Determining the maximum degree of harmonic coefficients in geopotential models by Monte Carlo methods

Random errors for the harmonic coefficients of a geopotential model are generated from the matrix of normal equations by a parallel computer applying the Gibbs sampler. This leads to random values for the harmonic coefficients. They are transformed by nonlinear, quadratic transformations to random values for the square roots of degree variances, of mean squares of geoid undulations and gravity anomalies. The expected values of these quantities are not equal to the values of these quantities computed by the estimated harmonic coefficients, due to correlations and errors in the estimation. By hypothesis tests estimated harmonic coefficients distorted by correlations and errors are detected. Applying the tests to the geopotential model ITG-CHAMP01 of the Institute of Theoretical Geodesy in Bonn it is concluded that above the degree 62 the harmonic coefficients cannot add any information to the geopotential model.     

Seal capacity estimation from subsurface pore pressures

A cap rock's capacity to seal hydrocarbons depends on its wettability and the sizes of the pore throats within the interconnected pore system that the leaking hydrocarbons must penetrate. These critical pore throat sizes are often poorly constrained in hydrocarbon exploration, partly because measurements of pore throat sizes have not been performed, and partly because pore throat measurements on a few individual samples in the cap rock may not be representative for the seal capacity of the top seal as a whole. To the contrary, the presence of formation overpressure can normally be estimated in drilled exploration targets. The presence of overpressure in reservoirs testifies to small pore throats in the cap rocks, as large pore throats will result in sufficiently high cap rock permeability to bleed off the overpressure. We suggest a stepwise procedure that enables quantification of top seal capacities of overpressured traps, based on subsurface pressure information. This procedure starts with the estimation of cap rock permeabilities, which are consistent with observed overpressure gradients across the top seals. Knowledge of burial histories is essential for these estimations. Relationships between pore throat size and permeability from laboratory experiments are then applied to estimate critical pore throat diameters in cap rocks. These critical pore throat diameters, combined with information of the physical properties of the pore fluids, are then used to calculate membrane seal capacity of cap rocks. Estimates of top seal capacity based on this procedure are rather sensitive to the vertical fluid velocity, but they are also to some extent sensitive to inaccuracies of the pore throat/permeability relationship, overpressure gradient, interfacial tensions between pore fluids, hydrocarbon density and water viscosity values. Despite these uncertainties, applications of the above‐mentioned procedure demonstrated that the mere presence of reservoir overpressures testifies to sufficient membrane seal capacity of cap rocks for most geological histories. Exempt from this statement are basins with rapid and substantial sediment compaction in the recent past.     

Fabric studies within the Cascade Lake shear zone, Sierra Nevada, California

The Cascade Lake shear zone occurs on the eastern margin of the Tuolumne Intrusive Suite, Sierra Nevada Batholith, California. Foliation in the zone is NNW trending and subvertical, and lineation is moderately south plunging. Deformation is syn-tectonic with emplacement of the Cathedral Peak granodiorite. A deformation gradient exists toward the NE margin of this pluton, with higher strains and lower temperatures of deformation found near the contact. We compare fabric data collected very densely in this shear zone using several techniques: field fabrics, 3D orientation of K-feldspar megacrysts, and AMS (anisotropy of magnetic susceptibility) analysis. In general, the results from the three different methods are in agreement. Deformation in this shear zone is part of a larger pattern of deformation within the Cathedral Peak granodiorite, as recorded by AMS analysis, and dextral shearing associated within the last stage of plutonism within the Sierra Nevada magmatic arc.     

Thermal evolution of an extensional detachment as constrained by organic metamorphic data and thermal modeling: Graz Paleozoic Nappe Complex (Eastern Alps)

Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms.     

Molecular formulae of marine and terrigenous dissolved organic matter detected by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

The chemical structure of refractory marine dissolved organic matter (DOM) is still largely unknown. Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR-MS) was used to resolve the complex mixtures of DOM and provide valuable information on elemental compositions on a molecular scale. We characterized and compared DOM from two sharply contrasting aquatic environments, algal-derived DOM from the Weddell Sea (Antarctica) and terrigenous DOM from pore water of a tropical mangrove area in northern Brazil. Several thousand molecular formulas in the mass range of 300-600 Da were identified and reproduced in element ratio plots. On the basis of molecular elemental composition and double-bond equivalents (DBE) we calculated an average composition for marine DOM. O/C ratios in the marine samples were lower (0.36 ± 0.01) than in the mangrove pore-water sample (0.42). A small proportion of chemical formulas with higher molecular mass in the marine samples were characterized by very low O/C and H/C ratios probably reflecting amphiphilic properties. The average number of unsaturations in the marine samples was surprisingly high (DBE = 9.9; mangrove pore water: DBE = 9.4) most likely due to a significant contribution of carbonyl carbon. There was no significant difference in elemental composition between surface and deep-water DOM in the Weddell Sea. Although there were some molecules with unique marine elemental composition, there was a conspicuous degree of similarity between the terrigenous and algal-derived end members. Approximately one third of the molecular formulas were present in all marine as well as in the mangrove samples. We infer that different forms of microbial degradation ultimately lead to similar structural features that are intrinsically refractory, independent of the source of the organic matter and the environmental conditions where degradation took place.     

Environmental policy reform on north-eastern Brazil’s agricultural frontier

The expansion of modern agriculture in developing countries presents numerous challenges for environmental policy makers. Environmental policies for agriculture in north-eastern Brazil’s soybean belt are analyzed, with emphasis on the role of a non-state actor in leading policy reforms. An organization representing large farmers is leading policy reforms to reduce the environmental impacts of modern agriculture. By contrast, state agencies are relatively weak and ineffective. The analysis situates this question conceptually in literatures stressing the political and structural causes of corporate environmentalism and literatures explaining the increasingly strong role of non-state actors in environmental governance. The case study focuses on the content of reforms, reasons why the non-state actor is so prominent, and the implications of policy reforms. State agencies face major challenges in environment-agriculture policy debates in places where environmental subsidies are unlikely, environmental information is poor, and organized private interests are influential.     

Luminescence dating of ice‐marginal deposits in northern Germany: evidence for repeated glaciations during the Middle Pleistocene (MIS 12 to MIS 6)

The exact number, extent and chronology of the Middle Pleistocene Elsterian and Saalian glaciations in northern Central Europe are still controversial. This study presents new luminescence data from Middle Pleistocene ice‐marginal deposits in northern Germany, giving evidence for repeated glaciations during the Middle Pleistocene (MIS 12 to MIS 6). The study area is located in the Leine valley south of the North German Lowlands. The data set includes digital elevation models, high‐resolution shear wave seismic profiles, outcrop and borehole data integrated into a 3D subsurface model to reconstruct the bedrock relief surface. For numerical age determination, we performed luminescence dating on 12 ice‐marginal and two fluvial samples. Luminescence ages of ice‐marginal deposits point to at least two ice advances during MIS 12 and MIS 10 with ages ranging from 461±34 to 421±25 ka and from 376±27 to 337±21 ka. The bedrock relief model and different generations of striations indicate that the older ice advance came from the north and the younger one from the northeast. During rapid ice‐margin retreat, subglacial overdeepenings were filled with glaciolacustrine deposits, partly rich in re‐worked Tertiary lignite and amber. During MIS 8 and MIS 6, the study area may have been affected by two ice advances. Luminescence ages of glaciolacustrine delta deposits point to a deposition during MIS 8 or early MIS 6, and late MIS 6 (250±20 to 161±10 ka). The maximum extent of both the Elsterian (MIS 12 and MIS 10) and Saalian glaciations (MIS 8? and MIS 6) approximately reached the same position in the Leine valley and was probably controlled by the formation of deep proglacial lakes in front of the ice sheets, preventing a further southward advance.     

The presolar grain inventory of fine‐grained chondrule rims in the Mighei‐type (CM) chondrites

We investigated the inventory of presolar silicate, oxide, and silicon carbide (SiC) grains of fine‐grained chondrule rims in six Mighei‐type (CM) carbonaceous chondrites (Banten, Jbilet Winselwan, Maribo, Murchison, Murray and Yamato 791198), and the CM‐related carbonaceous chondrite Sutter's Mill. Sixteen O‐anomalous grains (nine silicates, six oxides) were detected, corresponding to a combined matrix‐normalized abundance of ~18 ppm, together with 21 presolar SiC grains (~42 ppm). Twelve of the O‐rich grains are enriched in ¹⁷O, and could originate from low‐mass asymptotic giant branch stars. One grain is enriched in ¹⁷O and significantly depleted in ¹⁸O, indicative of additional cool bottom processing or hot bottom burning in its stellar parent, and three grains are of likely core‐collapse supernova origin showing enhanced ¹⁸O/¹⁶O ratios relative to the solar system ratio. We find a presolar silicate/oxide ratio of 1.5, significantly lower than the ratios typically observed for chondritic meteorites. This may indicate a higher degree of aqueous alteration in the studied meteorites, or hint at a heterogeneous distribution of presolar silicates and oxides in the solar nebula. Nevertheless, the low O‐anomalous grain abundance is consistent with aqueous alteration occurring in the protosolar nebula and/or on the respective parent bodies. Six O‐rich presolar grains were studied by Auger Electron Spectroscopy, revealing two Fe‐rich silicates, one forsterite‐like Mg‐rich silicate, two Al‐oxides with spinel‐like compositions, and one Fe‐(Mg‐)oxide. Scanning electron and transmission electron microscopic investigation of a relatively large silicate grain (490 nm × 735 nm) revealed that it was crystalline åkermanite (Ca₂Mg[Si₂O₇]) or a an åkermanite‐diopside (MgCaSi₂O₆) intergrowth.