Ophiolite remnants at the eastern margin of the Bohemian Massif and their bearing on the tectonic evolution

Summary Amphibolites are widespread in the eastern part of the Bohemian Massif, east of the South Bohemian Pluton. Based on their geological situation, their metamorphic evolution and their geochemistry, they were separated into three genetically different units: the Rehberg ophiolite, the Buschandlwand amphibolite and the Raabs group. The metamorphic Rehberg ophiolite consists of a ultramafic to mafic plutonic sequence overlain by a gabbro/dike complex and a volcanic section with basaltic, andesitic and rhyolitic volcanics associated with pelitic to psammitic sediments. The entire ophiolite underwent amphibolite facies metamorphism. Rock/MORB normalisation plots and other element ratio plots, such as Ti vs. V or Ta/Yb vs. Th/Yb argue for a supra-subduction zone environment as site of the origin of the Rehberg ophiolite. The Letovice ophiolite in Moravia is structured in a similar way. Geochemically it shows a more MORB like composition but also a distinct tholeiitic island arc group. Although there is no age data for the protolith of both ophiolites, it is believed that they have formed in an oceanic basin separating the Brunovistulian-Moravian block to the east and the Moldanubian block to the west. Possible traces of the continuation of the ophiolites towards the north can be found in the Stare Mesto ophiolites and the ophiolites surrounding the Sowie Gory block in the Sudetes.

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Ophiolitrelikte am ostrand der Böhmischen Masse und ihre bedeutung für die tektonische entwicklung

Zusammenfassung Amphibolite sind in der Böhmischen Masse, östlich des Südböhmischen Plutons weit verbreitet. Ausgehend von ihrer geologischen Position, ihrer metamorphen Entwick lung und ihrer Geochemie lassen sie sich in drei genetisch unterschiedliche Einheiten teilen: den Rehberg Ophiolith, den Buschandlwand Amphibolit und die Raabser Gruppe. Der metamorphe Rehberg Ophiolith besteht aus einer ultramatischen bis mafischen plutonischen Abfolge, die von einem Gabbro/Gangkomplex überlagert wird und einer vulkanischen Folge mit Basalten, Andesiten and Rhyoliten, die mit tonigen und sandigen Sedimenten verknüpft sind. Der gesamte Ophiolithkörper wurde unter amphibolitfaziellen Bedingungen metamorph überprägt. Rock/MORB Diagramme und andere Elementdarstellungen, wie z.B. das Ti vs. V, oder das Ta/Yb vs. Th/Yb Diagramm sprechen für eine Entstehung des Rehberg Ophioliths in einer Suprasubduction Zone. Der Letovice Ophiolith in Mähren weist eine ähnliche Struktur auf. Geochemisch zeigt er stärkere Ähnlichkeiten mit MORB, enthält aber auch Elemente von tholeiitischen Inselbogenbasalten. Auch wenn es für beide Ophiolithe noch keine Protolith-Altersdaten gibt, scheint es dennoch wahrscheinlich, daß sie in einem Ozeanbecken, das den Brunovistulisch-Moravischen Kontinentalblock im Osten vom Moldanubischen Kontinent im Westen trennt, gebildet wurden. Die mögliche Fortsetzung beider Ophiolithe könnten im Norden der Stare Mesto Ophiolith und die Ophiolithe rund um den Sowie Gory Block in den Sudeten darstellen.

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With 7 Figures     

Automated AF-demagnetization on the 2G-Enterprises through-bore,cryogenic magnetometer

Since the early sixties, alternating field demagnetization (AFD) has been a standard laboratory technique for demagnetizing rocks to expose the multicomponent structure of their natural remanent magnetization (NRM). In the majority of AFD implementations, however, the procedure remains as labour-intensive as ever. The implementation that we have developed at the Australian Geological Survey Organisation, automates the procedure for AFD based on the static method, and results in significant productivity and efficiency gains without compromising data quality. A properly formulated procedure for static AFD may be the only method of retrieving higher-coercivity components of natural remanence in samples prone to developing gyroremanence at higher alternating fields (AFs). Our AFD environment comprises: a 2G-Enterprises through-bore, cryogenic magnetometer; 2G AF-coils and control equipment; and personal computer software, developed by us, to control all procedural aspects for a complete AFD of a sample including, importantly, a counteracting procedure to neutralize the effects of gyroremanence build-up at higher AFs. With our system, AFD of 8 samples/day, each of 20+ steps, requires only 20 min of user attention compared with a full day for conventional systems.     

The economic restructuring of Moscow in the international context

This paper deals with the trends of economic restructuring in Moscow in the 1990s under globalization and reforms. The comparison of structural shifts in Moscow with the largest cities of the West gives an idea about the position of the Russian capital on the trajectory of post-industrial transformation. The analysis covers three dimensions: a) general trends of post-industrial restructuring, b) the role of large cities in national economies, and c) universal and special trends of intra-urban transformation. The reforms of the 1990s initiated many new developments in the economic life of Moscow, making it more similar to the Western cities, both in general sectoral structure and intra-urban landscape. Nevertheless, Moscow still lags far behind the world cities as regards the stage of the most important post-industrial processes. The conflict between new market developments and the inherited patterns of the socialist city becomes one of the driving forces of the economic transformation in Moscow as a whole and in different types of its districts.     

Trough structures in the Western syenite of Kûngnât, S Greenland: mineralogy and mechanism of formation

In the Western layered syenite stock of the Kûngnât complex, close to the intrusion wall, there are two groups of regularly spaced, horizontally aligned, stacks of infilled troughs. These features resemble, to some extent, the trough layering within the UZa trough zone of the gabbroic Skaergaard¹ intrusion. Such features have never before been described in syenitic rocks. The lower group comprises six stacks of infilled troughs; the upper group comprises seven. The two groups are vertically separated by about 10 m of sparsely layered syenite. The infilled troughs in the upper group are stacked vertically; those in the lower group gradually shift laterally and appear to converge over an antiformal structure. It is not possible to measure the plunge of the troughs due to outcrop geometry. Troughs are up to about 80 cm deep. The material filling the troughs is more melanocratic than the syenite that surrounds them. Individual troughs exhibit normal grading. The syenite within the troughs contains large amphibole and biotite oikocrysts. Faintly layered syenite occurs laterally between stacks. Minerals in the host syenite are more ferroan than those in the troughs, this is thought to represent re-equilibration with residual melt. Feldspar textures, irregular pyroxene and apatite zoning, and the presence of irregular shaped amphibole patches within pyroxene grains all imply alteration by a pervasive deuteric fluid in both troughs and host syenite. We suggest the following hypothesis for the formation of the troughs. A mafic crystal sheath which grows on the walls of the magma chamber becomes detached and flows downwards. The descending slurry forms a series of regularly spaced streams which erode trough shaped channels into the crystal pile at the base of the chamber. Uneroded crystal material separates the channels. Crystals are deposited from these streams. Successive streams flow over each other to generate stacks of troughs.     

Metropolitan growth and labor markets in Mexico

The objective of this paper is to examine the main changes in the metropolitan labor markets associated with economic restructuring in Mexico during the late 1980s and beginning of the 1990s. The analysis refers particularly to the four largest metropoles of the country, Mexico City, Guadalajara, Monterrey and Puebla, looking for common characteristics in their emergent employment structures now strongly differentiated in terms of rewards, stability in employment relations and conditions of access to jobs. The analysis reveals that largest metropolitan areas have been the most profoundly affected by the economic restructuring resulting from globalization, through a rapid de-industrialization and the expansion of the tertiary sector. Metropolitan labor markets in Mexico, at the time that show signs of social polarization in the formal sector, put in evidence a general process of precarization – less labor stability, replacement of permanent by part-time jobs, and increasing subcontracting –, segmentation of the labor force, and an increasing informal conditions of economic activities with small businesses and unskilled, temporarly and poorly paid jobs. The labor force segmentation and its more precarious and casual conditions are mostly explained by the impact of recent neoliberal policies, and recurrent economic crisis during the 1980s and 1990s which highly contributes to social inequality.     

THE IMPORTANCE OF TOPOGRAPHIC CORRECTIONS ON MAGNETOTELLURIC RESPONSE DATA FROM RUGGED REGIONS OF ANATOLIA

Topographic irregularities cause some distortions of magnetotelluric (MT) fields. In the vicinity of a topographic feature, the TM-mode distortion increases with the height and inclination of the slope. It is well-known that TM-mode ( E _⊥) topographic effects are much greater than TE-mode ( E _ı) distortions.   We have made a study of MT anomalies in TM-mode due to two-dimensional topography. In order to reduce these effects, the distortion tensor stripping technique was used. After corrections, the resulting data can be interpreted as if they were obtained over a flat surface and depend only on the subsurface structure. However, this technique sometimes causes some geometrical distortions of the real subsurface structure.   One of our aims is to overcome this failure. We have modified the correction coefficients by considering the actual one-dimensional geology. Model studies showed that our approach is especially useful in removing the terrain effects on complex 2D subsurface structures.   The other purpose of this study is to emphasize the importance of a proper terrain correction for data from sites having mountainous topography over complex geology, e.g. strike-slip faults, suture zones and rift valleys. Some examples of MT data sets collected from the North Anatolian Fault Zone and from the thrust regions of the Western Taurides will be presented.     

Untersuchung der Sorptionseigenschaften des Kationenaustauschers KB-2M mit Makronetzstruktur zur Abtrennung von Zinkionen aus Ab- und Spülwässern

Study of Sorptional Properties of the Cation Exchanger KB-2M with Macroreticular Structure for Recovery of Zinc Ions from Sewage and Rinsing Water Although a number of ion-exchange methods have been employed for the recovery of some transition metals from industrial effluents, knowledge about ion-exchange resins with macroreticular structure is poor. The present paper describes the mechanism of sorption on such exchangers and their application for recovery of zinc from sewage rinsing water. Ion exchanger of macroreticular structure are polymers with long-chained cross-linking agents. We have synthesized carboxylic ion-exchange resins by hydrolysis of copolymerisates of methyl acrylate with different cross-linking agents: divinylbenzene, divinyl sulfide, divinyl ester of ethylene glycol and divinyl ester of di- or triethylene glycol. The sorption process on modifications of the carboxylic resins KB-2 of various structure was studied with different methods: potentiometric titration, infrared spectroscopy, electron microscopy, X-ray structural analysis. The initial zinc concentration in rinsing water was 0.05 mol/L at pH from 3 to 6. For the sorption, 0.2…1.0 g of resin were equilibrated with 100 mL of zinc solution. After equilibrium (12 h), the resin was separated from solution. The zinc ions were determined by atomic absorption spectrometry after stripping with 100 mL of 10% sulfuric acid. The distribution ratio D was calculated (D: mmole of Zn sorbed per gram of resin divided by mmole of Zn per millilitre of solution). By means of infrared spectroscopy, the mechanism of sorption of zinc ions from rinsing water was determined. There may be a possibility of the formation of complexes in the cation-exchange resin phase. It was found out in this paper that the cation-exchanger KB-2M of macroreticular structure is the most effective for the sorption of the Zn²⁺-ions from sewage and rinsing water.     

The effect of sea-ice extent in the North Atlantic on the stability of the thermohaline circulation in global warming experiments

Different climate models simulate different behavior of the Atlantic meridional overturning circulation (MOC) under the same global warming scenario. We propose a plausible explanation for this and argue that a proper simulation of the present-day climate in the subpolar North Atlantic is important. This is illustrated using results from idealized global warming experiments, in which both the radiative forcing scenario and the model employed are the same, with the only major difference being the initial subpolar North Atlantic climate. The initial conditions are made progressively colder, with more extensive sea-ice cover in the northern North Atlantic.The key result is that starting from conditions which are too cold in the North Atlantic and with sea-ice that is too extensive leads to an MOC that is more stable to the radiative forcing. Furthermore, under considerably underestimated sea surface temperatures in subpolar regions, the MOC can even intensify. A reduction of freshwater flux associated with the reduction of sea-ice melt is shown to be important for such unusual behavior of the MOC. Other mechanisms are also considered, but not deemed as important in explaining published inter-model differences.     

Empirical Orthogonal Function (EOF) analysis of monsoon rainfall and satellite-observed outgoing long-wave radiation for Indian monsoon: a comparative study

Summary The present study involves the use of Empirical Orthogonal Function (EOF) analysis/Principal Component Analysis (PCA) to compare the dominant rainfall patterns from normal rainfall records over India, coupled with the major modes of the Outgoing Long-wave Radiation (OLR) data for the period (1979–1988) during the monsoon period (June–September). To understand the intraseasonal and interannual variability of the monsoon rainfall, daily and seasonal anomalies have been obtained by using the (EOF) analysis. Importantly, pattern characteristics of seasonal monsoon rainfall covering 68 stations in India are highlighted.The purpose is to ascertain the nature of rainfall distribution over the Indian continent. Based on this, the percentage of variance for both the rainfall and OLR data is examined. OLR has a higher spatial coherence than rainfall. The first principal component of rainfall data shows high positive values, which are concentrated over northeast as well as southeast, whereas for the OLR, the area of large positive values is concentrated over northwest and lower value over south India apart from the Indian ocean. The first five principal components explain 92.20% of the total variance for the rainfall and 99.50% of the total variance for the outgoing long-wave radiation. The relationship between monsoon rainfall and Southern Oscillations has also been examined and for the Southern Oscillations, it is 0.69 for the monsoon season. The El-Niño events mostly occurred during Southern Oscillations, i.e. Walker circulation. It has been found that the average number of low pressure system/low pressure system days play an important role during active (flood) or inactive (drought) monsoon year, but low pressure system days play more important role in comparison to low pressure systems and their ratio are (16:51) and (13:25) respectively. Significantly, the analysis identifies the spatial and temporal pattern characteristics of possible physical significance.     

A reexamination of the valley wind system in the Alpine Inn Valley with numerical simulations

Summary This paper presents idealized numerical simulations of the valley wind circulation in the Alpine Inn Valley, which are compared with existing data and are used to improve our dynamical understanding of the valley wind. The simulations have been performed with the Penn State/NCAR mesoscale model MM5. They use a high-resolution realistic topography but idealized large-scale conditions without any synoptic forcing to focus on the thermally induced valley wind system. The comparison with the available observations shows that this simplified set-up is sufficient to reproduce the essential features of the valley wind.The results show that the tributaries of the Inn Valley have a considerable impact on the along-valley mass fluxes associated with the valley wind circulation. The upvalley mass flux is found to increase where tributaries enter the Inn Valley from the north, that is, from the direction where the Alpine foreland is located. On the other hand, the upvalley mass flux is reduced at the junctions with southern tributaries because part of the upvalley flow is deflected into these tributaries. For the downvalley flow, the situation is essentially reversed, but the influence of the valley geometry on the flow structure is larger than for the upvalley flow. The most important feature is a lateral valley contraction near the valley exit into the Alpine foreland. It reduces the downvalley mass flux at low levels, so that the wind maximum in the interior of the valley is shifted to a fairly large distance from the ground. North of the valley contraction, however, the downvalley flow strongly accelerates and forms a pronounced low-level jet. A dynamical analysis indicates that this acceleration can be interpreted as a transition from subcritical to supercritical hydraulic flow. Another interesting feature is that the low-level jet maintains its structure for several tenths of kilometres into the Alpine foreland. This appears to be related to the fact that the lateral wind shear on the flanks of the jet is associated with a strong dipole of potential vorticity (PV). Due to the conservation properties of the PV, the downstream advection of the PV dipole leads to the formation of a band-like feature that decays fairly slowly.