Determination of Multiple Trace Element Compositions in Thin (> 30 μm) Layers of NIST SRM 614 and 616 Using Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry (LA-ICP-MS)

To understand and/or avoid small-scale chemical heterogeneities within geological materials prepared as normal thin sections, in situ multiple trace element determination coupled with the simultaneous microscopic observation of the sample during analysis is preferable. We have examined fifty trace elements in thin (< 30 μm) layers of the NIST SRM 614 and 616 glass reference materials by LA-ICP-MS using different pit diameters and internal standard elements (Ca and Si). Compositional heterogeneities of Tl, Bi, As and Cd were found in NIST SRM 614 and 616 at the spatial resolution of ca. 10 0 μm. Except for these elements, the RSDs of six determinations for most elements were better than 10% in NIST SRM 614 when ablation diameters were < 50 μm. The measured concentrations for most elements in NIST SRM 614 and 616 agree with previous values in the literature at the 95% confidence level with the exception of W and Bi. New LA-ICP-MS data for K, As and Cd are also reported. The results support the view that the latest LA-ICP-MS is a powerful and flexible analytical technique for the determination of multiple ultra-trace element compositions in geological materials prepared as normal thin sections of the type that has been used for polarising optical microscopic observations since the end of the 19th century.     

Orogenic Lherzolites and Mantle Processes: Editorial

The papers in this thematic issue of Journal of Petrology weredelivered at the Fourth International Workshop on Orogenic Lherzolitesand Mantle Processes, which was held in Samani, Hokkaido, Japan,between August 26 and September 3, 2002. Fifty oral presentationswere given and 45 posters were displayed during the meeting,and the research papers in this issue provide an     

Complete mantle section of a slow-spreading ridge-derived ophiolite: An example from the Isabela ophiolite in the Philippines

Abstract   The Isabela ophiolite shows a complete ophiolite sequence exposed along the eastern coast of northern Luzon, the Philippines. It forms the Cretaceous basement complex for the northeastern Luzon block. This ophiolite is located at the northern end of a trail of ophiolites and ophiolitic bodies along the eastern margin of the Philippine Mobile Belt. This paper presents new findings regarding the nature and characteristics of the Isabela ophiolite. Peridotites from the Isabela ophiolite are relatively fresh and are composed of spinel lherzolites, clinopyroxene-rich harzburgites, depleted harzburgites and dunites. The modal composition, especially the pyroxene content, defines a northward depletion trend from fertile lherzolite to clinopyroxene-rich harzburgites and more refractory harzburgites. Variation in modal composition is accompanied by petrographic textural variations. The chromium number of spinel, an indicator of the degree of partial melting, concurs with petrographic observations. Furthermore, the Isabela ophiolite peridotites are similar in spinel and olivine major-element geochemistry and clinopyroxene rare earth-element composition to abyssal peridotites from modern mid-oceanic ridges. Petrological and mineral compositions suggest that the Isabela ophiolite is a transitional ophiolite subtype, with the fertile lherzolites representing lower sections of the mantle column that are usually absent in most ophiolitic massifs. The occurrence of the fertile peridotite presents a rare opportunity to document the lower sections of the ophiolitic mantle. The variability in composition of the peridotites in one continuous mantle section may also represent a good analogy of the melting column in the present-day mid-oceanic ridges.     

WinASEAN for remote sensing data analysis

The image analysis system ASEAN (Advanced System for Environmental ANalysis with Remote Sensing Data) was designed and programmed by a software development group, ImaSOFr, Department of Remote Sensing Technology and GIS, Institute for Geography, National Centre for Natural Science and Technology of Vietnam under technical cooperation with the Remote Sensing Technology Centre of Japan and financial support from the National Space Development Agency of Japan. ASEAN has been in continuous development since 1989, with different versions ranging from the simplest one for MS-DOS with standard VGA 320×200×256 colours, through versions supporting SpeedStar 1.0 and SpeedStar PRO 2.0 true colour graphics cards, up to the latest version named WinASEAN, which is designed for the Windows 3.1 operating system. The most remarkable feature of WinASEAN is the use of algorithms that speed up the image analysis process, even on PC platforms. Today WinASEAN is continuously improved in cooperation with NASDA (National Space Development Agency of Japan), RESTEC (Remote Sensing Technology Center of Japan) and released as public domain software for training, research and education through the Regional Remote Sensing Seminar on Tropical Eco-system Management which is organised by NASDA and ESCAR In this paper, the authors describe the functionality of WinASEAN, some of the relevant analysis algorithms, and discuss its possibilities of computer-assisted teaching and training of remote sensing.     

Re–Os isotope systematics for the Lince–Estefanía deposit: constraints on the timing and source of copper mineralization in a stratabound copper deposit, Coastal Cordillera of Northern Chile

The Lince–Estefanía stratabound copper deposit in the Michilla district is one of the most important deposits in the Coastal Cordillera of northern Chile and is one of the most representative of this type of deposit. Chalcocite and bornite characterize the main stage of hypogene copper sulfide mineralization. Rhenium and osmium isotopes are used here to constrain the age of hypogene mineralization and the source of osmium contained in these ore minerals. A Re–Os isochron yielded an age of 160±16 Ma (2σ), with an associated initial ¹⁸⁷Os/¹⁸⁸Os ratio of 1.06±0.09 (mean square of weighted deviates=1.8). This age is consistent with available geochronological data from volcanic rocks that host the mineralization and associated alteration phases. The high initial ¹⁸⁷Os/¹⁸⁸Os ratio indicates a lower crustal component for the source of Os and, by inference, the Cu sulfides that contain this Os. Late hematite occurs as an isolated phase or, more commonly, is associated with the chalcocite–bornite and supergene chalcocite–covellite associations. Analyses performed on pure hematite indicate a disturbance of the Re–Os system, and hence, this mineral phase is not useful as a Re–Os geochronometer.     

Advanced Micro-XRF Method to Separate Sedimentary Rhythms and Event Layers in Sediments: Its Application to Lacustrine Sediment from Lake Suigetsu,Japan

Event-related sedimentary layers, which are deposited occasionally due to volcanic eruptions, earthquakes or heavy rains, are often contained in the rhythmical sequences of lacustrine and marine sediments. We have developed an analytical method for separating the sedimentary rhythms and the event layers identified using the scanning X-ray analytical microscope (SXAM) and obtained sequential profiles of seven elements Al, Si, K, Ca, Ti, Mn, and Fe in the lacustrine sediment from Lake Suigetsu, Japan. Two types of event layers could be detected from the elemental composition of 33 layers of sediment: three known volcanic ash layers and 30 clay layers containing 12 turbidites. The recurrence interval of the latter, which may potentially be initiated and archived by locally important earthquakes, is estimated to be an average of 640 ± 160 years by using Sompi event analysis (SEA) based on an autoregressive (AR) model. After removing those portions that represented event layers from the elemental profiles, we obtained event-removed (ER) temporal profiles based on the tephrochronology of the three volcanic ash layers. The ER temporal profiles of manganese and iron, probably representing the siderite content, showed a millennial-scale variation in the Holocene that corresponded well with ice-rafting events in the North Atlantic.     

Persistence of road runoff generation in a logged catchment in Peninsular Malaysia

Measurements of saturated hydraulic conductivity (K_s) and diagnostic model simulations show that all types of logging road/trail in the 14·4 ha Bukit Tarek Experimental Catchment 3 (BTEC3) generate substantial Horton overland flow (HOF) during most storms, regardless of design and level of trafficking. Near‐surface K_s(0–0·05 m) on the main logging road, skid trails and newly constructed logging terraces was less than 1, 2 and 34 mm h^?1, respectively. Near‐surface K_s on an abandoned skid trail in an adjacent basin was higher (62 mm h^?1), owing to the development of a thin organic‐rich layer on the running surface over the past 40 years. Saturated hydraulic conductivity measured at 0·25 m below the surface of all roads was not different (all <6 mm h^?1) and corresponded to the K_s of the adjacent hillslope subsoil, as most roads were excavated into the regolith more than 0·5–1 m. After 40 years, only limited recovery in near‐surface K_s occurred on the abandoned skid trail. This road generated HOF after the storage capacity of the upper near‐surface layer was exceeded during events larger than about 20 mm. Thus, excavation into low‐K_s substrate had a greater influence on the persistence of surface runoff production than did surface compaction by machinery during construction and subsequent use during logging operations. Overland flow on BTEC3 roads was also augmented by the interception of shallow subsurface flow traveling along the soil–saprolite/bedrock interface and return flow emerging from the cutbank through shallow biogenic pipes. The most feasible strategy for reducing long‐term road‐related impacts in BTEC3 is limiting the depth of excavation and designing a more efficient road network, including minimizing the length and connectivity of roads and skid trails. Copyright © 2007 John Wiley & Sons, Ltd.     

Deep and Bottom Currents in the Challenger Deep,Mariana Trench,Measured with Super-Deep Current Meters

The bottom currents in the Challenger Deep, the deepest in the world, were measured with super-deep current meters moored at 11°22′ N and 142°35′ E, where the depth is 10915 m. Three current meters were set at 9687 m, 10489 m and 10890 m at the station in the center of the Challenger Deep for 442 days from 1 August 1995 to 16 October 1996. Although rotor revolutions in 60 minutes of recording interval were zero for 37.5% of the time, the maximum current at the deepest layer of 10890 m was 8.1 cm s⁻¹, being composed of tidal currents, inertia motion and long period variations. Two current meters were set at 6608 m and 7009 m at a station 24.9 km north of the center for 443 days from 31 July 1995 to 16 October 1996, and two current meters at 6214 m and 6615 m at a station 40.9 km south of the center for 441 days from 2 August 1995 to 16 October 1996. The mean flow at 7009 m depth at the northern station was 0.7 cm s⁻¹ to 240°T, and that at 6615 m depth at the southern station was 0.5 cm s⁻¹ to 267°T. A westward mean flow prevailed at the stations, and no cyclonic circulation with mean flows of the opposite directions was observed in the Mariana Trench at a longitude of 142°35′ E. Power spectra of daily mean currents showed three spectral peaks at periods of 100 days, 28–32 days and 14–15 days. The peak at 100 day period was common to the power spectra.