Pollen Viability for Air Pollution Bio-Monitoring

Biological characterization of Corylus avellana L. and Pinus nigra L. pollen samples was carried out to determine the actual value of pollen as a bio-indicator of the effects of atmospheric pollution, using samples from plants naturally developed in sites controlled for air pollution. In Trentino (North Italy), we selected six stations at three different levels of air pollution, which are constantly monitored with automatic gauges by the Environmental Protection Agency of Trento.First results showed that pollen viability of both species, germinability and pollen tube length of P. nigra, were higher in areas with no road traffic compared to heavy traffic ones. Pollen viability of P. nigra was positively correlated to ozone (O₃) concentrations and altitude but negatively to sulphur dioxide (SO₂), particulate matter with a diameter less than 10 m (PM₁₀), nitrogen oxides (NO_x) and nitrogen dioxide (NO₂) concentrations.     

Frequency analysis of the stability of asteroids in the framework of the restricted three-body problem

The stability of some asteroids, in the framework of the restricted three-body problem, has been recently proved in (Celletti and Chierchia, 2003), by developing an isoenergetic KAM theorem. More precisely, having fixed a level of energy related to the motion of the asteroid, the stability can be obtained by showing the existence of nearby trapping invariant tori existing at the same energy level. The analytical results are compatible with the astronomical observations, since the theorem is valid for the realistic mass-ratio of the primaries. The model adopted in (Celletti and Chierchia, 2003), is the planar, circular, restricted three-body model, in which only the most significant contributions of the Fourier development of the perturbation are retained. In this paper we investigate numerically the stability of the same asteroids considered in (Celletti and Chierchia, 2003), (namely, Iris, Victoria and Renzia). In particular, we implement the nowadays standard method of frequency-map analysis and we compare our investigation with the analytical results on the planar, circular model with the truncated perturbing function. By means of frequency analysis, we study the behaviour of the bounding tori and henceforth we infer stability properties on the dynamics of the asteroids. In order to test the validity of the truncated Hamiltonian, we consider also the complete expression of the perturbing function on which we perform again frequency analysis. We investigate also more realistic models, taking into account the eccentricity of the trajectory of Jupiter (planar-elliptic problem) or the relative inclination of the orbits (circular-inclined model). We did not find a relevant discrepancy among the different models.     

Electron Excitation Rates in the Solar Corona for non-Maxwellian Electron Distributions

The influence of electron non-Maxwellian distributions (power and -distribution) on the electron excitation rate in the solar corona is demonstrated. It is shown that the deviations in electron excitation rate are sufficient to affect intensities of spectral lines. As an example the diagnostics of a power-law distribution are demonstrated for a simplified calculation of the resonance lines of Fexxiv, Fexxv and Fexxvi. The results can be used in diagnosing solar flare plasmas, where the deviations of the electron distribution from a Maxwellian distribution can be large.     

Polynomial approximation of Poincaré maps for hamiltonian systems

Different methods are proposed and tested for transforming a nonlinear differential system, and more particularly a hamiltonian one, into a map without having to integrate the whole orbit as in the well known Poincaré map technique. We construct piecewise polynomial maps by coarse-graining the phase surface of section into parallelograms using values of the Poincaré maps at the vertices to define a polynomial approximation within each cell. The numerical experiments are in good agreement with the standard map taken as a model problem. The agreement is better when the number of vertices and the order of the polynomial fit increase. The synthetic mapping obtained is not symplectic even if at vertices there is an exact interpolation. We introduce a second new method based on a global fitting . The polynomials are obtained using at once all the vertices and fitting by least square polynomes but in such a way that the symplectic character is not lost.     

Petrogenetic processes in the ultramafic, alkaline and carbonatitic magmatism in the Kola Alkaline Province: A review

Igneous rocks of the Devonian Kola Alkaline Carbonatite Province (KACP) in NW Russia and eastern Finland can be classified into four groups: (a) primitive mantle-derived silica-undersaturated silicate magmas; (b) evolved alkaline and nepheline syenites; (c) cumulate rocks; (d) carbonatites and phoscorites, some of which may also be cumulates. There is no obvious age difference between these various groups, so all of the magma-types were formed at the same time in a relatively restricted area and must therefore be petrogenetically related. Both sodic and potassic varieties of primitive silicate magmas are present. On major element variation diagrams, the cumulate rocks plot as simple mixtures of their constituent minerals (olivine, clinopyroxene, calcite, etc). There are complete compositional trends between carbonatites, phoscorites and silicate cumulates, which suggests that many carbonatites and phoscorites are also cumulates. CaO / Al₂O₃ ratios for ultramafic and mafic silicate rocks in dykes and pipes range up to 5, indicating a very small degree of melting of a carbonated mantle at depth. Damkjernites appear to be transitional to carbonatites. Trace element modelling indicates that all the mafic silicate magmas are related to small degrees of melting of a metasomatised garnet peridotite source. Similarities of the REE patterns and initial Sr and Nd isotope compositions for ultramafic alkaline silicate rocks and carbonatites indicate that there is a strong relationship between the two magma-types. There is also a strong petrogenetic link between carbonatites, kimberlites and alkaline ultramafic lamprophyres. Fractional crystallisation of olivine, diopside, melilite and nepheline gave rise to the evolved nepheline syenites, and formed the ultramafic cumulates. All magmas in the KACP appear to have originated in a single event, possibly triggered by the arrival of hot material (mantle plume?) beneath the Archaean/Proterozoic lithosphere of the northern Baltic Shield that had been recently metasomatised. Melting of the carbonated garnet peridotite mantle formed a spectrum of magmas including carbonatite, damkjernite, melilitite, melanephelinite and ultramafic lamprophyre. Pockets of phlogopite metasomatised lithospheric mantle also melted to form potassic magmas including kimberlite. Depth of melting, degree of melting and presence of metasomatic phases are probably the major factors controlling the precise composition of the primary melts formed.     

Sulphur atmospheric deposition in areas with different anthropogenic loads in Belarus

This article presents some results of an investigation of sulphur atmospheric deposition in areas with different anthropogenic loads in Belarus. Through sampling and chemical analysis of precipitation, new data about sulphate concentrations in precipitation and atmospheric deposition of sulphur in different conditions, including regional background conditions, a large industrial city and a zone affected by point source of sulphur emission, were obtained. Comparison of the chemical composition of precipitation at three sampling locations has shown that the local emission of sulphur compounds has a minor influence on local sulphur deposition. This data points to the dominant role of transboundary transfer of sulphur in contamination and acidification of the environment in Belarus.     

Amazon River discharge estimated from TOPEX/Poseidon altimetry

This paper presents an application of the TOPEX/Poseidon (T/P) satellite altimetry data to estimate river discharge at three sites along the Amazon River. We discuss the methodology to establish empirical relationships between satellite-derived water levels and daily estimations of river discharges based on rating curves and in situ level measurements at gauging stations. Three sites are chosen: Manacapuru (River Solimões), Jatuarana (nearby the confluence of the Solimões and Rio Negro rivers) and Óbidos (Amazon River). We then reconstruct the satellite-based river discharge over a 10-year time span (1992–2002). Comparison between satellite-derived and river discharge at the gauging stations shows that the T/P data can successfully be used for hydrological studies of large rivers, in providing in particular discharge estimates when in situ data are not available. To cite this article: E.A. Zakharova et al., C. R. Geoscience 338 (2006).     

Constraints and deception in the isotopic record; the crustal evolution of the west Musgrave Province,central Australia

The Hf and Nd isotopic evolution of the Musgrave Province, central Australia, is used to constrain the timing of crust formation and lithospheric organisation of Proterozoic Australia. The dataset from this region challenges two widely held tenets of Hf and Nd isotope systematics, namely; that crust formation events can only be identified as periods when crystallisation ages correspond to model ages, and that linear Hf evolution arrays away from depleted mantle (along crustal Lu/Hf or Sm/Nd slopes) reflect reworking of the same source.Hf isotopes in Musgrave Province zircon crystals indicate two major crust formation events at c. 1900 Ma and at 1600–1550 Ma. Although no juvenile rocks or crystals are known from c. 1900 Ma, radiogenic addition into the crust at this time is required to account for consistent Nd and Hf evolution patterns, which show no indication of an initially heterogeneous source. Oxygen isotopes in zircon grains confirm that much of the c. 1900 Ma Hf isotopic signal is not compromised by mixtures. Furthermore, the correspondence between mantle extraction and the commencement of reworking of Archean material supports new crust generation at c. 1900 Ma and a coupling between lower and upper crustal processes. The c. 1900 Ma timing of juvenile addition is dissimilar to that in the Albany–Fraser and Arunta Orogens and may reflect continental arc development on the margin of a southern continent.The general Hf isotopic evolution trend of the Musgrave Province apparently reflects reworking from a dominant c. 1900 Ma source with some additional unradiogenic and radiogenic input through time. However, in the 1220–1050 Ma interval this apparent isotopic evolution contrasts with geological observations that indicate input of voluminous mantle-derived material. Intracontinental rifts and other regions with sustained very-high temperature crustal recycling processes generate magmatic provinces with extreme HFSE-enrichment. This can have a profound influence on isotopic evolution trends, suppressing typical juvenile addition patterns. Isotopic mixture modelling indicates that a significant volume of mantle derived material can be accommodated within HFSE enriched magmas without diverging isotopic signatures from apparent reworking trends. In the Musgrave Province, the crust had become so HFSE enriched during the prolonged Musgrave Orogeny (1220–1150 Ma) that it was insensitive to mantle input, which is estimated to have been as much as 85% during this event.     

U‐Pb Detrital Zircon Analysis – Results of an Inter‐laboratory Comparison

Inter‐laboratory comparison of laser ablation ICP‐MS and SIMS U‐Pb dating of synthetic detrital zircon samples provides an insight into the state‐of‐the art of sedimentary provenance studies. Here, we report results obtained from ten laboratories that routinely perform this type of work. The achieved level of bias was mostly within ± 2% relative to the ID‐TIMS U‐Pb ages of zircons in the detrital sample, and the variation is likely to be attributed to variable Pb/U elemental fractionation due to zircon matrix differences between the samples and the reference materials used for standardisation. It has been determined that ~ 5% age difference between adjacent age peaks is currently at the limit of what can be routinely resolved by the in situ dating of detrital zircon samples. Precision of individual zircon age determination mostly reflects the data reduction and procedures of measurement uncertainty propagation, and it is largely independent of the instrumentation, analytical technique and reference samples used for standardisation. All laboratories showed a bias towards selection of larger zircon grains for analysis. The experiment confirms the previously published estimates of the minimum number of grains that have to be analysed in order to detect minor zircon age populations in detrital samples.