Holocene paleoenvironmental change inferred from two sediment cores collected in the Tibetan lake Taro Co

Journal of Paleolimnology - The Tibetan Plateau, also known as the “Water Tower of Asia” because of its function as a water storage and supply region, responds dramatically to modern...     

Oxygen isotope systematics of gem corundum deposits in Madagascar: relevance for their geological origin

The oxygen isotopic composition of gem corundum was measured from 22 deposits and occurrences in Madagascar to provide a gemstone geological identification and characterization. Primary corundum deposits in Madagascar are hosted in magmatic (syenite and alkali basalt) and metamorphic rocks (gneiss, cordieritite, mafic and ultramafic rocks, marble, and calc-silicate rocks). In both domains the circulation of fluids, especially along shear zones for metamorphic deposits, provoked in situ transformation of the corundum host rocks with the formation of metasomatites such as phlogopite, sakenite, and corundumite. Secondary deposits (placers) are the most important economically and are contained in detrital basins and karsts. The oxygen isotopic ratios (¹⁸O/¹⁶O) of ruby and sapphire from primary deposits are a good indicator of their geological origin and reveal a wide range of δ¹⁸O (Vienna Standard Mean Ocean Water) between 1.3 and 15.6‰. Metamorphic rubies are defined by two groups of δ¹⁸O values in the range of 1.7 to 2.9‰ (cordieritite) and 3.8 to 6.1‰ (amphibolite). “Magmatic” rubies from pyroxenitic xenoliths contained in the alkali basalt of Soamiakatra have δ¹⁸O values ranging between 1.3 and 4.7‰. Sapphires are classified into two main groups with δ¹⁸O in the range of 4.7 to 9.0‰ (pyroxenite and feldspathic gneiss) and 10.7 to 15.6‰ (skarn in marble from Andranondambo). The δ¹⁸O values for gem corundum from secondary deposits have a wide spread between −0.3 and 16.5‰. The ruby and sapphire found in placers linked to alkali basalt environments in the northern and central regions of Madagascar have consistent δ¹⁸O values between 3.5 and 6.9‰. Ruby from the placers of Vatomandry and Andilamena has δ¹⁸O values of 5.9‰, and between 0.5 and 4.0‰, respectively. The placers of the Ilakaka area are characterized by a huge variety of colored sapphires and rubies, with δ¹⁸O values between −0.3 and 16.5‰, and their origin is debated. A comparison with oxygen isotope data obtained on gem corundum from Eastern Africa, India, and Sri Lanka is presented. Giant placer deposits from Sri Lanka, Madagascar, and Tanzania have a large variety of colored sapphires and rubies with a large variation in δ¹⁸O due to mingling of corundum of different origin: mafic and ultramafic rocks for ruby, desilicated pegmatites for blue sapphire, syenite for yellow, green, and blue sapphire, and skarn in marbles for blue sapphire.     

Electron density distribution and bond critical point properties for forsterite, Mg2 SiO4, determined with synchrotron single crystal X-ray diffraction data

A generalized X-ray scattering factor model experimental electron density distribution has been generated for the orthosilicate forsterite, using an essentially extinction and absorption free set of single crystal diffraction data recorded with intense, high energy synchrotron X-ray radiation (E=100.6 keV). A refinement of the model converged with an R(F)=0.0061. An evaluation of the bond critical point, bcp, properties of the distribution at the (3, –1) stationary points for the SiO and MgO bonded interactions, yielded values that agree typically within ~5%, on average, with theoretical values generated with quantum chemical computational strategies, using relatively robust basis sets. On the basis of this result, the modeling of the experimental distribution is considered to be adequate. As the bcp properties increase in magnitude, the MgO and SiO bonds decrease in length as calculated for a number of rock forming silicates. As asserted by Coppens (X-ray charge densities and chemical bonding. Oxford University Press, Oxford, 1997), large negative ²(r_c) values, characteristic of shared interactions involving first row atoms, may not be characteristic of closed shell covalent bonded interactions involving second row Si, P and S atoms bonded to O. This study adds new evidence to the overall relatively good agreement between theoretical bcp properties generated with computational quantum strategies, on the one hand, and experimental properties generated with single crystal high energy synchrotron diffraction data on the other. The similarity of results not only provides a basis for using computational strategies for studying and modeling structures, defects and the reactivity of representative structures, but it also provides a basis for improving our understanding of the crystal chemistry of earth materials and the character of the SiO bonded interaction.     

Stability of fictitious Trojan planets in extrasolar systems

Our work deals with the dynamical possibility that in extrasolar planetary systems a terrestrial planet may have stable orbits in a 1:1 mean motion resonance with a Jovian like planet. We studied the motion of fictitious Trojans around the Lagrangian points L₄/L₅ and checked the stability and/or chaoticity of their motion with the aid of the Lyapunov Indicators and the maximum eccentricity. The computations were carried out using the dynamical model of the elliptic restricted three‐body problem that consists of a central star, a gas giant moving in the habitable zone, and a massless terrestrial planet. We found 3 new systems where the gas giant lies in the habitable zone, namely HD99109, HD101930, and HD33564. Additionally we investigated all known extrasolar planetary systems where the giant planet lies partly or fully in the habitable zone. The results show that the orbits around the Lagrangian points L₄/L₅ of all investigated systems are stable for long times (10⁷ revolutions). (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Investigation of groundwater resources using controlled-source radio magnetotellurics (CSRMT) in glacial deposits in Heby,Sweden

We have combined tensor radio magnetotelluric- (RMT, 15–250 kHz) and controlled source tensor magnetotelluric (CSTMT, 1–12 kHz) data for the mapping of aquifers in gravel formations lying in between crystalline bedrock and clay rich sediments in the Heby area some 40 km west of Uppsala in Sweden. The estimated transfer functions, the impedance tensor and the tipper vector generally satisfy 1D or 2D necessary conditions except for the lowest CSTMT frequencies where near field effects become more dominant.The data measured from 8 profiles were inverted with the Rebocc code of Siripunvaraporn and Egbert (2000) assuming plane wave conditions. This meant that only 12 frequencies in the range of 4–180 kHz could be used. The four lowest frequencies of CSTMT in the range of 1–2.8 kHz were excluded because of source effects. Data from all profiles were inverted with a starting model of 100 Ω-m and a relative error floor of 0.02 on apparent resistivity, corresponding to less than 1^° on phase. Tipper vectors are generally small except when source effects become dominant in the lowest frequencies of CSTMT and were therefore not used for inversion. Comparing with models derived from vertical electrical soundings, refraction and reflection seismic data as well as ground truth from exploration wells assessed the reliability of the deep part of the models. Furthermore we carried out a non-linear resolution analysis to better quantify the depth extent of the aquifers.The inverted models from the Heby area show well the thickness variations of glacial deposits overlying crystalline bedrock. Generally, the upper 20 m of the models have resistivities below 40 Ω-m, taken to represent clay rich formations. Below the clay layer resistivities increase to about 40–400 Ω-m, interpreted to represent sand/gravel formations with a maximum thickness of about 40 m and a width of several hundred metres. This is a potential aquifer that extends in approximately N–S direction for some kilometres.     

The Cretaceous–Palaeogene boundary at Gorgonilla Island,Colombia, South America

The discovery of a new Cretaceous/Palaeogene (K/Pg) bathyal marine sequence on Gorgonilla Island, SW Colombia, extends the presence of Chicxulub impact spherule deposits to the Pacific region of northern South America and to the Eastern Pacific Ocean. The Gorgonilla spherule layer is approximately 20 mm thick and consists of extraordinarily well‐preserved glass spherules up to 1.1 mm in diameter. About 70–90% of the spherules are vitrified, and their chemical composition is consistent with Haiti (Beloc) impact glass spherules. Normal size‐grading, delicate spherule textures, welded melt components and an absence of bioturbation or traction transport suggest that the Gorgonilla spherule layer represents an almost undisturbed settling deposit.     

Use of sedimentary diatoms from multiple lakes to distinguish between past changes in trophic state and climate: evidence for climate change in northern Germany during the past 5,000 years

Fossil diatoms from lake sediments have been used to infer both past trophic state and climate conditions. In Europe, climate reconstructions focused on northern and alpine regions because these areas are climatically sensitive and anthropogenic impact was low. In contrast, anthropogenic impact was often high in the central European lowlands, such as northern Germany, beginning in the Neolithic Age, ~3700 BC. Since that time, trophic state change was the main factor that affected diatom assemblages in central European lowland lakes. Therefore, it was considered difficult or impossible to identify climate changes in the region using sedimented diatoms. We used diatom assemblage changes, diatom-inferred total phosphorus concentrations and the relative abundance of planktonic diatoms from sediments of three lakes that differ in their location, size, morphology, catchment area and current trophic state to test whether we could distinguish between trophic state and climate signals over the past 5,000 years in northern Germany. In this study, changes in trophic state and climate were well differentiated. In the study lakes, relative abundance of planktonic diatoms seems to be linked to the length of lake mixing phases. Planktonic diatom abundance decreased during years with shorter mixing duration, and these shorter mixing times probably reflect colder winters. The diatom-inferred periods of short mixing phases from 1000 BC to AD 500 and from AD 1300 to 1800 coincide well with two known cooling phases in Europe and the North Atlantic region.     

Studies in the application of recurrence relations to special perturbation methods

The numerical integration of the differential equations describing dynamical systems has been shown in previous papers of this series to be most effectively accomplished by an explicit Taylor series method.In this paper we show that one explicit Taylor series method, developed earlier in this series and which appears to possess a high degree of versatility, yields considerable gains in efficiency over classical single-step and multi-step methods. (In this context efficiency is a measure of the time taken to carry out a calculation of a specific accuracy).For a given accuracy criterion governing the local truncation error (LTE) it is found that the Taylor series method is generallytwice as fast as the classical multi-step method and up totwenty times faster than the classical single-step method.