Distribution and Influence of Iron Phases on the Physico—Chemical Properties of Phyllosilicates

Clay minerals from different Cretaceous stratigraphic successions of Egypt were investigated using XRD,DTA,dissolution analysis(DCB),IR,Moessbauer and X-band Electron Spin Resonance(ESR) spectroscopies.The purity of the samples and the degree of structural order were determined by XRD.The location of Fe in the octahedral sheet is characterized by absorption bands at-875cm^-1 assigned as Al-OH-Fe which is present after chemical dissolution of free iron.The Moessbauer spectra of these clays sow two doublets with isomer shift and quadrupole splitting typical of octahedral coordinated Fe^3 ,in addition to third doubler with hyperfine parameter typical of Fe^2 in the spectra of Abu-Had kaolinite (H)sample.6-lines magnetic hyperfine components which are consistent with those of hematite are confirmed in the spectra of both Isel and Rish kaolinite samples.Goethite was confirmed by both IR and DTA.Multiple nature of ESR of these clays suggested structural Fe in distorted octaedral symmetry and as non-structural Fe.Little dispersion and low swelling indices as well as incomplete activaiton of investigated montmorillonite samples by NaCO3 appear to be due to incomplete disaggregation of montmorillonite particles.This can be explained by the ability of Fe-gel to aggregate the montmorillonite into pseudo-particles and retard the rigid-gel structure.However,extraction of this ferric amorphous compound by dithonite treatment recovers the surface properties of the montmorillonite samples.On the other hand,amounts and site occupation of Fe associated with kaolinite samples show a negative correlation with the parameters used to describe the degree of crystalline perfection,color,brightness and vitrification range of these kaolinite samples.     

Les manifestations tectono-sédimentaires d'âge Campanien–Maastrichtien en Tunisie : implications sur l'évolution géodynamique de la marge Nord-AfricaineThe Campanian–Maastrichtian synsedimentary tectonic activity: implication in the geodynamic evolution of the North African Margin

The synsedimentary tectonic activity evidenced in central and northern Tunisia points out the fact that the Campanian–Maastrichtian deposits are associated with several NW–SE and east–west normal faults. These results suggest that the east–west transform fault of North African Margin is still active during this stage. These data allow us to discuss a new geodynamic model for the North African Margin. To cite this article: M. Dlala, C. R. Geoscience 334 (2002) 135–140.     

Very short-term behaviour of the flare star EV Lac

Sinusoidal variations in Johnson'sB-band of the flare star EV Lac have been confirmed at its quiet state luminosity. The cycle lengths are more than one hour and less than two hours with amplitudes varying from 0 _. ^m 105 to 0 _. ^m 306. These registered cycles have agreed with cycles detected by Mavridis and Varvoglis (1990) and Mavridis (1990). In the same time, the cycles have confirmed the light variation detection in Johnson'sV-band in the same flare star by Pettersen (1980) with a cyclic period equals about 4 _. ^d 378 and an amplitude of about 0 _. ^m 07. Our net results confirm, to some extent, the presence of active region(s) as an origin of stellar flare phenomenon of UV Ceti type flare stars. We can cautiously say that the solar and stellar flare phenomenon have a similar origin.     

Erosion and accretion rates and their associated sediment characters along Ras El Bar coast,northeast Nile Delta,Egypt

Beach profile data, covering the coast of Ras El Bar, northeast Nile Delta, collected during the years from 1990 to 2002 combined with landsat images for the area and sedimentological investigation have been used to identify beach and nearshore seafloor sediment changes. Along the coast of Ras El Bar, two accretion sectors and one of erosion have been recognized. The first accretion sector is located west of Damietta harbour, where the harbour jetties have halted the littoral transport, while the second one is behind a system of detached breakwaters protecting Ras El Bar resort. Both the two sectors are characterized by growing shoreline with maximum rates ∼15 and 10 m/year, respectively. Also, they have maximum nearshore seafloor accretion rates of ∼18 and 22 cm/year, respectively. The erosion sector is located east of Damietta port and has a maximum rate of shoreline retreat ∼−10 m/year. Erosion of its nearshore seafloor is indicated recording a maximum rate of ∼−20 cm/year. The rate of net sediment volume change in the area indicates shifting of the accretion sector (II) westward, responding to installation of the new breakwaters unit. The two accretion sectors are characterized by dominance of moderately sorted fine sands in their shore area which change seaward into less sorting very fine sands. Beach sands of the eroded sector are poorly sorted medium grain size. The dominant constituents of heavy mineral species in beach and sea-bottom sands are the characteristic assemblages of the Nile deposits. The sands of the eroded zone are relatively enriched in monazite, zircon, tourmaline, garnet, and rutile.     

Settlement of inhomogeneous consolidating soils—II: The symmetrically loaded mass

We continue our study of the consolidation of inhomogeneous clay soils with an analysis of the response of a soil mass, whose shear modulus increases linearly with depth, to axially symmetric pressure on its surface. This extends the work reported in Part I on the corresponding one-dimensional problem of a clay column, and generalizes researches of Gibson and coworkers on the elastic model of the soil (i.e., the initial response). Because of great mathematical complexity when Poisson's ratio is allowed to assume arbitrary values, we have confined ourselves (as did Gibson in several of his papers) to variations of the modulus from a zero surface value, this being in reasonable accord with published test results on London clay. The deflection of points within this region, the deflection relative to the central one (that is, the shape of the deformed loading area), as well as the absolute deflection of surface points exterior to the load.     

Stage–discharge estimation in straight compound channels using isovel contours

For various hydrological applications such as flood control projects, a knowledge of stage–discharge relationship is of particular interest to river engineers. Stage–discharge curves in compound channels cannot be easily predicted in comparison with single channels due to their 3D characteristics of flow. In this paper, the concept of cross‐sectional isovel contours is used for estimation of stage–discharge curves in compound channels. The multivariate Newton's method is applied to the difference between the observed and estimated data to optimize the exponent values of the governing parameters. The accuracy of the proposed model is tested successfully against available experimental results, which are taken from the Flood Channel Facility (FCF) laboratory. Then the results are compared with the Single and Divided Channel Methods (SCM and DCM, respectively), the Weighted Divided Channel Method (WDCM), the exchange discharge method (EDM), and the Coherence Method (COHM). The average values of mean absolute percentage error (MAPE) and normalized root mean square error (NRMSE) in discharge estimation based on each referenced section at any level for 6 sections of the experimental cases are within 3.1% and 0.023, respectively. The biggest advantage of the proposed method is its inherent simplicity, which does not need any calibration.     

Neoproterozoic granites of Sharm El-Sheikh area,Egypt: mineralogical and thermobarometric variations

Calc-alkaline and alkaline intrusions of the late Neoproterozic form essential part of the Arabian–Nubian Shield. They were formed during the collision between East- and West-Gondwana. Sharm El-Sheikh area, Sinai, includes wide compositional array of these intrusions that can be considered as a case study. Variations in both tectonic and thermobarometric condition for granitic intrusions are studied. Four mappable granitic types are recognized namely monzogranite, syenogranite, alkali feldspar granites, and riebeckite-bearing granites. The monzogranite and the syenogranite of the study area are mostly I-type, whereas the alkali feldspar granite and the riebeckite-bearing granite belong to A-type granitoid. The calc-alkaline intrusions were formed in compressional setting due to decompressional melting of mafic lower crust. Partial melting and anatexing of crustal rocks are suggested to explain the protolith of the alkaline intrusions. The transition from the calc-alkaline magma to the alkaline one occurred as a result of the tectonic transition from compression regime to tectonic relaxation (extension setting) during the last stage of the Pan-African Orogeny. The amphiboles of the studied granites are classified as calcic- and alkali-amphiboles. The calcic-amphiboles are ferro-edenite while the alkali-amphiboles are typically riebeckite. Both amphibole types are of magmatic nature. Coexisting amphiboles and plagioclases are used to estimate the physicochemical parameters of magma crystallization. The syenogranite underwent temperature and pressure of formation range of 520–730 °C, <3 kbar. The alkali feldspar granite records 450–830 °C, <4 kbar, while the riebeckite-bearing granite records the lowest temperature condition among all varieties and estimate formation at 350–650 °C, <4 kbar.     

User-centered road network traffic analysis with MobilityDB

Performance indicators of road networks are a long-lasting topic of research. Existing schemes assess network properties such as the average speed on road segments and the queuing time at intersections. The increasing availability of user trajectories, collected mainly using mobile phones with a variety of applications, creates opportunities for developing user-centered performance indicators. Performing such an analysis on big trajectory data sets remains a challenge for the existing data management systems, because they lack support for spatiotemporal trajectory data. This article presents an end-to-end solution, based on MobilityDB, a novel moving object database system that extends PostgreSQL with spatiotemporal data types and functions. A new class of indicators is proposed, focused on the users' experience. The indicators address the network design, the traffic flow, and the driving comfort of the motorists. Furthermore, these indicators are expressed as analytical MobilityDB queries over a big set of real vehicle trajectories.     

Askival: An altered feldspathic cumulate sample in Gale crater

Askival is a light-toned, coarsely crystalline float rock, which was identified near the base of Vera Rubin Ridge in Gale crater. We have studied Askival, principally with the ChemCam instrument but also using APXS compositional data and MAHLI images. Askival and an earlier identified sample, Bindi, represent two rare examples of feldspathic cumulate float rocks in Gale crater with >65% relict plagioclase. Bindi appears unaltered whereas Askival shows textural and compositional signatures of silicification, along with alkali remobilization and hydration. Askival likely experienced multiple stages of alteration, occurring first through acidic hydrolysis of metal cations, followed by deposition of silica and possible phyllosilicates at low T and neutral-alkaline pH. Through laser-induced breakdown spectroscopy compositional analyses and normative calculations, we suggest that an assemblage of Fe-Mg silicates including amphibole and pyroxene, Fe phases, and possibly Mg-rich phyllosilicate are present. Thermodynamic modeling of the more pristine Bindi composition predicts that amphibole and feldspar are stable within an upper crustal setting. This is consistent with the presence of amphibole in the parent igneous rocks of Askival and suggests that the paucity of amphiboles in other known Martian samples reflects the lack of representative samples of the Martian crust rather than their absence on Mars.     

CO<Subscript>2</Subscript> and He degassing at El Chichón volcano,Chiapas, Mexico: gas flux,origin and relationship with local and regional tectonics

During 2007–2008, three CO₂ flux surveys were performed on El Chichón volcanic lake, Chiapas, Mexico, with an additional survey in April 2008 covering the entire crater floor (including the lake). The mean CO₂ flux calculated by sequential Gaussian simulation from the lake was 1,190 (March 2007), 730 (December 2007) and 1,134 g m⁻² day⁻¹ (April 2008) with total emission rates of 164 ± 9.5 (March 2007), 59 ± 2.5 (December 2007) and 109 ± 6.6 t day⁻¹ (April 2008). The mean CO₂ flux estimated from the entire crater floor area was 1,102 g m⁻² day⁻¹ for April 2008 with a total emission rate of 144 ± 5.9 t day⁻¹. Significant change in CO₂ flux was not detected during the period of survey, and the mapping of the CO₂ flux highlighted lineaments reflecting the main local and regional tectonic patterns. The ³He/⁴He ratio (as high as 8.1 R _A) for gases in the El Chichón crater is generally higher than those observed at the neighbouring Transmexican Volcanic Belt and the Central American Volcanic Arc. The CO₂/³He ratios for the high ³He/⁴He gases tend to have the MORB-like values (1.41 × 10⁹), and the CO₂/³He ratios for the lower ³He/⁴He gases fall within the range for the arc-type gases. The high ³He/⁴He ratios, the MORB-like CO₂/³He ratios for the high ³He/⁴He gases and high proportion of MORB-CO₂ (M = 25 ±15%) at El Chichón indicate a greater depth for the generation of magma when compared to typical arc volcanoes.