渤海海域油气勘探进展与前景展望

通过回顾我国渤海海域近50年的勘探历程,分析了油气发现的特点,指出从下第三系到上第三系勘探思路的转变是导致发现系列亿吨级大油气田的关键。迄今为止的重大发现主要分布于环渤中凹陷油气富集圈和沿岸两大地区。认为在有据可查的历史上,渤海海域发生过7级以上大地震的周围地区均发现有大油气田,因此将是发现油气田的有利地区。根据全国3轮油气资源评价数据,我国在渤海海域的油气勘探尚大有可为,重要的是要求较高的科技研究水平和更大的投入力度,渤海深浅层次资源潜力将获得更进一步的发掘。认为在50余年的勘探历程中,我3大国有石油公司及全国相关科技工作者均做出过重大贡献。     

南海高钙沉积物中18种常微量元素的ICP-AES测定方法研究

在利用ICP-AES分析南海高钙沉积物中的常微量元素时,钙、镁常常干扰其它元素测试。通过采用优化仪器工作参数、扣除背景值、谱线干扰校正和基体匹配的步骤,消除了元素干扰和钙、镁基体效应,提高了方法的灵敏度和准确度。通过对南海沉积物样品的大量实验和国家一级标准样验证,建立了适宜高钙海洋沉积物元素含量的ICP-AES测试方法。该方法检出限为1.55~271μg/L,相对标准偏差RSD<4.54%(n=6)。     

罗非鱼、南美白对虾对重金属富集的研究

对广东省养殖的罗非鱼Oreochromis niloticus及南美白对虾Litopeneaus vannamei体内Pb、Cd、Hg、As 4种重金属富集及分布状况进行研究。比较了不同规格罗非鱼及南美白对虾体内重金属差异。分析重金属在罗非鱼及南美白对虾不同部位的分布状况。结果表明,罗非鱼及南美白对虾体内Pb、Cd、Hg、As均有不同程度的检出,但含量均低于国家限定标准(NY5125-2002);其中Pb的含量最高,罗非鱼和南美白对虾体内Pb含量最高值分别为限量的39.32%和42.18%;重金属含量因其规格大小及部位而异,趋势为大规格样品重金属含量相对较高,重金属含量在罗非鱼及南美白对虾体内的增长情况与其体重具有正相关性;罗非鱼内脏重金属含量明显高于肌肉组织,虾头为虾重金属富集的主要部位。     

A comparison of several wave spectra for the random wave diffraction by a semi-infinite breakwater

A comparison of the diffraction of multidirectional random waves using several selected wave spectrum models is presented in this paper. Six wave spectrum models, Bretschneider, Pierson–Moskowitz, ISSC, ITTC, Mitsuyasu, and JONSWAP spectrum, are considered. A discrete form for each of the given spectrum models is used to specify the incident wave conditions. Analytical solutions based on both the Fresnel integrals and polynomial approximations of the Fresnel integrals and numerical solutions of a boundary integral approach have been used to obtain the two-dimensional wave diffraction by a semi-infinite breakwater at uniform water depth. The diffraction of random waves is based on the cumulative superposition of linear diffraction solution. The results of predicted random wave diffraction for each of the given spectrum models are compared with those of the published physical model presented by Briggs et al. [1995. Wave diffraction around breakwater. Journal of Waterway, Port, Coastal and Ocean Engineering—ASCE 121(1), 23–35]. Reasonable agreement is obtained in all cases. The effect of the directional spreading function is also examined from the results of the random wave diffraction. Based on these comparisons, the present model for the analysis of various wave spectra is found to be an accurate and efficient tool for predicting the random wave field around a semi-infinite breakwater or inside a harbor of arbitrary geometry in practical applications.     

Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H2S concentrations

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.     

计算数据域特征值的两种算法

设计两种计算数据域特征值的算法。此特征值通常是用线性反馈移位寄存器（ＬＦ－ＳＲ）组成的特征分析器得到的．在数据已按字节存放和速度要求不高的场合下，本算法将是十分方便和有用的．     

虾蟹海产品香味的前体物质的加热变化

本文研究了虾蟹海产品香味的前体物质在加热前后的变化。实验结果表明：对虾和蟹肌肉中的糖原和不饱和脂肪酸在加热前后含量下降，糖原是Ｍａｉｌｌａｒｄ反应的基础物质．不饱和脂肪酸是虾蟹肌肉香味中羰基化合物的前体物质。虾蟹肌肉中主要积累的核苷酸成分ＡＭＰ在加热后减少，而肌肉提取物中的游离氨基酸和结合氨基酸，特别是疏水氨基酸含量均增加。     

可编程序控制器的多机联用

多台可编程序控制器通过输入、输出点的直接连接,传递命令、状态和数据,实现多机联用系统。     

环胶州湾公路海上段汽车尾气的环境影响

对类比路段进行连续模拟试验,进行现场调查,给出汽车尾气主要污染物的排污强度,预测了汽车尾气中CO、C_nH_m和NO_x的扩散范围。     

崂山花岗岩地区含锶、偏硅酸矿泉水的形成机理

报道了崂山花岗岩地区矿泉水的特征。指出其矿泉类型为含锶、偏硅酸型，并讨论了其形成机理。