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11.
Eiji Ohtani 《Earth and Planetary Science Letters》1984,67(2):261-272
The densities of silicate liquids with basic, picritic, and ultrabasic compositions have been estimated from the melting curves of minerals at high pressures. Silicate liquids generated by partial melting of the upper mantle are denser than olivine and pyroxenes at pressures higher than 70 kbar, and garnet is the only phase which is denser than the liquid at pressures from 70 kbar to at least 170 kbar. In this pressure range, garnet and some fraction of liquid separate from ascending partially molten diapirs. It is therefore suggested that aluminium-depleted komatiite with a high Ca/OAl2O3 ratio may be derived from diapirs which originated in the deep upper mantle at pressures from 70 kbar to at least 140 kbar (200–400 km in depth), where selective separation of pyropic garnet occurs effectively. On the other hand, aluminium-undepleted komatiite is probably derived from diapirs originating at shallower depths (< 200 km). Enrichment of pyropic garnet is expected at depths greater than 200 km by selective separation of garnet from ascending diapirs. The 200-km discontinuity in the seismic wave velocity profile may be explained by a relatively high concentration of pyropic garnet at depths greater than 200 km. 相似文献
12.
Experiments on the solubility of FeO in molten iron have been carried out at temperatures between 2100 and 2550°C. The results show that liquid FeO is extensively soluble in molten iron at 2500°C and indicate that they probably become completely miscible above 2800°C. Liquid iron in equilibrium with crystalline magnesiowüstite (Mg0.8Fe0.2)O which is believed to be an important mineral in the lower mantle, would dissolve about 14 mol.% of FeO at 2500°C and 40 mol.% of FeO at 2800°C. The geochemical implications of these results are discussed. It is concluded that the outer core probably contains a large amount of dissolved FeO and that oxygen is probably the principal light element in the outer core. 相似文献
13.
Application of an infrared carbon dioxide and humidity instrument to studies of turbulent transport 总被引:4,自引:0,他引:4
Eiji Ohtaki 《Boundary-Layer Meteorology》1984,29(1):85-107
A calibration equation and some results of the field performance of an infrared instrument, which is designed to measure simultaneous fluctuations of atmospheric carbon dioxide and water vapor, are described. Field observations show that the instrument is suitable for simultaneous measurement of turbulent fluxes of carbon dioxide and water vapor in conjunction with a sonic anemometer. Measured values of carbon dioxide and water vapor fluxes show diurnal variations characterized by crop activity with respect to assimilation, respiration and evapotranspiration. Carbon dioxide is transferred downward during the daytime and upward at night, while latent heat and sensible heat are transferred in the opposite sense. The non-dimensional gradient of carbon dioxide is expressed in the following form under weak unstable conditions:
c
= (1 – 16
v
)-1/2. Here,
v
is the Monin-Obukhov stability parameter including the humidity effect. This relation was originally proposed for temperature and humidity. Thus, the results indicate that the turbulent mechanisms of carbon dioxide fluctuations are similar to those of other scalar entities. This is strongly supported by the high correlation coefficient found between fluctuations of carbon dioxide and temperature or humidity in the air layer over crop fields. 相似文献
14.
Eiji Ohtaki 《Boundary-Layer Meteorology》1980,19(3):315-336
Turbulent fluctuations in CO2 concentrations over a paddy field are measured by a fastresponse device with an open sensing path. This IR device coupled with a sonic anemometer constitutes an eddy correlation instrument to measure CO2 fluxes. Three experiments were conducted in the surface layer over paddy 90 cm high. The stability (z – d)/L ranged from -0.14 to 0.20, where L denotes the Monin-Obukhov length.CO2 power spectra show the range of applicability of the -2/3 power law to be between f = 0.2 and f = 2, where f is the frequency normalized by wind speed and height. The cospectral estimate between CO2 and vertical component of wind speed ranging from f = 0.005 to f = 2 shows a peak at about f = 0.15 under near-neutral stratification.Hourly means of CO2 flux measured by the eddy correlation method increase with intensity of net radiation. The maximum value of downward flux of CO2 rises to 0.6 mg cm-2 hr-1 over the paddy field at the stage of ear emergence.Some turbulence statistics relating to the CO2 transport are evaluated: the correlation coefficient between CO2 and vertical velocity is about -0.3, and that between CO2 and humidity attains -0.7 ~ -0.8 under unstable stratification; nondimensional gradients c for CO2 and m for wind speed are 0.89 and 0.99, respectively. 相似文献
15.
16.
The Iwami epithermal silver deposit consists of Ag-Cu veins in a dacitic intrusive body at the deep portion of the Eikyu area, and veinlets with disseminated Ag mineralization in dacitic tuff breccia at a shallow portion of the Fukuishi area. Hydrothermal alteration associated with the silver mineralization is characterized by intense potassium metasomatism with oxidizing conditions. An illite zone occurs around the pathways of uprising fluids in both the Eikyu and Fukuishi areas. It grades laterally into the illite/smectite zone, which is surrounded by a broad smectite zone. Because of boiling, abundant adularia associated with silver mineralization overlaps on the altered tuff breccia in the Fukuishi area. The alteration zoning suggests that the western Eikyu area and the eastern Fukuishi area belong to a single hydrothermal system. The data of fluid inclusion microthermometry indicate that the temperatures range 220–270°C, and salinities range 5–7 wt percent NaCl equivalent for the silver mineralization at the upper portion in the Eikyu area and the lower portion in the Fukuishi area. Radiometric ages for volcanic rocks in the area range from 2.19 to 1.64 Ma, and the dacitic intrusion formed at approximately 1.6 Ma. The silver-dominant mineralizing hydrothermal fluids system was active around 1.44 to 1.07 Ma, which formed the Eikyu Ag-Cu veins at depth, and the Fukuishi Ag ores at the shallower portion. 相似文献
17.
Origin of EL3 chondrites: Evidence for variable C/O ratios during their course of formation—A state of the art scrutiny 下载免费PDF全文
A. El Goresy Y. Lin M. Miyahara A. Gannoun M. Boyet E. Ohtani P. Gillet M. Trieloff A. Simionovici L. Feng L. Lemelle 《Meteoritics & planetary science》2017,52(5):781-806
Mineral inventories of enstatite chondrites; (EH and EL) are strictly dictated by combined parameters mainly very low dual oxygen (fO2) and sulfur (fS2) fugacities. They are best preserved in the Almahata Sitta MS‐17, MS‐177 fragments, and the ALHA 77295 and MAC 88136 Antarctic meteorites. These conditions induce a stark change of the geochemical behavior of nominally lithophile elements to chalcophile or even siderophile and changes in the elemental partitioning thus leading to formation of unusual mineral assemblages with high abundance of exotic sulfide species and enrichment in the metallic alloys, for example, silicides and phosphides. Origin and mode of formation of these exotic chondrites, and their parental source regions could be best scrutinized by multitask research experiments of the most primitive members covering mineralogical, petrological, cosmochemical, and indispensably short‐lived isotopic chronology. The magnitude of temperature and pressure prevailed during their formation in their source regions could eventually be reasonably estimated: pre‐ and postaccretionary could eventually be deduced. The dual low fugacities are regulated by the carbon to oxygen ratios estimated to be >0.83 and <1.03. These parameters not only induce unusual geochemical behavior of the elements inverting many nominally lithophile elements to chalcophile or even siderophile or anthracophile. Structure and mineral inventories in EL3 and EH3 chondrites are fundamentally different. Yet EH3 and EL3 members store crucial information relevant to eventual source regions and importantly possible variation in C/O ratio in the course of their evolution. EL3 and EH3 chondrites contain trichotomous lithologies (1) chondrules and their fragments, (2) polygonal enstatite‐dominated objects, and (3) multiphase metal‐rich nodules. Mineralogical and cosmochemical inventories of lithologies in the same EL3 indicate not only similarities (REE inventory and anomalies in oldhamite) but also distinct differences (sinoite‐enstatite‐graphite relationship). Oldhamite in chondrules and polygonal fragments in EL3 depict negative Eu anomaly attesting a common cosmochemical source. Metal‐dominated nodules in both EL3 and EH3 are conglomerates of metal clasts and sulfide fragments in EH3 and concentrically zoned C‐bearing metal micropebbles (≥25 μm ≤50 μm) in EL3 thus manifesting a frozen in unique primordial accretionary metal texture and composition. Sinoite‐enstatite‐diopside‐graphite textures reveal a nucleation and growth strongly suggestive of fluctuating C/O ratio during their nucleation and growth in the source regions. Mineral inventories, sulfide phase relations, sinoite‐enstatite‐graphite intergrowth, carbon and nitrogen isotopic compositions of graphite, spatial nitrogen abundance in graphite in metal nodules, and last but not least 129I/129Xe and 53Mn/53Cr systematics negate any previously suggested melting episode, pre‐accretionary or dynamic, in parental asteroids. 相似文献
18.
Seismic observations have shown structural variation near the base of the mantle transition zone(MTZ)where subducted cold slabs,as visualized with high seismic speed anomalies(HSSAs),flatten to form stagnant slabs or sink further into the lower mantle.The different slab behaviors were also accompanied by variation of the "660 km" discontinuity depths and low viscosity layers(LVLs) beneath the MTZ that are suggested by geoid inversion studies.We address that deep water transport by subducted slabs and dehydration from hydrous slabs could affect the physical properties of mantle minerals and govern slab dynamics.A systematic series of three-dimensional numerical simulation has been conducted to examine the effects of viscosity reduction or contrast between slab materials on slab behaviors near the base of the MTZ.We found that the viscosity reduction of subducted crustal material leads to a separation of crustal material from the slab main body and its transient stagnation in the MTZ.The once trapped crustal materials in the MTZ eventually sink into the lower mantle within 20-30 My from the start of the plate subduction.The results suggest crustal material recycle in the whole mantle that is consistent with evidence from mantle geochemistry as opposed to a two-layer mantle convection model.Because of the smaller capacity of water content in lower mantle minerals than in MTZ minerals,dehydration should occur at the phase transformation depth,~660 km.The variation of the discontinuity depths and highly localized low seismic speed anomaly(LSSA) zones observed from seismic P waveforms in a relatively high frequency band(~1 Hz) support the hypothesis of dehydration from hydrous slabs at the phase boundary.The LSSAs which correspond to dehydration induced fluids are likely to be very local,given very small hydrogen(H~+) diffusivity associated with subducted slabs.The image of such local LSSA zones embedded in HSSAs may not be necessarily captured in tomography studies.The high electrical conductivity in the MTZ beneath the northwestern Pacific subduction zone does not necessarily require a broad range of high water content homogeneously. 相似文献
19.
Yangting Lin Ahmed El Goresy Sen Hu Jianchao Zhang Philippe Gillet Yuchen Xu Jialong Hao Masaaki Miyahara Ziyuan Ouyang Eiji Ohtani Lin Xu Wei Yang Lu Feng Xuchao Zhao Jing Yang Shin Ozawa 《Meteoritics & planetary science》2014,49(12):2201-2218
Two petrographic settings of carbonaceous components, mainly filling open fractures and occasionally enclosed in shock‐melt veins, were found in the recently fallen Tissint Martian meteorite. The presence in shock‐melt veins and the deuterium enrichments (δD up to +1183‰) of these components clearly indicate a pristine Martian origin. The carbonaceous components are kerogen‐like, based on micro‐Raman spectra and multielemental ratios, and were probably deposited from fluids in shock‐induced fractures in the parent rock of Tissint. After precipitation of the organic matter, the rock experienced another severe shock event, producing the melt veins that encapsulated a part of the organic matter. The C isotopic compositions of the organic matter (δ13C = ?12.8 to ?33.1‰) are significantly lighter than Martian atmospheric CO2 and carbonate, providing a tantalizing hint for a possible biotic process. Alternatively, the organic matter could be derived from carbonaceous chondrites, as insoluble organic matter from the latter has similar chemical and isotopic compositions. The presence of organic‐rich fluids that infiltrated rocks near the surface of Mars has significant implications for the study of Martian paleoenvironment and perhaps to search for possible ancient biological activities on Mars. 相似文献
20.
Hiromi Hayashi Eiji Ohtani Hidenori Terasaki Yoshinori Ito 《Geochimica et cosmochimica acta》2009,73(16):4836-4475
Coupled 186Os/188Os and 187Os/188Os enrichments of plume-derived lavas have been suggested to reflect contributions of materials from the outer core (Brandon et al., 1998). This hypothesis is based on the assumption that the Earth’s liquid outer core has high Pt/Os and slightly high Re/Os ratios as a result of the crystallization of the solid inner core, and shows coupled enrichments in the 186Os/188Os and 187Os/188Os ratios, reflecting the decay of 190Pt and 187Re to 186Os and 187Os, respectively. Partitioning experiments of Pt-Re-Os between solid and liquid metal were performed at 5-20 GPa and 1250-1400 °C, to examine the effects of pressure in the Fe-Ni-S system. The ratios (DOs/DPt, DOs/DRe) of measured partition coefficients of Pt, Re and Os are almost constant with increasing pressure. DOs/DPt increases significantly, whereas DOs/DRe decreases, with increasing sulphur content in the liquid metal. On the basis of the present experimental results, it is unlikely that the required Pt-Re-Os fractionation is generated during inner core crystallization, assuming that the light element in the Earth’s core is sulphur. 相似文献