Asteroid (101955) 1999 RQ36: Spectroscopy from 0.4 to 2.4 μm and meteorite analogs

We present reflectance spectra from 0.4 to 2.4 μm of Asteroid (101955) 1999 RQ36, the target of the OSIRIS-REx spacecraft mission. The visible spectral data were obtained at the McDonald Observatory 2.1-m telescope with the ES2 spectrograph. The infrared spectral data were obtained at the NASA Infrared Telescope Facility using the SpeX instrument. The average visible spectrum is combined with the average near-infrared wavelength spectrum to form a composite spectrum. We use three methods to constrain the compositional information in the composite spectrum of Asteroid (101955) 1999 RQ36 (hereafter RQ36). First, we perform a least-squares search for meteorite spectral analogs using 15,000 spectra from the RELAB database. Three most likely meteorite analogs are proposed based on the least-squares search. Next, six spectral parameters are measured for RQ36 and their values are compared with the ranges in parameter values of the carbonaceous chondrite meteorite classes. A most likely meteorite analog group is proposed based on the depth of overlap in parameter values. The results of the least-squares search and the parametric comparisons point to CIs and/or CMs as the most likely meteorite analogs for RQ36, and COs and CHs as the least likely. RQ36 has a spectrally “blue” continuum slope that is also observed in carbonaceous chondrites containing magnetite. We speculate that RQ36 is composed of a “CM1”-like material. Finally, we compare RQ36 to other B-type asteroids measured by Clark et al. (Clark, B.E. et al. [2010]. J. Geophys. Res. 115, E06005). The results of this comparison are inconclusive. RQ36 is comparable to Themis spectral properties in terms of its albedo, visible spectrum, and near-infrared spectrum from 1.1 to 1.45 μm. However, RQ36 is more similar to Pallas in terms of its near-infrared spectrum from 1.6 to 2.3 μm. Thus it is possible that B-type asteroids form a spectral continuum and that RQ36 is a transitional object, spectrally intermediate between the two end-members. This is particularly interesting because Asteroid 24 Themis was recently discovered to have H₂O ice on the surface (Rivkin, A., Emery, J. [2010]. Nature 464, 1322–1323; Campins, H. et al. [2010a]. Nature 464, 1320–1321).     

A methodological approach to water quality assessment in an ungauged basin,Buenos Aires,Argentina

The Reconquista River is one of the most polluted rivers in Latin America. This paper aims at identifying the dynamics of water quality in an area with low or “background” concentrations of pollutants within the Reconquista River system in order to better define levels of pollution in the main system. In order to describe the dynamics of water quality in the background area, we propose a methodology based on flow estimation with the instantaneous unit hydrograph model and on measurements of physical and chemical water variables under different hydrological conditions. Because of high dissolved oxygen and low ammonium and o-phosphate concentrations, the Arroyo Durazno, a tributary stream of the Reconquista River, is defined as a background area. When a storm event begins, the concentration of nitrates and the electrical conductivity diminish. An increase in dissolved organic carbon suggests an important input of carbon from hillslope runoff. The proportion of fulvic and humic acids also increases. On the receding limb of the hydrograph, nitrate concentration was lower than during maximum flow and organic carbon concentration remained high. This behavior, known as the “flushing effect”, suggests that the soluble material accumulated in the drainage area during dry periods is transported to the stream by leaching or “lixiviation” and surface runoff, thus raising solute concentrations during the first few hours of the storm. Water quality changes rapidly, even in background areas, due to its dependence on the flow. The methodology followed in this paper can also be applied to other basins with similar characteristics. Due to the difficulty in defining baseline areas for surface waters, a knowledge of background water quality and its dynamics is essential for understanding pollution trends and anthropogenic impacts on rivers.     

Phylogeny, diet, and habitat of an extinct ground sloth from Cuchillo Curá, Neuquén Province, southwest Argentina

Advancements in ancient DNA analyses now permit comparative molecular and morphological studies of extinct animal dung commonly preserved in caves of semiarid regions. These new techniques are showcased using a unique dung deposit preserved in a late glacial vizcacha (Lagidium sp.) midden from a limestone cave in southwestern Argentina (38.5° S). Phylogenetic analyses of the mitochondrial DNA show that the dung originated from a small ground sloth species not yet represented by skeletal material in the region, and not closely related to any of the four previously sequenced extinct and extant sloth species. Analyses of pollen and plant cuticles, as well as analyses of the chloroplast DNA, show that the Cuchillo Curá ground sloth browsed on many of the same herb, grass, and shrub genera common at the site today, and that its habitat was treeless Patagonian scrub-steppe. We envision a day when molecular analyses are used routinely to supplement morphological identifications and possibly to provide a time-lapse view of molecular diversification.     

On the Solar Origins of Intense Geomagnetic Storms Observed During 6–11 March 1993

Intense geomagnetic storms with DST index -100 nT were recorded on 9 March and 11 March 1993 associated with solar activity on 6 March and 9-10 March, respectively. In this paper, we discuss the characteristic features of the solar origins of the two events that gave rise to coronal and interplanetary disturbances and as a consequence produced strong geomagnetic activity at the Earth. The source of the activity in one case is attributed to a major 3M7.0 flare that occurred on 6 March 1993 and in the other case, to two large filament disruptions on the disk during 9-10 March, 1993. Both these sources were found to be located near changing or varying low-latitude coronal holes. They were also located close to the heliospheric currents sheets. Distinct X-ray activity was observed for both the events as observed by the Yohkoh SXT telescope. The detailed evolution and a comparison of these events on the basis of Yohkoh soft X-ray observations are presented here.     

Comparison of four numerical models for simulating seepage from salt marsh sediments

A boundary integral equation method (BIEM) model and three differently formulated finite element method (FEM) models were implemented to explore the spatial and temporal patterns in marsh pore water seepage that each generated. The BIEM model is based on the Laplace equation coupled to a dynamic free-surface condition that assumes that, as the water-table changes, the aquifer instantaneously loses or gains an amount of water equal to the change in head times the specific yield. The FEM models all implement a simplified Richards equation that allows gradual desaturation or resaturation and thus flow in both the saturated and unsaturated zones of the aquifer. Two of the FEM models are based on the governing equation for the USGS model SUTRA and thus take into account fluid and aquifer compressibility. One of these was modified to take into account the effect of tidal loading on the total stress, which is assumed to be constant in the derivation of the original version of SUTRA. The third FEM model assumes that neither the fluid or aquifer matrix is compressible so that changes in storage are due solely to changes in saturation. The unmodified SUTRA model generated instantaneous boundary fluxes that were up to two orders of magnitude greater, and spatially more uniform, than those of the other models. The FEM model without compressibility generated spatial and temporal patterns of the boundary fluxes very similar to those produced by the BIEM model. The SUTRA model with the tidal stress modification gave fluxes similar in magnitude to the BIEM and no compressibility models but with distinctly different distributions in space and time. These results indicate that accurate simulation of seepage from marsh soils is highly sensitive to aquifer compressibility and to proper formulation of the effect of tidal loading on the total stress in the aquifer. They also suggest that accurate simulation may require total stress correction not only for tidal loading but for changes in the water table as well. Finally, to aid the development of methods for the measurement of compressibility, we present a schematic, pore-scale model to illustrate the factors that may govern the compressibility of marsh soils.     

Grain size and depositional environment as predictors of permeability in coastal marine sands

More than half of the surface sediments covering the continental shelves are sandy, which may permit substantial sub-seafloor pore water advection. Knowledge of sediment permeability is required for quantifying advection and associated solute transport, but studies of marine sediments typically report grain size analyses rather than permeability. Here data from 23 studies were examined to determine the range in permeabilities reported for sublittoral marine sands and to assess the utility of permeability–grain size relationships in this setting. In the resulting database, the permeability of small (∼30 cm) undisturbed cores collected from the sea floor all fell between 2 × 10⁻¹² and 4 × 10⁻¹⁰ m², a range where advective transport induced by wave and current action should be pervasive. The range in grain size was very similar for near-shore (<10 m water depth) and continental shelf samples (>10 m water depth), but the permeability of the continental shelf samples was consistently lower for the same median grain size. Empirical permeability–grain size relationships generated a poor fit (r² = 0.35) for the aggregate data, but separate relationships for near-shore and continental shelf samples were significantly better, r² = 0.66 and 0.77, respectively. Permeability–grain size relationships thus may be useful for sublittoral sands, but a larger database needs to be accumulated before reliable fit parameters and variability can be predicted. Thus it is recommended that permeability be routinely determined when characterizing sedimentological properties of marine sand deposits. Concurrent determinations of sediment bulk density and porosity may further improve estimates of permeability.     

Comparison of marine and river water humic substances in a Patagonian environment (Argentina)

Structural aspects of humic substances (HSs) in marine waters of Engaño Bay (Atlantic Ocean) and water from the Chubut River (Patagonia, Argentina) were compared. The HSs were isolated, purified, and analyzed using a multiple-method approach for structural characterization: elemental analysis, nuclear magnetic resonance (¹³C and ¹H NMR), infrared spectroscopy (FTIR), UV-visible absorption and fluorescence. Similarities between the marine and freshwater components were evaluated on the basis of N and O contents, H/C and C/N atomic ratios, infrared bands from nitrogen-containing and carboxylic groups, percentage of functional groups obtained from NMR spectra, spectral slope coefficient of absorption spectra, absorbance ratios at 250 and 365 nm (E ₂/E ₃), aromaticity, excitation–emission matrices and fluorescence quantum yield. Both the Engaño Bay and Chubut River waters have HSs that are mainly composed of fulvic acids (FAs); although they are very similar, they may be distinguished from one another. Similarities include the predominance of aliphatic carbon content (low aromatic content); however, the water bodies differed in their content of proteins and carboxylic acids. The Engaño Bay FAs have mainly an aquatic origin; although the Chubut River FAs suggest a similar aquagenic origin, there is also evidence of contributions from pedogenic FAs.     

Set-up of a decision support system to support sustainable development of the Laguna de Bay,Philippines

Over recent decades, population expansion, deforestation, land conversion, urbanisation, intense fisheries and industrialisation have produced massive changes in the Laguna de Bay catchment, Philippines. The resulting problems include rapid siltation of the lake, eutrophication, inputs of toxics, flooding problems and loss of biodiversity. Rational and systematic resolution of conflicting water use and water allocation interests is now urgently needed in order to ensure sustainable use of the water resources. With respect to the competing and conflicting pressures on the water resources, the Laguna Lake Development Authority (LLDA) needs to achieve comprehensive management and development of the area. In view of these problems and needs, the Government of the Netherlands was funding a two-year project entitled 'Sustainable Development of the Laguna de Bay Environment'.A comprehensive tool has been developed to support decision-making at catchment level. This consists of an ArcView GIS-database linked to a state-of-the-art modelling suite, including hydrological and waste load models for the catchment area and a three-dimensional hydrodynamic and water quality model (Delft3D) linked to a habitat evaluation module for the lake. In addition, MS Office based tools to support a stakeholder analysis and financial and economic assessments have been developed. The project also focused on technical studies relating to dredging, drinking water supply and infrastructure works. These aimed to produce technically and economically feasible solutions to water quantity and quality problems. The paper also presents the findings of a study on the development of polder islands in the Laguna de Bay, addressing the water quantity and quality problems and focusing on the application of the decision support system.     

An evaluation of glass prisms in boat docks to reduce shading of submerged aquatic vegetation in the lower St. Johns River,Florida

The effectiveness of glass prisms in boat docks was assessed to determine if shading impacts to submerged aquatic vegetation (SAV), primarilyVallisneria americana, were reduced. Six experimental docks, three with prisms and three without prisms, were constructed in the lower St. Johns River, Florida. SAV percent cover and photosynthetically active radiation (PAR) were monitored under each dock and in an adjacent control area with no experimental docks. Subsurface PAR during the growing season of the first year of the study was not significantly greater beneath docks having prisms than beneath docks without prisms. Postconstruction SAV monitoring (February 2000 to May 2002) revealed no significant differences in SAV percent cover between dock treatments, although coverage declined in both dock treatments and the control area. Declining water quality conditions at the study site clearly impacted the health of the SAV habitat as indicated by the decline in SAV coverage in the control area initially in the study. Given the subsequent resurgence of SAV in the control area, the additional light transmitted through the prisms did not appear to be biologically significant or adequate to counteract effects from larger-scale environmental stressors.