Isothermal compression of low-cordierite to 30 kbar (25° C)

The compression of cordierite (Mg, Fe)₂Al₄Si₅O₁₈·n (H₂O, CO₂; Na⁺, K⁺) has been studied up to 30 kbar (25° C) by volumetric measurements with a piston cylinder apparatus and by X-ray measurements with a diamond-anvil cell. Natural cordierite of intermediate Mg-Fe composition and synthetic Mg-cordierite served as samples. Two discontinuities at 2.2±0.3 and 9.0±0.6 kbar which are correlated with very small volume changes (0.3?0.05%) have been found. The X-ray data indicate, however, no symmetry change of the crystal structure. The two discontinuities are interpreted as phase transitions. The two discontinuities establish three pressure dependent phases referred to as low-pressure (LP)-, first high-pressure (HP1)- and second high-pressure (HP2)-phase. The gross compressibility of cordierite decreases from 1.1 Mbar^?1 at low pressure to 0.7 Mbar^?1 at 30 kbar for the intermediate Mg-Fe cordierite, and to 0.4 Mbar^?1 for Mg-cordierite. Depending on the pressure transmitting medium used in the two different compression techniques, two kinds of compression behavior are observed for cordierite. The measurements with the piston cylinder apparatus where lead is used as quasihydrostatic pressure medium indicate normal compression properties. The X-ray data, however, obtained with the diamond anvil cell where a methanol-ethanol mixture provides hydrostatic pressure conditions yield, e.g. for the HP1-phase a dramatic decrease in compressibility to almost zero. IR-spectra from samples of augmenting experiments with methanol, deuteromethanol and D₂O as pressure media indicate that pressure media of which the molecule size is comparable with the dimensions of the cordierite channels may be incorporated in the structure. This suggests that under such hydrostatic conditions the compression of cordierite is modified by a structure internal component which is acting via the channel system.     

Das Relief des Mars' Versuch einer zusammenfassenden Übersicht

The analysis of the martian relief leads to the conclusion that some of the most important relief elements are either concentrically or radially arranged with respect to a central structure and hence form aureoles. In this paper four different types of aureoles are identified and described:

1. impact aureoles (as result of extradynamics),
2. volcanic aureoeles (as result of lava flow through vents),
3. tectonic aureoles (as result of isostatic adjustment and/or settlement),
4. permafrost-related aureoles and mega-aureoles (as result of migration above thawing permafrost in areas with high relief).

The spatial distribution of these different types of aureoles indicates the predominant type of relief-forming dynamics in the area of their distribution (impact-related aureoles occur predominantly in the area of the Southern Uplands; volcanic, tectonic and permafrost-related aureoles in the area of large-scale updomings-TaNoVa, Elysiumand their volcanic provinces).     

Characteristics of a planar rock slide: Hamersley range, Western Australia

A large planar rock slide in the Hamersley Range, Western Australia, is described and analysed for possible causes of failure. The general characteristics of the slide are determined by the major joint sets. The rock mass consists predominantly of alternating massive chert members and argillaceous horizons—giving the rock mass a distinctive flaggy appearance. The failure plane dips at 17° and is coincident with a shale horizon. Because of the low inclination of the failure plane factors of safety less than one cannot be obtained from limiting-equilibrium hindcast estimates, unless high joint-water pressures and/or seismic loading are invoked. But while the operation of these two factors cannot be totally ruled out, the field evidence suggests that the necessary conditions for failure were due to the weathering out of shale horizons which could have led to “adjustments” of the rock mass, giving rise to dynamic loading conditions along potential failure planes.     

A deuterium-hydrogen fractionation mechanism in magnesium oxide

Water dissolved in a nominally anhydrous oxide like MgO forms not only OH^? ions, as is usually assumed, but also molecular H₂ and peroxy anions O₂^2?. The specific lattice site where this reaction occurs has been identified for the model-type MgO structure: it is the fully OH^? compensated cation vacancy. In partially deuterated synthetic MgO, molecular D₂ forms preferentially to H₂, by a factor of the order of 4. Three methods have been used to study this very large D/H fractionation experimentally: mass spectrometry, electron spin resonance and infrared spectroscopy. All give consistent results and confirm that internal D/H fractionation occurs and is a function of the temperature. Theoretically the D/H fractionation is explained by the lower zeropoint energy of D₂ with respect to H₂, amplified by secondary processes through which the molecular hydrogen species become mobilized and eventually lost via diffusion. The possible consequences of such internal D/H fractionation processes are indicated for the interpretation of water and hydrogen release patterns, with varying D/H ratios, from terrestrial and extraterrestrial samples.     

Velocity constraints for the inner core inferred from long-period PKP amplitudes

Long-period PKP amplitudes from 16 earthquakes in the distance range 110– 170° are compared with theoretical amplitudes which are derived from synthetic seismograms calculated for 56 systematic modifications of Earth model 1066B in the inner core. A suitable normalization procedure allows for the common representation of all observed amplitudes as a function of epicentral distance. Using the theoretical amplitude distributions it can be shown that the parameters of a regression line through the logarithmic and normalized amplitudes between 110 and 134° are related to the velocity and density jump at the inner-core boundary (ICB). The analysis shows that the dominant influence on the PKP amplitudes is the P-velocity jump which can be restricted to 0.64 ± 0.05 km s^?1. There exists a trade-off between the S-velocity jump and the density jump. Restricting the latter to the reasonable range 0–1.2 g cm^?3 the S-velocity jump at the ICB can be inferred to be 2.5–3.0 km s^?1. A rather strong S-velocity gradient below the ICB follows from the condition that the S-wave travel-time through the inner core agrees with that implied by free oscillation observations. This leads to central S-velocities between 3.81 and 4.15 km s^?1, assuming a parabolic velocity law.     

Anthropogenic effects on sedimentary facies in Lake Baldeney,West Germany

Analysis of well logs of Lake Baldeney, a reservoir of the Ruhr River, yields four facies factors that reflect the effect of anthropogenic processes on the sediment. First, the sedimentation rate is directly related to the subsidence caused by mining. The extent of the subsidence was such that the sediment load of the river could not compensate for the sinking of the lake bottom. Discharged sediment filled about one-fifth of the basin within 40 years. In certain areas of the basin the sedimentation rate reached up to 10 cm per year. Second, the grain-size distribution of the sediment was influenced by long-term and short-term events. During the subsidence, grain-size distribution remained relatively constant. The destruction of the Möhne River dam during World War II resulted in the presence of an extremely large grain size as evidenced by the so-calledMöhnelage. The filling of the lake after 1961 was accompanied by a continual increase in medium grain size. Third, until 1975, the mode of the lake sediment reflects the effect of mining in the vicinity of the lake. High coal content can be traced to its origin. The introduction of modern production processes, modernization of coal dressing, and hydraulic hauling is documented in the sediment. Finally, the heavy metal content of the sediment corresponds to the industrial development in the drainage area the Ruhr River. The accumulation of Cd reached an extreme concentration, exceeding the natural content by a thousand times. Variation in concentration reflects an increase in industrial production, as well as measures undertaken to restore water quality.     

721矿山南铀矿石微生物槽浸的适应性实验研究

以山南铀矿石为研究对象，探讨了微生物槽浸铀实验过程中有关参数（Fe^3 ,Fe^2 ,pH,Eh,U)的变化规律。在此基础上，评价了山南铀矿石微生物槽浸的适应性。     

Flood Events in the Rhine Basin: Genesis,Influences and Mitigation

The paper analyses the hydrological regime of the Rhine catchment,the genesis of recent floods,and recommends some research and practical activities to mitigate flood damage. The catchment of the Rhine River can be divided into four main subcatchments: the alpine region with the Aare River as its main tributary and downstream the lower mountain regions of the tributaries Neckar, Main and Moselle. These four basins generate very different hydrographs. Due to the geographical conditions, the average discharge maximums shift from summer to winter downstream the Rhine. Moreover, the spatial and temporalprecipitation patterns of each river have a strong influence on the individual flood events. Some recent extraordinary floods are used to illustrate the parameters that have influenced these events.A strong relationship between recent climate change observationsand the occurrence of flood levels cannot be proven. However, the consequences of human interventions and the resulting changes to the river system (the Rhine and its tributaries) for the hydrograph can be quantified precisely.The influences of different land-use and climatic scenarios on flood conditions in the Rhine basin have not yet been separately identified. Thus, the Dutch-German project LAHoR was established. The primary aim of this project is to giveadvice for the ``Action Plan on Flood Defence' of the International Commission for the Protection of the Rhine (IKSR). In this plan a multidisciplinary approach to mitigating floods is suggested.It is anticipated that the plan willgenerate synergistic effects between flood prevention, water management, regional planning, agriculture, forestry and ecological demands.     

The Holocene paleohydrology and climatic history of the northern great sandy desert - fitzroy trough: With special reference to the history of the northwest Australian monsoon

The Holocene history of the northwest Australian monsoon is considered in the light of new stratigraphic findings from the southern margin of the monsoon regime. A discussion of the present-day climatology of northwestern Australia and synoptic controls on precipitation in the areas at the southern margin of the monsoon regime is given as background information for the interpretation of stratigraphic findings from swamp and alluvial sequences. The stratigraphic findings point to little change in the intensity of the northwest Australian monsoon since ca. 6.5 ka. A more tentative inference drawn from the field evidence is that the monsoon activity may well have been reduced in this region during the Early Holocene; during this time insolation levels were also reduced. The possible relationship of the northwest Australian monsoon to insolation levels is explored. It is clear that monsoon behavior cannot be accounted for as a simple linear response of monsoon intensity to variations in insolation. Possible controls are discussed with particular emphasis on the plausibility of changes in the damping of convective motions providing the mechanism. Gill's model of heat-induced circulation is used to provide some evidence in favour of this conjecture.