A TEM study of exsolution in Ca-rich pyroxenes from the Paris and Renazzo chondrites: Determination of type I chondrule cooling rates

We conducted a transmission electron microscope study of the exsolution microstructures of Ca-rich pyroxenes in type I chondrules from the Paris CM and Renazzo CR carbonaceous chondrites in order to provide better constraints on the cooling history of type I chondrules. Our study shows a high variability of composition in the augite grains at a submicrometer scale, reflecting nonequilibrium crystallization. The microstructure is closely related to the local composition and is thus variable inside augite grains. For compositions inside the pyroxene miscibility gap, with a wollastonite (Wo) content typically below 40 mole%, the augite grains contain abundant exsolution lamellae on (001). For grain areas with composition close to Wo₄₀, a modulated texture on (100) and (001) is the dominant microstructure, while areas with compositions higher than Wo₄₀ do not show any exsolution microstructure development. To estimate the cooling rate, we used the spacing of the exsolution lamellae on (001), for which the growth is diffusion controlled and thus sensitive to the cooling rate. Despite the relatively homogeneous microstructures of augite grains with Wo < 35 mole%, our study of four chondrules suggests a range of cooling rates from ~10 to ~1000 °C h⁻¹, within the temperature interval 1200–1350 °C. These cooling rates are comparable to those of type II chondrules, i.e., 1–1000 °C h⁻¹. We conclude that the formation of type I and II chondrules in the proto-solar nebula was the result of a common mechanism.     

Holocene history of fire,vegetation and land use from the central Pyrenees (France)

Located on a mountain pass in the west-central Pyrenees, the Col d'Ech peat bog provides a Holocene fire and vegetation record based upon nine ¹⁴C (AMS) dates. We aim to compare climate-driven versus human-driven fire regimes in terms of frequency, fire episodes distribution, and impact on vegetation. Our results show the mid-Holocene (8500–5500 cal yr BP) to be characterized by high fire frequency linked with drier and warmer conditions. However, fire occurrences appear to have been rather stochastic as underlined by a scattered chronological distribution. Wetter and colder conditions at the mid-to-late Holocene transition (4000–3000 cal yr BP) led to a decrease in fire frequency, probably driven by both climate and a subsequent reduction in human land use. On the contrary, from 3000 cal yr BP, fire frequency seems to be driven by agro-pastoral activities with a very regular distribution of events. During this period fire was used as a prominent agent of landscape management.     

Geomorphologic evidence for Plio‐Quaternary shortening in the southern Neuquén basin (40°S,Argentina)

A morphostructural analysis of a Pliocene flood basalt formation in the southern Neuquén basin (40°S) shows evidence of contractional deformation less than 3.5 Ma ago. This formation exhibits a general dip towards the south‐east, with relict outcrops located 100 m higher than the main source volcano, which suggests a local tilting of the lava flow. This tilt has been brought about by Plio‐Quaternary reactivation of the eastern border of the Sañico Massif along two thrusts that offset the lava flow. Another long‐wavelength bulge in the southern part of the lava flow unit indicates a possible Pliocene uplift of the North Patagonian Massif. These results provide new evidence of continuing shortening in the Neuquén basin during the Plio‐Quaternary, challenging the hypothesis that an extensional regime has existed since the end of the Miocene in this basin.     

Relationship between valve activity, microalgae concentration in the water and toxin accumulation in the digestive gland of the Pacific oyster Crassostrea gigas exposed to Alexandrium minutum

The complexity of the relationships between Alexandrium minutum (A.m.) concentration in the water ([A.m.]_w), Paralytic Shellfish Poisoning contamination in the digestive gland ([PSP]_dg) and valve behavior was explored in oysters Crassostrea gigas. Two experiments were conducted, during which oysters’ valve behaviour were analyzed. Oysters, first acclimated for 10-days with the non harmful microalgae Heterocapsa triquetra (H.t.), were exposed to four microalgae mixtures at constant total concentrations of 10 × 10³ cells ml⁻¹ (experiment-1) and 5 × 10³ cells ml⁻¹ (experiment-2): 100% A.m.; 50% A.m.-50% H.t.; 25% A.m.-75% H.t.; 100% H.t. At the end of experiment-2, [PSP]_dg were measured.At 10 × 10³ cells ml⁻¹, the microalgal ingestion decreased (p < 0.05) with increasing [A.m.]_w but not at 5 × 10³ cells ml⁻¹ (p > 0.05). The frequency of microclosures specifically increased with [A.m.]_w (p < 0.05) and the opening duration with [PSP]_dg (p < 0.0001). Oysters exhibiting the maximum increase in opening duration also exhibited the highest [PSP]_dg. The results are discussed in terms of oyster physiology and origin of the behavioral response.     

Using short-lived nuclides of the U- and Th-series to probe the kinetics of colloid migration in forested soils

The recent chemical dynamics of a podzolic forest soil section (from the Strengbach watershed, France) was investigated using U- and Th-series nuclides. Analyses of (²³⁸U), (²³⁰Th), (²²⁶Ra), (²³²Th), (²²⁸Ra) and (²²⁸Th) activities in the soil particles, the seepage waters, and the mature leaves of the beech trees growing on this soil were performed by TIMS or gamma spectrometry. The simultaneous analysis of the different soil (sl) compartments allows to demonstrate that a preferential Th leaching over Ra must be assumed to explain the (²²⁶Ra/²³⁰Th), (²²⁸Ra/²³²Th) and (²²⁸Th/²²⁸Ra) disequilibria recorded in the soil particles. The overall Ra- and Th- transfer schemes are entirely consistent with the prevailing acido-complexolysis weathering mechanism in podzols. Using a continuous open-system leaching model, the (²²⁶Ra/²³⁰Th) and (²²⁸Ra/²³²Th) disequilibria measured in the different soil layers enable dating of the contemporary processes occurring in this soil. In this way, we have determined that a preferential Th-leaching from the shallow Ah horizon, due to a strong complexation with organic colloids, began fairly recently (18 years ago at most). The continual increase in pH recorded in precipitations over the last 20 years is assumed to be the cause of this enhanced organic complexation. A lower soil horizon (50-60 cm) is also affected by preferential Th leaching, though lasting over several centuries at least, with a much smaller leaching rate. The migration of Th isotopes through this soil section might hence be used as a tracer for the organic colloids migration and the induced radioactive disequilibria demonstrate to be useful for assessing the colloidal migration kinetics in a forested soil.Ra and Th isotopic ratios also appear to be valuable tracers of some mineral-water-plant interactions occurring in soil. The (²²⁸Ra/²²⁶Ra) ratio enables discrimination of the Ra flux originating from leaf degradation from that originating from mineral weathering in shallow −10 cm seepage soil waters. It appears that, at least in some cases, the Ra-isotopic ratio measured in forest-soil seepage waters may not be representative of the Ra-isotopic ratio released from mineral weathering, indicating that the different origins of the dissolved ²²⁶Ra and ²²⁸Ra must be taken into account.     

Use of micro-XRF chemical analysis for mapping volcanogenic massive sulfide related hydrothermal alteration: Application to the subaqueous felsic dome-flow complex of the Cap d'Ours section,Glenwood rhyolite,Rouyn-Noranda,Québec,Canada

A new analytical method using micro-X-ray fluorescence (XRF) is presented for the in situ analysis of major elements in rock samples. This approach has allowed for a separate study of hydrothermal alteration of matrix versus fragments in volcaniclastic material (i.e. flow breccia). This is particularly important for volcanogenic massive sulfide (VMS) exploration in subaqueous felsic dome-flow complexes, where brecciated facies are omnipresent and the imprint of hydrothermal alteration is typically heterogeneous. In this study, eleven elements are measured with a 1.7 by 1.3 mm window considered to be representative of each sample, based on replicate analyses. An average is calculated for the analyzed window and yields a nearly complete analysis with the exception of loss of ignition (LOI). Micro-XRF data were validated using whole rock XRF analyses performed on the same sample block. The application of this chemical method has been tested successfully on thin sections from the Cap d'Ours section of the Glenwood rhyolite in the Rouyn-Noranda region of Québec, Canada. With 58 samples spaced at approximately 50 m intervals, two styles of alteration zoning were recognized: (1) a lateral and concordant zoning expressed by vent-proximal silicification in the west grading toward vent-distal chlorite–sericite alteration to the east, and (2) vertical and discordant zoning expressed by stronger sericitization in the upper part of later volcanic quartz- and feldspar-phyric endogenous lobes. The former is typical of cooling induced by seawater interaction at the lava–water interface at temperatures greater than 400 °C, whereas the latter is related to lower temperature (< 300 °C) hydrothermal mineralization associated with endogenous lobe emplacement within the volcanic pile. The presented results clearly demonstrate the potential use of the micro-XRF data for characterizing weak to intense hydrothermal alteration in highly fragmented volcanic rocks.     

Determination of chemical weathering rates from U series nuclides in soils and weathering profiles: Principles,applications and limitations

The development of U-series nuclides for investigating weathering processes has been significantly stimulated by the analytical improvement made over the last decades in measuring the ²³⁸U series with intermediate half-lives (i.e., ²³⁴U–²³⁰Th–²²⁶Ra). It is proposed in this paper to present principles and methods that are now being developed to determine weathering rates from the study of U-series nuclides in soils and weathering profiles. Mathematical approaches, developed to calculate such rates, are based on some implicit assumptions that are also presented and must be kept in mind if one wants to correctly interpret the obtained ages.     

Carbon and oxygen stable isotope compositions of late Pleistocene mammal teeth from dolines of Ajoie (Northwestern Switzerland)

Fossils of megaherbivores from eight late Pleistocene ¹⁴C- and OSL-dated doline infillings of Ajoie (NW Switzerland) were discovered along the Transjurane highway in the Swiss Jura. Carbon and oxygen analyses of enamel were performed on forty-six teeth of large mammals (Equus germanicus, Mammuthus primigenius, Coelodonta antiquitatis, and Bison priscus), coming from one doline in Boncourt (~ 80 ka, marine oxygen isotope stage MIS5a) and seven in Courtedoux (51–27 ka, late MIS3), in order to reconstruct the paleoclimatic and paleoenvironmental conditions of the region. Similar enamel δ¹³C values for both periods, ranging from − 14.5 to − 9.2‰, indicate that the megaherbivores lived in a C₃ plant-dominated environment. Enamel δ¹⁸O_PO4 values range from 10.9 to 16.3‰ with a mean of 13.5 ± 1.0‰ (n = 46). Mean air temperatures (MATs) were inferred using species-specific δ¹⁸O_PO4–δ¹⁸O_H2O-calibrations for modern mammals and a present-day precipitation δ¹⁸O_H2O-MAT relation for Switzerland. Similar average MATs of 6.6 ± 3.6°C for the deposits dated to ~ 80 ka and 6.5 ± 3.3°C for those dated to the interval 51–27 ka were estimated. This suggests that these mammals in the Ajoie area lived in mild periods of the late Pleistocene with MATs only about 2.5°C lower than modern-day temperatures.     

Insight into the development of a carbonate platform through a multi-disciplinary approach: a case study from the Upper Devonian slope deposits of Mount Freikofel (Carnic Alps,Austria/Italy)

The development and behavior of million year-scaled depositional sequences recorded within Palaeozoic carbonate platform has remained poorly examined. Therefore, the understanding of palaeoenvironmental changes that occur in geological past is still limited. We herein undertake a multi-disciplinary approach (sedimentology, conodont biostratigraphy, magnetic susceptibility (MS), and geochemistry) of a long-term succession in the Carnic Alps, which offers new insights into the peculiar evolution of one of the best example of Palaeozoic carbonate platform in Europe. The Freikofel section, located in the central part of the Carnic Alps, represents an outstanding succession in a fore-reef setting, extending from the Latest Givetian (indet. falsiovalis conodont zones) to the Early Famennian (Lower crepida conodont zone). Sedimentological analysis allowed to propose a sedimentary model dominated by distal slope and fore-reef-slope deposits. The most distal setting is characterized by an autochthonous pelagic sedimentation showing local occurrence of thin-bedded turbiditic deposits. In the fore-reef slope, in a more proximal setting, there is an accumulation of various autochthonous and allochthonous fine- to coarse-grained sediments originated from the interplay of gravity-flow currents derived from the shallow-water and deepwater area. The temporal evolution of microfacies in the Freikofel section evolves in two main steps corresponding to the Freikofel (Unit 1) and the Pal (Unit 2) limestones. Distal slope to fore-reef lithologies and associate changes are from base to top of the section: (U1) thick bedded litho- and bioclastic breccia beds with local fining upward sequence and fine-grained mudstone intercalations corresponding, in the fore-reef setting, to the dismantlement of the Eifelian–Frasnian carbonate platform during the Early to Late Frasnian time (falsiovalis to rhenana superzones) with one of the causes being the Late Givetian major rift pulse; (U2) occurrence of thin-bedded red nodular and cephalopod-bearing limestones with local lithoclastic grainstone intercalations corresponding to a significant deepening of the area and the progressive withdrawal of sedimentary influxes toward the basin, in relation with Late Frasnian sea-level rise. MS and geochemical analyses were also performed along the Freikofel section and demonstrate the inherent parallel link existing between variation in MS values and proxy for terrestrial input. Interpretation of MS in terms of palaeoenvironmental processes reflects that even though distality remains the major parameter influencing MS values, carbonate production and water agitation also play an important role.