. Hence, although positive but small specialisation gains exist in EU fisheries today, these gains might potentially be increased by liberalising access to fishing quotas and allowing transferability of quotas between individuals from different countries on a permanent basis. Increasing the gains might, however, affect relative stability.