On the Mechanism of Air Pollutant Removal in Two-Dimensional Idealized Street Canyons: A Large-Eddy Simulation Approach

Flow resistance, ventilation, and pollutant removal for idealized two-dimensional (2D) street canyons of different building-height to street-width (aspect) ratios $AR$ are examined using the friction factor $f$ , air exchange rate (ACH), and pollutant exchange rate (PCH), respectively, calculated by large-eddy simulation (LES). The flows are basically classified into three characteristic regimes, namely isolated roughness, wake interference, and skimming flow, as functions of the aspect ratios. The LES results are validated by various experimental and numerical datasets available in the literature. The friction factor increases with decreasing aspect ratio and reaches a peak at $AR = 0.1$ in the isolated roughness regime and decreases thereafter. As with the friction factor, the ACH increases with decreasing aspect ratio in the wake interference and skimming flow regimes, signifying the improved aged air removal for a wider street canyon. The PCH exhibits a behaviour different from its ACH counterpart in the range of aspect ratios tested. Pollutants are most effectively removed from the street canyon with $AR = 0.5$ . However, a minimum of PCH is found nearby at $AR = 0.3$ , at which the pollutant removal is sharply weakened. Besides, the ACH and PCH are partitioned into the mean and turbulent components to compare their relative contributions. In line with our earlier Reynolds-averaged Navier–Stokes calculations (Liu et al., Atmos Environ 45:4763–4769, 2011), the current LES shows that the turbulent components contribute more to both ACH and PCH, consistently demonstrating the importance of atmospheric turbulence in the ventilation and pollutant removal for urban areas.     

Assessing climate change vulnerability with group multi-criteria decision making approaches

This study developed an approach to assess the vulnerability to climate change and variability using various group multi-criteria decision-making (MCDM) methods and identified the sources of uncertainty in assessments. MCDM methods include the weighted sum method, one of the most common MCDM methods, the technique for order preference by similarity to ideal solution (TOPSIS), fuzzy-based TOPSIS, TOPSIS in a group-decision environment, and TOPSIS combined with the voting methods (Borda count and Copeland’s methods). The approach was applied to a water-resource system in South Korea, and the assessment was performed at the province level by categorizing water resources into water supply and conservation, flood control and water-quality sectors according to their management objectives. Key indicators for each category were profiled with the Delphi surveys, a series of questionnaires interspersed with controlled opinion feedback. The sectoral vulnerability scores were further aggregated into one composite score for water-resource vulnerability. Rankings among different MCDM methods varied in different degrees, but noticeable differences in the rankings from the fuzzy- and non-fuzzy-based methods suggested that the uncertainty with crisp data, rather widely used, should be acknowledged in vulnerability assessment. Also rankings from the voting-based methods did not differ much from those from non-voting-based (i.e., average-based) methods. Vulnerability rankings varied significantly among the different sectors of the water-resource systems, highlighting the need to assess the vulnerability of water-resource systems according to objectives, even though one composite index is often used for simplicity.     

Toxicity of antifouling biocides to the intertidal harpacticoid copepod Tigriopus japonicus (Crustacea, Copepoda): effects of temperature and salinity

Intertidal harpacticoid copepods are commonly used in eco-toxicity tests worldwide. They predominately live in mid-high shore rock pools and often experience a wide range of temperature and salinity fluctuation. Most eco-toxicity tests are conducted at fixed temperature and salinity and thus the influence of these environmental factors on chemical toxicity is largely unknown. This study investigated the combined effect of temperature and salinity on the acute toxicity of the copepod Tigriopus japonicus against two common biocides, copper (Cu) and tributyltin (TBT) using a 2 × 3 × 4 factorial design (i.e. two temperatures: 25 and 35 °C; three salinities: 15.0‰, 34.5‰ and 45.0‰; three levels of the biocide plus a control). Copper sulphate and tributyltin chloride were used as the test chemicals while distilled water and acetone were utilised as solvents for Cu and TBT respectively. 96h-LC50s of Cu and TBT were 1024 and 0.149 μg l⁻¹ respectively (at 25 °C; 34.5‰) and, based on these results, nominal biocide concentrations of LC0 (i.e. control), LC30, LC50 and LC70 were employed. Analysis of Covariance using ‘concentration’ as the covariate and both ‘temperature’ and ‘salinity’ as fixed factors, showed a significant interaction between temperature and salinity effects for Cu, mortality increasing with temperature but decreasing with elevated salinity. A similar result was revealed for TBT. Both temperature and salinity are, therefore, important factors affecting the results of acute eco-toxicity tests using these marine copepods. We recommend that such eco-toxicity tests should be conducted at a range of environmentally realistic temperature/salinity regimes, as this will enhance the sensitivity of the test and improve the safety margin in line with the precautionary principle.     

Laboratory studies on seismic and electrical properties of the moon

Laboratory measurements of seismic wave velocities and electrical properties of Apollo lunar samples and similar material of terrestrial origin are discussed in this paper. Measurements of the electrical properties show that in the frequency range above a few hundred Hz the outer region of the Moon may be considered as a low loss dielectric. This observation supports a longstanding speculation that dry, powdered rocks in which the dielectric loss tangent is frequency-independent over a wide range of frequency are present in the uppermost lunar surface layers. The surface layers of the Moon are likely to have an extremely low electrical conductivity. Thus future electromagnetic probing of the Moon to a few hundred kilometer depth is possible in the few kHz frequency range. Based on ultrasonic experiments with pressure as a variable, we next present the elastic constants and equations of state of lunar materials and characteristic dispersion of seismic wave velocities of the Moon. We find thatP andS wave velocities increase sharply within the first 30 km depth and then level off gradually. Combining this observation with lunar seismic and geophone data, we believe that the first 30 km of the Moon may be interpreted as a scattering region. If H₂O exists on the Moon, H₂O may occur at some shallow depth beneath the outermost surface layer in solid ice interlocking cracks and pores and mineral grains. The rocks in this permafrost state have relatively low seismic velocity and highQ. If permafrost does exist, we would expect a wide range of electrical conductivity and dielectric constant. Future electromagnetic probing of the Moon should yield very usefull information on the physical state of the lunar interior; when this electrical information is combined with the seismic information, we should learn much more about the internal constitution and the state of the Moon than is known today.     

First-Order Inconsistencies Caused by Rogue Trajectories

A theoretical requirement of the Interaction by Exchange with the Conditional Mean (IECM) micromixing model is that the mean concentration field produced by it must be consistent with the mean concentration field produced by a traditional Lagrangian stochastic (LS) marked particle model. We examine the violation of this requirement that occurs in a coupled LS–IECM model when unrealistically high particle velocities occur. No successful strategy was found to mitigate the effects of these rogue trajectories. It is our hope that this work will provide renewed impetus for investigation into rogue trajectories and methods to eliminate them from LS models.     

Public health impacts of climate change in Washington State: projected mortality risks due to heat events and air pollution

Illness and mortality related to heat and worsening air quality are core public health concerns associated with climate change projections. We examined the historical relationship between age- and cause-specific mortality rates from 1980 through 2006 and heat events at the 99th percentile of humidex values in the historic period from January 1, 1970 to December 31, 2006 in the greater Seattle area (King, Pierce and Snohomish counties), Spokane County, the Tri-Cities (Benton and Franklin counties) and Yakima County; the relative risks of mortality during heat events were applied to population and climate projections for Washington State to calculate number of deaths above the baseline (1980–2006) expected during projected heat events in 2025, 2045 and 2085. Three different warming scenarios were used in the analysis. Relative risks for the greater Seattle area showed a significant dose-response relationship between heat event duration and daily mortality rates for non-traumatic deaths for persons ages 45 and above, typically peaking at four days of exposure to humidex values above the 99th percentile. The largest number of projected excess deaths in all years and scenarios for the Seattle region was found for age 65 and above. Under the middle warming scenario, this age group is expected to have 96, 148 and 266 excess deaths from all non-traumatic causes in 2025, 2045 and 2085, respectively. We also examined projected excess deaths due to ground-level ozone concentrations at mid century (2045–2054) in King and Spokane counties. Current (1997–2006) ozone measurements and mid-twenty-first century ozone projections were coupled with dose-response data from the scientific literature to produce estimates overall and cardiopulmonary mortality. Daily maximum 8-h ozone concentrations are forecasted to be 16–28% higher in the mid twenty-first century compared to the recent decade of 1997–2006. By mid-century in King County the non-traumatic mortality rate related to ozone was projected to increase from baseline (0.026 per 100,000; 95% confidence interval 0.013–0.038) to 0.033 (95% CI 0.017–0.049). For the same health outcome in Spokane County, the baseline period rate of 0.058 (95% CI 0.030–0.085) was estimated increase to 0.068 (95% CI 0.035–0.100) by mid-century. The cardiopulmonary death rate per 100,000 due to ozone was estimated to increase from 0.011 (95% CI 0.005–0.017) to 0.015 (0.007–0.022) in King County, and from 0.027 (95% CI 0.013–0.042) to 0.032 (95% CI 0.015–0.049) in Spokane County. Public health interventions aimed at protecting Washington’s population from excessive heat and increased ozone concentrations will become increasingly important for preventing deaths, especially among older adults. Furthermore, heat and air quality related illnesses that do not result in death, but are serious nevertheless, may be reduced by the same measures.     

Satellite and ground observations for large-scale air pollution transport in the Yellow Sea region

Large-scale air pollution transport (LSAPT) in the Yellow Sea region and their inflow onto the Korean Peninsula were observed through satellite images and ground measurements. LSAPT includes regional continental air-masses saturated with pollutants originating from China and subsequently landing on or passing through the Korean Peninsula. It is also possible to identify the distribution and transport patterns of LSAPT over the Yellow Sea. The ground concentrations for PM10, PM2.5 and CO measured at Cheongwon, located in the centre of south Korea, were compared with NOAA satellite images. Notably, the episodes observed of the LSAPT show a PM2.5 to PM10 ratio of 74% of the daily maximum concentrations. However, cases of duststorms were clearly distinguished by much higher PM10 concentrations and a ratio of 30% of PM2.5 to PM10 for daily maximum concentrations. For the episode on January 27, 2006, the inflow of a regionally polluted continental air-mass into the central and southwestern regions of the Korean Peninsula was observed sequentially at various ground observatories as well as by satellite. The north airflow dissipated the clouds over Mt. Halla on Jeju Island and further downwind, reducing air pollution and creating a von Kármán vortex.