Platinum‐group elements and rhenium in mantle xenoliths from the East Sayan volcanic field (Siberia,Russia): evaluation of melt extraction and refertilization processes in lithospheric mantle of the Tuva‐Mongolian massif

We determined the concentrations of platinum‐group elements (PGE) and rhenium in granular spinel lherzolites entrained as xenoliths in the Late Cenozoic volcanic rocks of the East Sayan within the Sarkhoi palaeo‐arc block of the Tuva‐Mongolian massif. Major element, PGE and rhenium variations in the East Sayan xenoliths can be explained by impregnation of up to 15% of arc‐type melt into initially depleted mantle harzburgite. Such a refertilization process probably took place in the Middle Neoproterozoic, when the Tuva‐Mongolian massif was in a subduction environment. East Sayan xenoliths show close similarities to Vitim xenoliths, whose host basalts erupted within an off‐cratonic crustal block. Both East Sayan and Vitim xenoliths are different from cratonic and circum‐cratonic peridotite xenoliths of worldwide localities.     

Geo-informational simulation of possible changes in Central Asian water resources

This study simulates water resources in the Tien Shan alpine basins to forecast how global and regional climate changes would affect river runoff. The model employed annual mean values for the major characteristics of the water cycle: annual air temperature, precipitation, evapotranspiration and river runoff. The simulation was based on 304 hydro-meteorological stations, 23 precipitation sites, 328 high altitudinal points with glaciological measurements, 123 stream-gauges, and 54 evaporation sites, and it took into account topography. The findings were simulated over Tien Shan relief using a 1:500,000 scale 100 m grid resolution Digital Elevation Model. An applicable GIS-based distributed River Runoff Model was implemented in regional conditions and tested in the Tien Shan basins. The annual evapotranspiration exceeds the river runoff in the Tien Shan watersheds particularly up to 3700 m. Hypothetical climate-change scenarios in the Tien Shan predict that by 2100 river runoff will increase by 1.047 times with an increase in air temperature averaging 3 °C and an increase in precipitation averaging 1.2 times the current levels. Change in precipitation, rather than temperature, is the main parameter determining river runoff in the Tien Shan. The maximum ratio for predicted river runoff could reach up to 2.2 and the minimum is predicted to be 0.55 times current levels. This possibly dramatic change in river runoff indicates on non-linear system response caused mainly by the non-linear response of evapotranspiration from air temperature and precipitation changes. In the frame of forecasted possible climate change scenarios the probability of river runoff growth amounts 83–87% and probability of this decline is 17–13% by 2100 in the Tien Shan River basins.     

δ53Cr values of catchment runoff exhibit seasonality regardless of bedrock Cr concentrations: Role of periodically changing chromium export fluxes

One pre-requisite for the construction of a global chromium isotope mass balance is detailed understanding of Cr isotope systematics in the critical zone where redox-processes can modify the isotope signature of geogenic Cr input into the hydrosphere. A Cr isotope inventory of bedrock, soil, and runoff was performed in a Central European headwater catchment underlain by amphibolite, situated in the vicinity of two previously studied catchments underlain by different bedrock types (serpentinite and leucogranite). Fresh bedrock in the amphibolite catchment NAZ contained ~300 mg/kg Cr, serpentinite at PLB contained ~800 mg/kg Cr, and leucogranite at LYS contained ~2 mg/kg Cr. Monthly hydrochemical monitoring at all three sites revealed higher Cr(VI) export fluxes in winter than in summer. NAZ was characterized by a distinct seasonality in the δ⁵³Cr values, with minima during winter/spring snowmelts (−0.35‰) and maxima during dry summers (0.40‰). Similar seasonality in δ⁵³Cr values had been reported from PLB and LYS. Bedrock at all three sites had similar Cr isotope composition close to −0.10‰, a value indistinguishable from the δ⁵³Cr value of bulk silicate Earth (BSE). Positive mean δ⁵³Cr value of NAZ runoff indicated Cr-isotope fractionations during weathering of geogenic Cr(III), combined with adsorption of the resulting Cr(VI) on soil particles during pedogenesis. However, the mass-weighted mean δ⁵³Cr of NAZ runoff was lower (−0.08‰), indistinguishable from the Cr isotope signature of bedrock. The same pattern of lower mass-weighted mean δ⁵³Cr values of runoff, compared to arithmetic mean δ⁵³Cr values of runoff, were observed also at PLB and LYS. We suggest that elevated Cr runoff fluxes in winter remove some of the residual isotopically light Cr that accumulated in the soil during summer. Seasonality in runoff δ⁵³Cr values appears to be a relatively widespread phenomenon, de-coupled from Cr availability for chemical weathering.     

Segmental closure of the Mongol-Okhotsk Ocean: Insight from detrital geochronology in the East Transbaikalia Basin

The Late Paleozoic–Early Mesozoic Mongol-Okhotsk Ocean extended between the Siberian and Amur–North China continents.The timing and modalities of the oceanic closure are widely discussed.It is largely accepted that the ocean closed in a scissor-like manner from southwest to northeast(in modern coordinates),though the timing of this process remains uncertain.Recent studies have shown that both western(West Transbaikalia)and eastern(Dzhagda)parts of the ocean closed almost simultaneously at the Early–Middle Jurassic boundary.However,little information on the key central part of the oceanic suture zone is available.We performed U-Pb(LA-ICP-MS)dating of detrital zircon from wellcharacterized stratigraphic sections of the central part of the Mongol-Okhotsk suture zone.These include the initial marine and final continental sequences of the East Transbaikalia Basin,deposited on the northern Argun-Idemeg terrane basement.We provide new stratigraphic ages for the marine and continental deposits.This revised chronostratigraphy allows assigning an age of~165–155 Ma,to the collisionrelated flexure of the northern Argun-Idemeg terrane and the development of a peripheral foreland basin.This collisional process took place 5 to10 million years later than in the western and eastern parts of the ocean.We demonstrate that the northern Argun-Idemeg terrane was the last block to collide with the Siberian continent,challenging the widely supported scissor-like model of closure of the MongolOkhotsk Ocean.Different segments of the ocean closed independently,depending on the initial shape of the paleo continental margins.     

Multi-proxy climate and environmental records from a Holocene eutrophic mire,southern taiga subzone,West Siberia

Palaeoenvironmental reconstructions from peat are strongly focused on ombrotrophic mires, but this study demonstrates that eutrophic mires can also be used. A multi-proxy approach was applied to a eutrophic mire on a floodplain terrace in the southern taiga of West Siberia. The results of the reconstruction were considered in the wide geographic context of the surrounding regions, including Siberia and Central Asia. Different palaeoecological proxies (analysis of plant macrofossils, testate amoebae, oribatid mites, molluscs, peat humification, ash content and spectral characteristics of humic acids) were used in this study. The results of different proxies showed a high level of consistency among themselves, which allowed for a robust interpretation of Holocene mire development. Throughout the ~7800 years history of the mire, there was a high level of surface wetness. The presence of mineral matter in the peat between 7800 and 5100 cal. a BP indicates regular flooding caused by the intensive fluvial activity, apparently resulting from increased precipitation. This was followed by a trend towards a gradual decrease in surface wetness from conditions of high surface moisture (stagnant water) between 5100 and 3000 cal. a BP to present day conditions of moderate surface moisture with a water table slightly below the mire surface. This pattern is consistent with the well-documented long-term trend from palaeoecological records throughout the taiga and arctic zones in West Siberia and central arid Asia. Our data further support the idea that the westerlies were the dominant driver of climate for the southern taiga of West Siberia during the Middle to Late Holocene.     

Construction and screening of a functional metagenomic library to identify novel enzymes produced by Antarctic bacteria

A metagenomic fosmid library of approximately 52 000 clones was constructed to identify functional genes encoding cold-adapted enzymes. Metagenomic DNA was extracted from a sample of glacial meltwater,...