Coupled evolution of back-arc and island arc-like mafic crust in the late-Neoproterozoic Agardagh Tes-Chem ophiolite, Central Asia: evidence from trace element and Sr–Nd–Pb isotope data

. We report major-element, trace-element and isotopic data of volcanic rocks from the late-Neoproterozoic (570 Ma) Agardagh Tes-Chem ophiolite in Central Asia, south-west of Lake Baikal (50.5°N, 95°E). The majority of samples are high-alumina basalts and basaltic andesites having island-arc affinities. They were derived from an evolved parental magma (Mg#̾.60, Cr~180 ppm, Ni~95 ppm) by predominantly clinopyroxene fractionation. The parental magma developed from a primary mantle melt by fractionation of about 12% of an olivine+spinel assemblage. The island-arc rocks have high abundances of incompatible trace elements (light rare-earth element abundances up to 100 times chondritic, chondrite-normalised (La/Yb)_n=14.6-5.1) and negative Nb anomalies (Nb/La=0.37-0.62), but low Zr/Nb ratios (7-14). Initial )_Nd values are around +5.5, initial Pb isotopic compositions are ²⁰⁶Pb/²⁰⁴Pb=17.39-18.45, ²⁰⁷Pb/²⁰⁴Pb=15.49-15.61, ²⁰⁸Pb/²⁰⁴Pb=37.06-38.05. Enrichment of large-ion lithophile elements within this group is significant (Ba/La=11-130). Another group of samples consists of back-arc basin-related volcanic rocks. They are most likely derived from the same depleted mantle source as the island-arc rocks, but underwent higher degrees of melting (8-15%) and are not influenced by slab components. They have lower abundances of incompatible trace elements, flat rare-earth element patterns [(La/Yb)_n=0.6-2.4] and higher )_Nd values (+7.8 to +8.5). Negative Nb anomalies are absent (Nb/La=0.81-1.30), but Zr/Nb is high (21-48). At least three components are necessary to explain the geochemical evolution of the volcanic rocks: (1) an enriched (ocean island-like) component characterised by a high Nb concentration (up to 30 ppm), an absent negative Nb anomaly, a low Zr/Nb ratio (~6.5), a low )_Nd value (around 0), and radiogenic ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb; (2) a back-arc basin component similar to N-MORB with a flat rare-earth element pattern and a high )_Nd value (around +8.5); and (3) an island-arc component from a mantle source which was modified by the downgoing slab. Crystal fractionation superimposed on mixing and source contamination by subducted sediments is suitable to explain the observed geochemical data. The most likely geodynamic environment to produce these characteristics is a young, intra-oceanic island-arc system and an associated back-arc basin.     

Cathodoluminescence petrography and isotope geochemistry of KT impact ejecta deposited 360 km from the Chicxulub crater, at Albion Island, Belize

The depositional and diagenetic history of Cretaceous–Tertiary (KT) impact ejecta deposited 360 km from the Chicxulub crater, at Albion Island, Belize, has been investigated using integrated cathodoluminescence and isotopic analyses. A quarry exposes 26 m of Upper Cretaceous Barton Creek Formation dolomitized marine limestone overlain by 16 m of dolomitized Albion Formation impact ejecta. The Albion Formation consists of a lower fine‐grained ≈1‐m‐thick spheroid bed and an upper 15‐m‐thick coarse conglomeratic diamictite bed. A 14‐event paragenetic sequence has been documented and used as a temporal framework to interpret chemostratigraphic trends in bulk rock δ¹⁸O, δ¹³C and ⁸⁷Sr/⁸⁶Sr. The uppermost surface of the Barton Creek Formation was subaerially exposed before the KT impact, as indicated by a brecciated palaeosol that caps upsection decreases in δ¹³C and δ¹⁸O. Small 1‐cm‐diameter spheroids in the spheroid bed exhibit vermicular crystalline textures but lack the concentric zonations common to accretionary lapilli. These spheroids are hypothesized originally to have been impact glass or reactive Ca and Mg oxide dusts that adhered to water vapour particles condensing from the cooling impact vapour cloud. The spheroids were dolomitized soon after deposition. The earliest dolomitization in the matrix sediments of the Albion Formation was also post‐depositional, replacing clays formed by devitrification of impact glass. Dolomite and clay ⁸⁷Sr/⁸⁶Sr exhibit a distinct symmetrical distribution in the spheroid bed ranging from 0·707745 to 0·707872. Although unproven, this may represent primary changes in the chemical composition of the impact glass. The limestone clasts in the diamictite bed were dolomitized before the KT impact and exhibit upsection decreases in bulk rock ⁸⁷Sr/⁸⁶Sr. This suggests that the clasts were excavated from strata equivalent in age or older than the Barton Creek Formation at locations closer to, or in, the Chicxulub crater.     

Effects of weather and snow conditions on reproduction and survival of semi-domesticated reindeer (R. t. tarandus)

In this work we investigated the effects of local weather and snow conditions on the reproduction and survival of semi-domesticated reindeer ( Rangifer t. tarandus ) from 1962 to 1987 in four separate study areas in northern Finland. Reindeer density had no negative effect on calf percentage in slaughter (October-January) in any area. The higher the number of very warm days or mean temperatures in summer, the lower was the calf percentage in all forested areas (Sodankylä, Muonio and Ivalo). In the Muonio area, calf percentage was also reduced by winters with abundant snow accumulation. In the open, mountainous Kevo area, calf percentage was reduced with a high number of warm days (mean T>0°C) during the previous December. However, if the previous May was warm in that area, it had an opposite effect. High reindeer densities seemed to increase mortality only in the Sodankylä area. Abundant snow accumulation during winter reduced the survival index of reindeer both in the Sodankylä and Ivalo areas. In the Muonio area, mortality of reindeer was increased with a high number of warm days in December. In the Kevo area, reindeer density or any climatic parameters could not explain yearly differences in mortality. This study indicated that permanent changes in climatic conditions could have different impacts in woodland as opposed to open, mountainous regions. In general, if global climatic change means weather instability in early winter and more snow, it also brings more difficulties for reindeer. However, if climate change means that snow melts earlier in the spring, some conditions could become more favourable for reindeer.     

Predicting the Peak in World Oil Production

The US Department of Energy's Energy Information Administration (EIA) recently predicted that world oil production could continue to increase for more than three decades, based on the recent US Geological Survey (USGS) evaluation of world oil resources and a simple, transparent model. However, it can be shown that this model is not consistent with actual oil production records in many different regions, particularly that of the US, from which it was derived. A more careful application of the EIA model, using the same resource estimates, indicates that at best non-OPEC oil production can increase for less than two decades, and should begin to decline at the latest sometime between 2015 and 2020. OPEC at this point will completely control the world oil market and will need to meet increased demand as well as compensate for declining production of non-OPEC producers. OPEC could control the market even sooner than this, given its larger share of proven oil reserves, probable difficulties in transforming non-OPEC undiscovered reserves into proven reserves, and the converging interests of all oil producers as reserves are depleted. This has significant implications for the world economy and for US national security.     

Beach–dune interactions on the dry–temperate Danube delta coast

Beach–dune seasonal elevation changes, aeolian sand transport measurements, bathymetric surveys and shoreline evolution assessments were used to investigate annual and seasonal patterns of dune development on Sfântu Gheorghe beach, the Danube delta coast, from 1997 to 2004. Dune volume increased consistently (1.96 m³ m^− 1 y^− 1 to 5.1 m³ m^− 1 y^− 1) over this 7-year period with higher rates in the southward (downdrift) direction. Dune aggradation is periodically limited by storms, each of which marks a new evolutionary phase of the beach–dune system. As a consequence of the variable beach morphology and vegetation density during a year, foredune growth occurs during the April–December interval while between December and April a slightly erosive tendency is present. The pattern of erosion and deposition shown by the topographical surveys is in good agreement with the sand transport measurements and demonstrates the presence of a vigorous sand flux over the foredunes which is 20–50% smaller than on the beach. This high sand flux, due to low precipitation and sparse vegetation cover, creates an aerodynamically efficient morphology on the seaward dune slope. The seaward dune face accretes during low to medium onshore winds (5.5–12 m s^− 1) and erodes during high winds (> 12 m s^− 1).     

Oxygen isotope systematics of gem corundum deposits in Madagascar: relevance for their geological origin

The oxygen isotopic composition of gem corundum was measured from 22 deposits and occurrences in Madagascar to provide a gemstone geological identification and characterization. Primary corundum deposits in Madagascar are hosted in magmatic (syenite and alkali basalt) and metamorphic rocks (gneiss, cordieritite, mafic and ultramafic rocks, marble, and calc-silicate rocks). In both domains the circulation of fluids, especially along shear zones for metamorphic deposits, provoked in situ transformation of the corundum host rocks with the formation of metasomatites such as phlogopite, sakenite, and corundumite. Secondary deposits (placers) are the most important economically and are contained in detrital basins and karsts. The oxygen isotopic ratios (¹⁸O/¹⁶O) of ruby and sapphire from primary deposits are a good indicator of their geological origin and reveal a wide range of δ¹⁸O (Vienna Standard Mean Ocean Water) between 1.3 and 15.6‰. Metamorphic rubies are defined by two groups of δ¹⁸O values in the range of 1.7 to 2.9‰ (cordieritite) and 3.8 to 6.1‰ (amphibolite). “Magmatic” rubies from pyroxenitic xenoliths contained in the alkali basalt of Soamiakatra have δ¹⁸O values ranging between 1.3 and 4.7‰. Sapphires are classified into two main groups with δ¹⁸O in the range of 4.7 to 9.0‰ (pyroxenite and feldspathic gneiss) and 10.7 to 15.6‰ (skarn in marble from Andranondambo). The δ¹⁸O values for gem corundum from secondary deposits have a wide spread between −0.3 and 16.5‰. The ruby and sapphire found in placers linked to alkali basalt environments in the northern and central regions of Madagascar have consistent δ¹⁸O values between 3.5 and 6.9‰. Ruby from the placers of Vatomandry and Andilamena has δ¹⁸O values of 5.9‰, and between 0.5 and 4.0‰, respectively. The placers of the Ilakaka area are characterized by a huge variety of colored sapphires and rubies, with δ¹⁸O values between −0.3 and 16.5‰, and their origin is debated. A comparison with oxygen isotope data obtained on gem corundum from Eastern Africa, India, and Sri Lanka is presented. Giant placer deposits from Sri Lanka, Madagascar, and Tanzania have a large variety of colored sapphires and rubies with a large variation in δ¹⁸O due to mingling of corundum of different origin: mafic and ultramafic rocks for ruby, desilicated pegmatites for blue sapphire, syenite for yellow, green, and blue sapphire, and skarn in marbles for blue sapphire.     

Single zircon ages of migmatitic gneisses and granulites in the Obudu Plateau: Timing of granulite-facies metamorphism in southeastern Nigeria

A single zircon geochronological study of gneisses from the Obudu Plateau of southeastern Nigeria, using the evaporation technique, indicates that zircons recorded several Precambrian high-grade metamorphic events (Eburnean and Pan-African). Igneous and multifaceted metamorphic zircons yielded ²⁰⁷Pb/²⁰⁶Pb ages of 2062.4 ± 0.4 Ma, 1803.8 ± 0.4 Ma and 574 ± 10 Ma, respectively and confirm for the first time that granulite-facies metamorphism affected the basement of southeastern Nigeria, resulting in the formation of charnockites and granulitic gneisses. The Pan-African high-grade event was coeval with the formation of granulites in Cameroon, Togo and Ghana and resulted from collisional processes during continental amalgamation to form the Gondwana supercontinent. The sources of the sediments, which were deposited at ≈605 Ma and metamorphosed at 574 Ma, comprise older igneous and metamorphic protoliths (including inherited xenocrystic zircons up to 2.5 Ga in age). The Palaeoproterozoic zircons seem to have survived Pan-African melting.     

Anisotropy in the continental upper mantle: possible evidence from explosion seismology

Summary. Peculiarities of propagation in the upper mantle of western Europe are documented by profiles of stations recording body waves generated by explosions. Azimuthal variations of travel times and amplitudes of P waves and possible birefringence of S waves may be associated with an anisotropic layer at depths where the lithosphere-asthenosphere transition is supposed to be.