Determination of Selenium in Marine Aquatic Products by Hydride Generation-atomic Fluorescence Spectrometry （HG-AFS）

A method for the analysis of selenium in marine aquatic products by HG-AFS has been investigated. The method is based on the reduction of inorganic selenium to volatile SeH2 which is bubbled out by carrier gas of pure argon, and then swept to Ar-H2 flame quarts atomizer to measure its fluorescence intensity. The hydride generation, transportation, atomization and some instrumental parameters were studied by a kind of orthogonal design. The optimum conditions selected are as follows： reactive acidity, 20% HC1; the amount of NaBH4, 4.9mL; gas flow of argon, 600mLmin^-1; atomizing temperature, 200 ℃ ; negative high voltage, - 300V; light current, 100 mA; integral time, 7s. The detection limit of the presented method is 0.072μgL^-1 for selenium. The calibration curve shows a satisfactory line inthe concentration range from 0.000 to 1.000μgL^-1 Se. The recovery is 95.8%-102.2%.     

Active and passive arching stresses outside a deep trapdoor

Acta Geotechnica - The classic trapdoor configuration has been useful to examine the changes in stresses expected on buried structures. However, the primary focus of previous studies has been on...     

Electrical triggering of earthquakes: results of laboratory experiments at spring-block models

Recently published results of field and laboratory experiments on the seismic/acoustic response to injection of direct current(DC) pulses into the Earth crust or stressed rock samples raised a question on a possibility of electrical earthquake triggering. A physical mechanism of the considered phenomenon is not clear yet in view of the very low current density(10~(-7)–10~(-8) A/m~2) generated by the pulsed power systems at the epicenter depth(5–10 km) of local earthquakes occurred just after the current injection. The paper describes results of laboratory‘‘earthquake' triggering by DC pulses under conditions of a spring-block model simulated the seismogenic fault. It is experimentally shown that the electric triggering of the laboratory ‘‘earthquake'(sharp slip of a movable block of the spring-block system) is possible only within a range of subcritical state of the system, when the shear stress between the movable and fixed blocks obtains 0.98–0.99 of its critical value. The threshold of electric triggering action is about 20 A/m~2 that is 7–8 orders of magnitude higher than estimated electric current density for Bishkek test site(Northern Tien Shan, Kirghizia) where the seismic response to the man-made electric action was observed. In this connection, the electric triggering phenomena may be explained by contraction of electric current in the narrow conductive areas of the faults and the corresponding increase in current density or by involving the secondary triggering mechanisms like electromagnetic stimulation of conductive fluid migration into the fault area resulted in decrease in the fault strength properties.