DInSAR analysis of ALOS PALSAR images for the assessment of very slow landslides: the Tena Valley case study

In this work we analyse the performance of advanced land observing satellite (ALOS) phased array type L-band syntetic aperture radar (PALSAR) images for mapping and monitoring of very slow landslides using conventional differential interferometry in the Tena Valley (Central Pyrenees, Spain). These results are compared with those retrieved in previous works where multi-band advanced differential interferometric synthetic aperture radar (DInSAR) analysis was performed for the same area using PSI techniques. The study area is largely underlain by slates (ca. 80 %) where large deep-seated very slow earth flows are dominant. The results reveal that DInSAR analysis is able to measure displacements of landslides with a greater spatial coverage than PSI analysis, but for a lower amount of them (nine against 51). Overall, the combination of the DInSAR and multi-band PSI analysis permitted to map and monitor 68 % of the landslides in Tena Valley. From this amount, 63 landslides are considered as active. The main advantage of DInSAR with respect to PSI analysis is the capability to detect faster movements (up to 145 cm?year^?1) derived from the 46 days interferograms. That is the case of Sextas and La Selva landslides where an acceleration of the moving mass was measured after intense rainfall periods producing major damages to linear infrastructures. The combination of measured displacement from ALOS interferograms, with the observed damages on the A-136 road, was useful to assess the potential damage that could cause these slow movements. In general, it is demonstrated that even though PSI analysis provides a better performance in terms of landslide mapping, L-band DInSAR analysis provides an added value for landslide hazard assessment through radar remote sensing. For this reason it is necessary to encourage the launch of new satellite missions similar to ALOS PALSAR that could operate with shorter revisiting time periods.     

Determination of Fe<Superscript>3+</Superscript>/ΣFe ratios in chrome spinels using a combined Mössbauer and single-crystal X-ray approach: application to chromitites from the mantle section of the Oman ophiolite

We present the results of a comparative study in which we have measured Fe³⁺/ΣFe ratios in chromites from mantle chromitites in the Oman ophiolite using Mössbauer spectroscopy and single-crystal X-ray diffraction. We have compared these results with ratios calculated from mineral stoichiometry and find that mineral stoichiometry calculations do not accurately reflect the measured Fe³⁺/ΣFe ratios. We have identified three groups of samples. The majority preserve Fe³⁺/ΣFe ratios which are thought to be magmatic, whereas a few samples are highly oxidized and have high Fe³⁺/ΣFe ratios. There is also a group of partially oxidized samples. The oxidized chromites show anomalously low cell edge (a ₀) values and their oxygen positional parameters among the lowest ever found for chromites. Site occupancy calculations show that some chromites are non-stoichiometric and contain vacancies in their structure randomly distributed between both the T and M sites. The field relationships suggest that the oxidation of the magmatic chromitites took place in association with a ductile shear zone in mantle harzburgites. Primary magmatic Fe³⁺/ΣFe ratios measured for the Oman mantle chromitites are between 0.193–0.285 (X-ray data) and 0.164–0.270 (Mössbauer data) and preserve a range of Fe³⁺/ΣFe ratios which we propose is real and reflects differences in the composition of the magmas parental to the chromitites. The range of values extends from those MORB melts (0.16 ± 0.1) to those for arc basalts (0.22–0.28).     

Magmatism and fenitization in the Cretaceous potassium-alkaline-carbonatitic complex of Ipanema S?o Paulo State, Brazil

The Ipanema alkaline-carbonatitic complex is part of the Meso-Cenozoic alkaline magmatism located within the southeastern part of the Brazilian Platform. Drill-core and field sampling have indicated the occurrence of glimmerites, with subordinate shonkinites (mela-syenites), clinopyroxene-bearing glimmerites, diorites and syenites. The glimmerites are cross-cut by lamprophyric dykes and calciocarbonatites. Fenitization has deeply affected the country rocks, originating dioritic and syenitic rocks. The Ipanema rocks show a distinct potassic affinity. The initial Sr-Nd- isotopic composition of the Ipanema rocks (⁸⁷Sr/⁸⁶Sr?=?0.70661–0.70754 and ¹⁴³Nd/¹⁴⁴Nd?=?0.51169–0.51181) is similar to that of tholeiitic and potassium-rich-alkaline rocks of the Eastern Paraguay. Stable isotope data for the Ipanema calciocarbonatite suggest interaction with fluids at temperatures typical of hydrothermal stages, as hypothesized for other carbonatite complexes from southeastern Brazil. The chemical differences between the lamprophyre, glimmerites, carbonatites, apatitites and magnetitites, and the absence of marked REE enrichment in the evolved lithologies, all indicate that fractional crystallization and accumulus of liquidus phases in a magma reservoir, likely coupled with liquid immiscibility processes, may have played an important role in the genesis of the Ipanema rocks.     

Raman study of MgCr2O4–Fe2+Cr2O4 and MgCr2O4–MgFe2 3+O4 synthetic series: the effects of Fe2+ and Fe3+ on Raman shifts

Two synthetic series of spinels, MgCr₂O₄–Fe²⁺Cr₂O₄ and MgCr₂O₄–MgFe₂ ³⁺O₄ have been studied by Raman spectroscopy to investigate the effects of Fe²⁺ and Fe³⁺ on their structure. In the first case, where Fe²⁺ substitutes Mg within the tetrahedral site, there is a continuous and monotonic shift of the Raman modes A_1g and E_g toward lower wavenumbers with the increase of the chromite component into the spinel, while the F_2g modes remain nearly in the same position. In the second series, for low Mg-ferrite content, Fe³⁺ substitutes for Cr in the octahedral site; when the Mg-ferrite content nears 40 %, a drastic change in the Raman spectra occurs as Fe³⁺ starts entering the tetrahedral site as well, consequently pushing Mg to occupy the octahedral one. The Raman spectral region between 620 and 700 cm^?1 is associated to the octahedral site, where three peaks are present and it is possible to observe the Cr–Fe³⁺ substitution and the effects of order–disorder in the tetrahedral site. The spectral range at 500–620 cm^?1 region shows that there is a shift of modes toward lower values with the increase of the Mg-ferrite content. The peaks in the region at 200–500 cm^?1, when observed, show little or negligible Raman shift.     

Eo-Alpine HP metamorphism in the Permian intrusives from the steep belt of the central Alps (Languard-Campo nappe and Tonale Series)

Abstract

Diorites and granitoids that intruded the Upper Austroalpine units of the central Alps during the Permian display map-pable tectonic imprints and metamorphic transformations that were acquired during the Alpine tectonometamorphic cycle. Superposed heterogeneous deformations interacted with metamorphic re-equilibration stages and created a range of textural types that reflect local deformation gradients: coronitic transformations textures, normally foliated S-tectonites and mylonitic foliations. The three textural types are distinguished on maps recording foliation trajectories of successive deformation phases, which are correlated to the evolution of metamorphic assemblages. Tectonic deformation of Alpine age is represented by three generations of ductile syn-metamorphic structures. The mineral assemblages stable during the first Alpine deformation phase (D1) are Amp_II + P1_II + white mica, + Zo/Czo + Grt + Qtz ± Mg-Ch1 ± Ilm in metadiorites and P1_II + white mica_I + Zo/Czo + Grt + Amp_II + Qtz ± Ilm/Ttn in metagranitoids; the successive foliations D2a and D2b are defined by greenschist facies minerals. Thermobarometric estimates allow T = 500–600 °C and P = 1.1 ± 0.2 GPa conditions to be determined during D1 and T ≤ 350 °C and P ≤ 0.5 GPa during D2. Relict igneous minerals in metadiorites allow to determine intrusive conditions of T = 879 ± 110 °C and P = 0.4–0.7 GPa. Radiometric ages and P/T ratio of Alpine P_maxT_Pmax suggest that the inferred P-T-d-t path may represent the thermal state of the initial Alpine subduction stages. © 2000 Éditions scientifiques et médicales Elsevier SAS     

Influence of rainfall and soil properties spatial aggregation on extreme flash flood response modelling: An evaluation based on the Sesia river basin,North Western Italy

High resolution radar rainfall fields and a distributed hydrologic model are used to evaluate the sensitivity of flood and flash flood simulations to spatial aggregation of rainfall and soil properties at catchment scales ranging from 75 to 983 km². Hydrologic modeling is based on a Hortonian infiltration model and a network-based representation of hillslope and channel flow. The investigation focuses on three extreme flood and flash flood events occurred on the Sesia river basin, North Western Italy, which are analysed by using four aggregation lengths ranging from 1 to 16 km. The influence of rainfall spatial aggregation is examined by using the flow distance as a spatial coordinate, hence emphasising the role of river network in the averaging of space–time rainfall. The effects of reduced and distorted rainfall spatial variability on peak discharge have been found particularly severe for the flash flood events, with peak errors up to 35% for rainfall aggregation of 16 km and at 983 km² catchment size. Effects are particularly remarkable when significant structured rainfall variability combines with relatively important infiltration volumes due to dry initial conditions, as this emphasises the non-linear character of the rainfall–runoff relationship. In general, these results confirm that the correct estimate of rainfall volume is not enough for the accurate reproduction of flash flood events characterised by large and structured rainfall spatial variability, even at catchment scales around 250 km². However, accurate rainfall volume estimation may suffice for less spatially variable flood events. Increasing the soil properties aggregation length exerts similar effects on peak discharge errors as increasing the rainfall aggregation length, for the cases considered here and after rescaling to preserve the rainfall volume. Moreover, peak discharge errors are roughly proportional to runoff volume errors, which indicates that the shape of the flood wave is influenced in a limited way by modifying the detail of the soil property spatial representation. Conversely, rainfall aggregation may exert a pronounced influence on the discharge peak by reshaping the spatial organisation of the runoff volumes and without a comparable impact on the runoff volumes.