Surface complexation modeling of Uranium(VI) sorption on quartz in the presence and absence of alkaline earth metals

Surface complexation models (SCMs) are widely utilized as a tool to study the mobility of radionuclide to the environment. In this study, two SCMs, electrostatic (ES) and non-electrostatic (NES) models are employed in order to simulate the sorption behavior of U(VI) on quartz in the absence of Mg, Ca, and Sr and ES model in the presence of alkaline earth metals. The surface reaction constants (log K) for ES and NES models were fitted to experimental data by coupling PEST with PHREEQC. The SCM prediction of U(VI) sorption on quartz in the absence of alkaline earth metals is in good agreement with the experimental data in the pH range 6.5–9. The estimated log K values are sensitive to both ES and NES model calculations. In U(VI)-Mg-quartz, U(VI)-Ca-quartz, and U(VI)-Sr-quartz systems, only the ES model shows the general trend of the experimental data. The estimated log K values are sensitive with respect to the surface reactions. Hence, the ES model is more suitable for model calculations of the U(VI)-Mg-quartz, U(VI)-Ca-quartz, and U(VI)-Sr-quartz systems.     

Mobilization of trace metals in a tropical turbid estuary influenced by a monsoon season

The selective removal of trace metals by suspended matter in high turbidity zones plays a major role in the fluvial transport of terrigenous metals to the marine environment. The seasonal longitudinal variability of trace elements (Cu, Zn, Cd, Ni, Pb, Fe, and Mn) in Cochin estuary, a tropical positive estuary, was studied and the results were compared with the prevailing situation in other subtropical waterways. The hydrodynamical features showed increasing turbidity downstream with increasing salinities during both the seasons. In contrast with the temperate estuaries where the development of turbidity maxima causes the removal of metals, the estuaries of tropics modify the fluvial transport of metals by the way of redistribution between the dissolved and particulate fractions in the intermediate salinities. In Cochin estuary, the distributional features of trace metals are primarily influenced by the variations in salinities and river discharges. Consequently, this gives rise to two different types of distributional patterns: (1) during premonsoon, the estuarine reactivity is more pronounced and hence, mid-estuarine solubilization of the particulate metal appears to play a prominent role in controlling the fluxes of trace metals studied and (2) but during monsoon, the hydrological conditions influence the downstream transport of the metals more by physical dilution than chemical reactivity.     

Influence of flow velocity on conservative solute transport in sets of parallel fractures with fracture skin

Analysis of contaminant transport through fractured crystalline rocks has received considerable attention, particularly with regard to subsurface nuclear waste repositories. Most of the studies have employed the dual continuum approach, with the fractures and the rock matrix as the two continuums, assuming that fractures control the overall conductivity of the rock and the porous matrix just provides storage. However, field observations of rock fractures have shown that the real situation can be very complex. Based on some recent investigations, it has been reported that the portion of the rock matrix adjacent to many open fractures is physically and chemically altered. These alterations, referred to as the fracture skin, can have different sorption and diffusion properties compared to those of the undisturbed rock matrix and this may influence the transport of solutes through such formations. In the present study, a numerical model is developed to simulate conservative solute transport in a fractured crystalline rock formation using the triple continuum approach ?? with the fracture, fracture skin and the rock matrix as the three continuums. The model is solved using a fully implicit finite difference scheme. Contaminant migration in the fractured formation with and without skin has been simulated. It is observed that contaminant penetration along the fracture is enhanced at large flow velocities. The effect of flow velocity on conservative solute transport is investigated for different fracture apertures and fracture skin thicknesses. The influence of flow velocity on contaminant transport is demonstrated to be more with change in fracture aperture than with change in skin thickness.     

Unusual Association of Skipjack Tunas Katsuwonus pelamis and a Longline Vessel

Ocean Science Journal - Skipjack tuna were observed for the first time swimming in front of the bow of a fishing vessel during a tagging campaign in the North Atlantic. Video recordings show how...     

Comparison of Grid Averaged Altimeter and Buoy Significant Wave Heights in the Northern Indian Ocean

A quantitative comparison of the collocated inter-annual significant wave height (SWH) data collected between 2006 and 2009 from buoys and altimeters at nine buoy locations (total n = 2241) in the Northern Indian Ocean is attempted for assessing the validity of daily averaged gridded altimeter significant wave height (ASWH) provided by AVISO for operational use. ASWH is underestimated by 0.20 m, the root-mean-square error (RMSE) is less than 0.30 m, the Scatter Index is less than 20%, and the correlation coefficient is greater than 0.90. Further, at three locations, the examination of the above statistics showed that the bias and RMSE is high during the southwest monsoon season compared with the Northeast monsoon. Scatter Index showed only slight variation (14–18%) for different ranges of SWH. The response of the daily average gridded ASWH data during extreme conditions (cyclones) in the vicinity of the buoy locations is poor at all compared buoy locations. The gridded ASWH from different satellite missions provided by AVISO can be used for basin scale validation experiments of the wave model and for climatological studies in the Indian Ocean, except during cyclone conditions.     

Microscale Response of Sediment Variables to Benthic Disturbance in the Central Indian Ocean Basin

Abstract

The response of sediment bacteria and biochemical variables to benthic disturbance was investigated in the Central Indian Ocean Basin from cores at nine stations. Generally, bacterial density and biochemical variables declined vertically with depth in the upper layers of the cores. Mechanical disturbance caused by a hydraulic disturber brought about a substantial decrease in total bacterial numbers. However, the numbers of retrievable bacteria increased by two orders of magnitude. The biochemical parameters decreased in quantity with a shift in the linear relationship. The data suggest that abiotic artifacts will directly affect the biomass and biochemistry of the sediment.     

A Methodology for Simulating Radionuclide Diffusion in Unsaturated Soils

In this paper, a methodology that can be employed to simulate radionuclide migration through unsaturated soils, under laboratory conditions, has been developed and reported. This was achieved with the help of a specially designed half-cell setup to study diffusion characteristics of inactive forms of Cs⁺, Sr⁺² and Co⁺² in two different types of soils, corresponding to their different compaction states. It has been noted that the apparent diffusion coefficient strongly depends on the volumetric water content of the soil. However, increase of the apparent diffusion coefficient for higher volumetric water contents is found to be much less as compared to the lower volumetric water contents.     

Geochemical characterization of source rock from the north bank area,upper Assam basin

The study area is confined to a part of upper Assam basin, north of river Brahmaputra (north bank). Seven exploratory wells have been drilled in this part of the basin in order to probe the hydrocarbon prospects of the area. The exploratory efforts did not indicate significant hydrocarbon prospects in the north bank. Since the presence of source rock is an important component of the petroleum system, a detailed systematic study of source rock potential was carried out by analysing known source rock intervals in these seven wells. In the present study, Rock-Eval pyrolysis combined with specific geochemical analyses like GC and TLCFID has been used to characterise the source rocks, their distribution and thermal maturity of the organic matter. The source rocks in the area show mainly Type III, land-plant derived organic matter along with some Type II organic matter. They are predominantly gas prone in nature, although mixed and oil-prone source rocks are occasionally present. Although source rock intervals have been identified in the Langpar, Sylhet limestone and Kopili formations, the Barail Group and the Tipam sandstone Formation, the bulk of the source rock occurs within the Kopili Formation. Geochemical analyses of the cores indicate oil signatures at certain depths, although no commercial oil was discovered. The hydrocarbon generation potential of these source rocks are constrained by low maturity at the presently drilled depths.     

Basement tectonics and flexural subsidence along western continental margin of India

The Paleocene-recent post-rift subsidence history recorded in the Mumbai Offshore Basin off western continental margin of India is examined. Results obtained through 2-D flexural backstripping modelling of new seismic data reveal considerable thermo-tectonic subsidence over last ca. 56 Myr. Reverse postrift subsidence modelling with variable β stretching factor predicts residual topography of ca. 2000 m to the west of Shelf Margin Basin and fails to restore late Paleocene horizon and the underlying igneous basement to the sea level. This potentially implies that:(1) either the igneous basement formed during the late Cretaceous was emplaced under open marine environs; or(2) a laterally varying cumulative subsidence occurred within Mumbai Offshore Basin(MOB) during ca. 68 to ca. 56 Ma. Pre-depositional topographic variations at ca. 56 Ma across the basin could be attributed to the extensional processes such as varied lower crustal underplating along Western Continental Margin of India(WCMI). Investigations about basement tectonics after unroofing of sediments since late Paleocene from this region support a transitional and heavily stretched nature of crust with high to very high β factors. Computations of past sediment accumulation rates show that the basin sedimentation peaked during late Miocene concurrently with uplift of Himalayan-Tibetan Plateau and intensification of Indian monsoon system. Results from basin subsidence modelling presented here may have significant implications for further studies attempting to explore tectono-climatic interactions in Asia.     

Induced magnetic field of the equatorial electrojet at the surface of the Earth

Summary. The northward component of the induced magnetic field due to the equatorial electrojet at the Earth's surface is calculated using a more realistic local time variaton of the external field due to the electrojet than is provided for by models of the electrojet currently used in induction calculations. It is seen that appreciable induction effects can be expected about an hour before local noon for the kind of local time variation considered. Our results are in qualitative agreement with direct observations of Earth currents in the equatorial region in Nigeria. At local times when observable induction effects are present, the magnetic field due to the electrojet is necessarily three-dimensional; hence in order to obtain the internal part directly from the observed total field due to the electrojet at the Earth's surface, a three-dimensional formulation is required.