The Bayesian approach to an internally consistent thermodynamic database: theory, database, and generation of phase diagrams

An internally consistent thermodynamic dataset has been derived for 148 endmember phases (145 solids and 3 fluids) comprising the elements Li, Na, K, Be, Mg, Ca, Ti, Cr, Mn, Fe, Zn, Al, Si, C, H, and O. This has been achieved by simultaneous treatment of phase property (like standard enthalpy of formation, standard entropy, molar heat capacity, molar volume, thermal expansivity, bulk modulus etc.) and reaction reversal data by the Bayesian method. The theory underlying the approach, and the computational methods involved, are briefly outlined. (For the benefit of readers unfamiliar with inference statistics, the basic concepts of the Bayes method are also presented in such a way that they can be grasped intuitively.) Although not yet addressed, this method can be extended to refine the thermodynamic mixing properties of crystalline solutions. The sources of the input data, culled from the literature, are summarized in the Appendix. The resulting database is succinctly documented in this paper. It includes the enthalpies of formation and entropies, their uncertainties, and the correlation among them. The database allows calculation of P-T, T-X _CO2, P-X _CO2, and T-f _O2 sections, with error propagation into the computed phase diagrams on a routine basis. A user-friendly computer program has been written to generate such phase diagrams. It is public domain software. The software and the thermodynamic database (which includes a complete documentation of the thermodynamic data above and beyond those listed (Table 2, here) may be downloaded from the web site http://homepage.ruhr-uni-bochum.de/niranjan.chatterjee/Index.htm. Examples of computed phase diagrams are given to illustrate the quality of the data and the capabilities of the software. Received: 11 March 1998 / Accepted: 11 June 1998     

Identity building and social transformation: the cases of Namibia and Botswana compared

Namibia and Botswana differ from other sub-Saharan nations in their record of stable political performance. However, both countries have to face increasing social problems. In the case of Namibia these are still mainly related to the process of post-apartheid national reconciliation and identity building, in the case of Botswana they refer to issues of growing tribal tensions and of a gradual interior restructuring of society. This paper analyzes the various patterns of social transformation in the two countries and examines in what ways state-society relations are different from other African nations. This revised version was published online in July 2006 with corrections to the Cover Date.     

Observations of Electromagnetically Coupled Dust in the Jovian Magnetosphere

We report on dust measurements obtained during the seventh orbit of the Galileo spacecraft about Jupiter. The most prominent features observed are highly time variable dust streams recorded throughout the Jovian system. The impact rate varied by more than an order of magnitude with a 5 and 10 hour periodicity, which shows a correlation with Galileo's position relative to the Jovian magnetic field. This behavior can be qualitatively explained by strong coupling of nanometer-sized dust to the Jovian magnetic field. In addition to the 5 and 10 h periodicities, a longer period which is compatible with Io's orbital period is evident in the dust impact rate. This feature indicates that Io most likely is the source of the dust streams. During a close (3,095 km altitude) flyby at Ganymede on 5 April 1997 an enhanced rate of dust impacts has been observed, which suggests that Ganymede is a source of ejecta particles. Within a distance of about 25 R_J(Jupiter radius, R_J= 71,492 km) from Jupiter impacts of micrometer-sized particles have been recorded which could be particles on bound orbits about Jupiter. This revised version was published online in July 2006 with corrections to the Cover Date.     

On the properties of strange modes

Properties of the so-called strange modes occurring in linear stability calculations of stellar models are discussed. The behaviour of these modes is compared for two different sets of stellar models, for very massive zero-age main-sequence stars and for luminous hydrogen-deficient stars, both with high luminosity-to-mass ratios. We have found that the peculiar behaviour of the frequencies of the strange modes with the change of a control parameter is caused by the pulsation amplitude of a particular eigenmode being strongly confined to the outer part of the envelope, around the density inversion zone. The frequency of a strange mode changes because the depth of the confinement zone changes with the control parameter. Weakly non-adiabatic strange modes tend to be overstable because the amplitude confinement quenches the effect of radiative damping. On the other hand, extremely non-adiabatic strange modes become overstable because the perturbation of radiation force (gradient of radiation pressure) provides a restoring force that can be out of phase with the density perturbation. We discuss this mechanism by using a plane-parallel two-zone model.     

Kepone®: Toxicity and bioaccumulation in blue crabs

Two long-term studies were conducted to determine toxicity, uptake and depuration of Kepone in blue crabs (Callinectes sapidus). In the first, Kepone was administered to crabs in seawater (0.03 or 0.3 μg Kepone/I) or food (eastern oyster,Crassostrea virginica, containing 0.25 μg/g Kepone). Uptake of Kepone in 28 days was primarily through the contaminated oysters. When these crabs were held in Kepone-free seawater and fed Kepone-free oysters for 28 days, no loss of the insecticide was evident. There were adverse effects on molting and survival in crabs fed oysters that contained 0.25 μg/g Kepone. A second study was conducted to determine: (1) the depuration of Kepone over a 90-day period in blue crabs fed oysters from the James River, Virginia (containing 0.15 μg/g Kepone); and (2) the effects of Kepone on molting and survival of blue crabs fed James River oysters or laboratory-contaminated oysters that contained 0.15 or 1.9 μg/g Kepone. Crabs fed Kepone-contaminated oysters followed by a diet of Kepone-free oysters for 90 days had detectable concentrations of the insecticide in tissues. Also, blue crabs that ate oysters containing Kepone in concentrations similar to those found in oysters from the James River, died or molted less frequently than crabs fed Kepone-free oysters meats.     

A Study of Ozone Laminae Using Diabatic Trajectories, Contour Advection and Photochemical Trajectory Model Simulations.

In this paper, we show that the rate of ozone loss in both polar and mid-latitudes, derived from ozonesonde and satellite data, has almost the same vertical distribution (although opposite sense) to that of ozone laminae abundance. Ozone laminae appear in the lower stratosphere soon after the polar vortex is established in autumn, increase in number throughout the winter and reach a maximum abundance in late winter or spring. We indicate a possible coupling between mid-winter, sudden stratospheric warmings (when the vortex is weakened or disrupted) and the abundance of ozone laminae using a 23-year record of ozonesonde data from the World Ozone Data Center in Canada combined with monthly-mean January polar temperatures at 30 hPa.Results are presented from an experiment conducted during the winter of 1994/95, in phase II of the Second European Stratospheric And Mid-latitude Experiment (SESAME), in which 93 ozone-enhanced laminae of polar origin observed by ozonesondes at different time and locations are linked by diabatic trajectories, enabling them to be probed twice or more. It is shown that, in general, ozone concentrations inside laminae fall progressively with time, mixing irreversibly with mid-latitude air on time-scales of a few weeks. A particular set of laminae which advected across Europe during mid February 1995 are examined in detail. These laminae were observed almost simultaneously at seven ozonesonde stations, providing information on their spatial scales. The development of these laminae has been modelled using the Contour Advection algorithm of Norton (1994), adding support to the concept that many laminae are extrusions of vortex air. Finally, a photochemical trajectory model is used to show that, if the air in the laminae is chemically activated, it will impact on mid-latitude ozone concentrations. An estimate is made of the potential number of ozone molecules lost each winter via this mechanism.     

The influence of sea waves on the wind profile

From wind profile and wave measurements performed during the JONSWAP II experiment, relations between the dimensionless profile slope and the significant wave height are derived. It is shown that the wind profile is distorted by the waves especially in the vicinity of the water surface. The wave influence on the profile seems to be restricted to heights below about three wave heights. Above this level, the dimensionless profile slope is an approximately constant value corresponding to a drag coefficient of about 1.15 × 10^–3.     

Noble gas investigations of lunar rocks 10017 and 10071

The noble gases He, Ne, Ar, Kr and Xe and also K and Ba were measured in the Apollo 11 igneous rocks 10017 and 10071, and in an ilmenite and two feldspar concentrates separated from rock 10071. Whole rock K/Ar ages of rocks 10017 and 10071 are (2350 ± 60) × 10⁶ yr and (2880 ± 60) × 10⁶ yr, respectively. The two feldspar concentrates of rock 10071 have distinctly higher ages: (3260 ± 60) × 10⁶ yr and (3350 ± 70) × 10⁶ yr. These ages are still 10 per cent lower than the Rb/Sr age obtained by Papanastassiouet al. (1970) and some Ar⁴⁰ diffusion loss must have occurred even in the relatively coarse-grained feldspar.The relative abundance patterns of spallation Ne, Ar, Kr and Xe are in agreement with the ratios predicted from meteoritic production rates. However, diffusion loss of spallation He³ is evident in the whole rock samples, and even more in the feldspar concentrates. The ilmenite shows little or no diffusion loss. The isotopic composition of spallation Kr and Xe is similar to the one observed in meteorites. Small, systematic differences in the spallation Kr spectra of rocks 10017 and 10071 are due to variations in the irradiation hardness (shielding). The Kr spallation spectra in the mineral concentrates are different from the whole rock spectra and also show individual variations, reflecting the differences in target element composition. The relative abundance of cosmic ray produced Xe¹³¹ differs by nearly 50 per cent in the two rocks. The other Xe isotopes show no variations of similar magnitude. The origin of the Xe¹³¹ yield variability is discussed.Kr⁸¹ was measured in all the samples investigated. The Kr⁸¹/Kr exposure ages of rocks 10017 and 10071 are (480 ± 25) × 10⁶ yr and (350 ± 15) × 10⁶ yr, respectively. Exposure ages derived from spallation Ne²¹, Ar³⁸, Kr⁸³ and Xe¹²⁶ are essentially in agreement with the Kr⁸¹/Kr ages. The age of rock 10071 might be somewhat low because of a possible recent exposure of our sample to solar flare particles.     

A record of long-time rift activity and earthquake-induced ground effects in Pleistocene deposits of southern Tenerife (Canary Islands,Spain)

Faults with a well-defined strike direction that precisely coincides with the southern rift fault system occur in the study area in southern Tenerife. This fault system was generated contemporaneously with a chain of cinder cones ~948 ka. Open fractures in ignimbrites (~668 ka) and fossil beach deposits (~42 ka) of the El Médano area suggest that the rift-associated fault system was seismically active in the aftermath of the initial volcanic activity (~948 ka) and is probably still active. A second fault system striking perpendicular to the rift-related faults probably originates from a Holocene paleoearthquake of moderate intensity. Earthquake-induced ground effects in fossil beach deposits within the study area are consistent with seismically induced ground effects of several recent and well-documented earthquakes, as well as gravitational sliding triggered by an intense earthquake in the Nicoya Peninsula of Costa Rica in 1990. Both, the rift-associated and the earthquake-induced fault system, initially produced open fractures that were occupied by plants and subsequently stabilized by cementation, forming conspicuous sediment structures in fossil beach deposits of the El Médano site in southern Tenerife.