Relative optical mass functions for air, water vapour, ozone and nitrogen dioxide in atmospheric models presenting different latitudinal and seasonal conditions

Summary A study of the dependence features of the relative optical mass functions for air, water vapour, ozone and nitrogen dioxide on the apparent solar zenith angle was performed by calculating these optical parameters by means of the well-known computer code LOWTRAN 7 at several values of and for nine atmospheric models characterized by different latitudes and seasons. Moreover, other investigations were performed on the dependence features of (i) the relative optical air mass on the thermal characteristics of the low troposphere, (ii) the relative optical water vapour mass on the vertical distribution characteristics of absolute humidity in the troposphere, and (iii) the relative optical mass function for ozone and nitrogen dioxide on the shape characteristics of the vertical profiles of the two gaseous concentrations and the concentration peak altitudes. The results are compared with the values given by the two simple formulas proposed by Kasten (1966) for air and water vapour and the formulas defined by Young (1969) and Staehelin et al. (1995) for ozone and nitrogen dioxide. From this comparison, a wide set of correction factors were obtained which can be conveniently used in the analysis of multispectral sun-radiometric measurements for calculating, with a very high precision, the values of the four optical mass functions at all the angles in the 0° to 87° range, corresponding to the various latitudinal and seasonal conditions described by the nine atmospheric models.With 9 Figures     

Validation of Ground-Based Visible Measurements of Total Ozone by Comparison with Dobson and Brewer Spectrophotometers

Comparisons of total column ozone measurements from Dobson, Brewer and SAOZ instruments are presented for the period 1990 to 1995 at seven stations covering the mid- and the high northern latitudes, as well as the Antarctic region. The main purpose of these comparisons is to assess, by reference to the well established Dobson network, the accuracy of the zenith-sky visible spectroscopy for the measurement of total ozone. The strengths and present limitations of this latter technique are investigated. As a general result, the different instruments are found to agree within a few percent at all stations, the best agreement being obtained at mid-latitudes. On average, for the mid-latitudes, SAOZ O₃ measurements are approximately 2% higher than Dobson ones, with a scatter of about 5%. At higher latitudes, both scatter and systematic deviation tend to increase. In all cases, the relative differences between SAOZ and Dobson or Brewer column ozone are characterised by a significant seasonal signal, the amplitude of which increases from about 2.5% at mid-latitude to a maximum of 7.5% at Faraday, Antarctica. Although it introduces a significant contribution to the seasonality at high latitude, the temperature sensitivity of the O₃ absorption coefficients of the Dobson and Brewer instruments is shown to be too small to account for the observed SAOZ/Dobson differences. Except for Faraday, these differences can however be largely reduced if SAOZ AMFs are calculated with realistic climatological profiles of ozone, pressure and temperature. Other sources of uncertainties that might affect the comparison are investigated. Evidence is found that the differences in the air masses sampled by the SAOZ and the other instruments contribute significantly to the scatter, and the impact of the tropospheric clouds on SAOZ measurements is displayed.     

Results from combining tectonic observations and SAR interferometry for the 1995 Grevena earthquake: A summary

Soon after the 1995 Grevena M_s = 6.6 event, we mapped the Palaeochori earthquake fault break. These tectonic observations are combined with the surface displacement field determined with the SAR interferometry to model the fault dislocation at depth.     

Microdeformation of lacustrine laminite sequences from Late Miocene formations of SE Spain: an interpretation of loop bedding

Lacustrine laminated sediments (laminites) present in Late Miocene formations of the Híjar Basin, SE Spain, display well developed loop bedding, a structure consisting of bundles of laminae that are sharply constricted at intervals, giving a morphology of loops or links of a chain. The laminite sequences, which are interbedded with turbidite marlstones, were accumulated on the bottom of a permanently stratified lake developed in a rapidly subsiding basin limited by 010° and 105° normal faults. As deduced from both macro- and microdeformational analyses, the basin evolved under an extensional stress field throughout the Late Miocene. Four main types of loops, simple and complex loops with subcategories, have been recognized within the laminite sequence. Simple loops of type 1 show the best definite pattern, quite similar to ' pinch and swell structures ', a type of boudinage typical of stretching of alternating beds where the competence contrast is not strongly marked. The remaining loop types display contortion and occasional breakage of laminae (microfaulted edges) indicative of microdeformation near the boundary between the ductile-brittle deformational fields. The distribution of the various loop types across the laminite sequence reflects an interplay between progressive lithification of the laminites as sedimentation progressed and tectonic stresses which affected the sediment sequence. Accordingly, a mechanism of deformation under an extensional stress field, ultimately related to the creep movement of the main basin faults which resulted in successive seismic shocks of low magnitude, is proposed to explain the formation of loop bedding in the laminites.     

Electronic and magnetic properties of a natural aegirine as observed from its Mössbauer spectra

A natural sample of aegirine, ideally NaFeSi₂O₆, has been studied by transmission Mössbauer spectroscopy in the range 4.2–480?K. At selected temperatures, a longitudinal external field of 60?kOe was applied to the absorber. The sample was observed to order magnetically at 11±1?K. The paramagnetic Mössbauer spectra (MS) show the presence of ～10% Fe²⁺ in the M1 sites of the clinopyroxene structure. These MS have been decomposed into four quadrupole doublets: two minor ones for Fe²⁺ on M1 sites, a dominant one due to Fe³⁺ on M1 sites, and a second ferric component, with a contribution of ～3% and attributable to the tetrahedral sites. Two possibilities concerning the origin of the two distinct Fe²⁺ (M1) doublets are discussed. They are respectively based on inter-valence charge transfer and on the existence of distinct Fe²⁺ orbital configurations at the two M1 sites. Neither of the two models could be firmly excluded. The asymmetry parameter η of the electric field gradient at the Fe³⁺ (M1) sites is close to 1.0 and the quadrupole splitting within 0.34±0.01?mm/s at all temperatures. The MS at 4.2?K shows an asymmetric hyperfine-field distribution for Fe³⁺, with a maximum-probability field of 468?kOe. The maximum-probability field for Fe²⁺ is found to be 220?kOe. The shape of the applied-field MS at 4.2?K implies a static antiferromagnetic ordering and was successfully interpreted by a bidimensional distribution of the magnitude and orientation of the hyperfine field. Finally, the temperature variations of the respective centre shifts and quadrupole splittings could be explained on the basis of existing theoretical models.     

Extragalactic source counts and contributions to the anisotropies of the cosmic microwave background: predictions for the Planck Surveyor mission

We present predictions for the counts of extragalactic sources, the contributions to fluctuations and their angular power spectrum in each channel foreseen for the Planck Surveyor (formerly COBRAS/SAMBA ) mission. The contribution to fluctuations owing to clustering of both radio and far-IR sources is found to be generally small in comparison with the Poisson term; however the relative importance of the clustering contribution increases and may eventually become dominant if sources are identified and subtracted down to faint flux limits. The central Planck frequency bands are expected to be 'clean': at high galactic latitude (| b | > 20°), where the reduced galactic noise does not prevent the detection of the extragalactic signal, only a tiny fraction of pixels is found to be contaminated by discrete extragalactic sources. Moreover, the 'flat' angular power spectrum of fluctuations resulting from extragalactic sources substantially differs from that of primordial fluctuations; therefore, the removal of contaminating signals is eased even at frequencies where point sources give a sizeable contribution to the foreground noise.     

Effect of Spectral Resolution on the Mg II Index as a Measure of Solar Variability

The solar Mgii core-to-wing ratio is a useful index of UV variability throughout the solar cycle because it has been measured since 1978 in a series of successive satellite missions: Nimbus 7, Solar Mesosphere Explorer (SME), the NOAA 9–14 series, Upper Atmosphere Research Satellite (UARS), and ERS-2. Eventual construction of a single time series from 1978 to the present by combining these measurements will give a long record of almost daily UV variability to serve as a surrogate for estimating both UV and EUV solar radiation. Here we address the effect of spectral resolution on determination of both long-term and short-term solar variability from this index. We use UARS/SOLSTICE measurements of the Mgii line from October 1991 to December 1996 to study the effect of two spectral resolution regimes characteristic of existing measurements, 0.20 to 0.25 nm and 1.10 to 1.15 nm, on determination of the amplitude of 27-day rotational modulation and the more gradual change in chromospheric radiation in the declining phase of solar cycle 22. The two Mgii indices give solar variations that differ by a scaling factor of 2× for both the solar cycle change from 1992 to 1997 and the amplitude of 27-day modulation over the same period. Both types of measurements appear to yield solar signal equally well except at solar minimum when the solar changes become quite small.     

Effect of hydrologic management on marsh surface sediment deposition in coastal Louisiana

High rates of coastal land loss in Louisiana have prompted efforts to maintain or restore coastal wetland habitats, and structural management of marsh hydrology is one of a number of approaches that has been adopted. The aim of this study was to determine the effect of hydrologic management measures on marsh-surface sediment deposition in the Mississippi deltaic plain. Four impoundments, ranging in size from 50 ha to 177 ha and similarly sized control sites were included in the study. At each site, marsh-surface sediment traps were collected approximately biweekly for 3.5 yr to measure changes in sediment deposition. There was no significant difference in sediment deposition between any of the impoundment and control sites during the premanagement period. The results show no significant difference in marsh-surface sediment deposition between management year 1992–1993 and management year 1994–1995, but management year 1993–1994 had significantly lower sediment deposition than either the first or the last year of the study. Management year 1992–1993 showed the highest sediment deposition when it was assessed across all basins, areas, and sites, and this high rate of deposition is accounted for by the impact of Hurricane Andrew. For all management years there were significant differences between impoundment and control sites, with control sites showing higher rates of marsh surface sediment deposition than impoundments. No clear pattern was identified concerning the influence of various types of hydrologic management on rates of sediment deposition. This reduction in sediment deposition indicated that the areas under management in this study are receiving insufficient inorganic sediment deposition to keep pace with sea-level rise.     

Carbonyls and nonmethane hydrocarbons at rural European sites from the mediterranean to the arctic

Results of regular measurements during 1992–1995 of hydrocarbons and carbonyl compounds for a number of rural European monitoring sites are presented. The measurements are part of the EMEP programme for VOC measurements in Europe. In addition, several years of regular measurements are included from the Norwegian stations Birkenes at the south coast, and Zeppelin Mountain on Spitsbergen in the Arctic. The sampling frequency has been about twice per week throughout the years, implying that a substantial amount of measurement data are available. Almost all the chemical analyses have been performed by one laboratory, the EMEP Chemical Co-ordinating Centre located at NILU, which avoids problems of intercomparison and intercalibration among different laboratories. For the measured concentrations both seasonal and geographical variations are shown and discussed. The diurnal cycles of the hydrocarbon concentrations were studied in detail at one site, where the grab samples by EMEP where compared with a parallel continuous sampler, operated by EMPA, Switzerland. Hydrocarbons linked to natural gas and fuel evaporation become well mixed into the Arctic in the winter, whereas combustion products show a latitudinal gradient. The sum of oxygenated species constitutes about 5–15% of the sum of C₂–C₅ hydrocarbons in winter. In summer they are almost equal in magnitude, consistent with an increasing oxidation of hydrocarbons.