Evaporation metamorphism of primitive dust material in the early solar nebula

An evaporation experiment on matrix material of the Murchison (C2) meteorite up to 1900°C in vacuo has revealed the evaporation sequence of primitive dust material and the associated evolution of residual solid phases from hydrous silicates through magnesium silicates and iron-metal to calcium-aluminum oxides. The comparison with primitive meteorites suggests that the evaporation metamorphism coupled with the re-condensation may have played an important role in the generation of diverse primitive meteorites in the early solar nebula.     

A note on stilpnomelane mineralogy

Stilpnomelane analyses are classified into two separate groups of ferro- and ferristilpnomelanes on the H₂O(+)-Fe₂O₃/(Fe₂O₃+FeO) diagram. The relation is not comparable with that of oxyhornblende.     

Robust active vibration suppression control with constraint on the control signal: application to flexible structures

A unified mathematical framework, sustained by experimental results, is presented for robust controller design taking into account the constraint on the control signal. The design procedure is exemplified for an active vibration suppression control problem with applications to flexible structures. The considered experimental set‐up is a three‐storey flexible structure with an active mass driver placed on the last storey. First, the considered flexible structure is identified and the model's parametric uncertainties are deduced. Next, control constraints are presented for the robust control design problem, taking into account the restriction imposed on the control signal. Finally, the effectiveness of the control system is tested through experiments, when the input disturbance is assumed to be a sinusoidal one as well as a historical earthquake record (1940 El Centro record). Copyright © 2003 John Wiley & Sons, Ltd.     

Single beam analogy for describing soil–pile group interaction

Most laterally loaded piles are flexible in the sense that they are not deformed over their entire lengths. Instead, pile deflections become negligible below an ‘active pile length’ L_a. This L_a is an important parameter that governs the overall behavior of a rigidly capped pile group. In the present approach, piles closely grouped together beneath a superstructure are viewed as a single equivalent upright beam whose stiffness matrix determines L_a. This idea is verified for different cases of pile spacing, and is further extended for nonlinear behavior of soils surrounding grouped piles.     

Variation of the distribution coefficients of rare earth elements in modern coral-lattices: species and site dependencies

Rare earth element (REE) concentrations in the carbonate lattice of four species of coral have been analyzed and compared with the dissolved REE in ambient seawaters. The corals were from two areas of different salinity, marine (34-34.5) and bay (33-34). The measurement of REE in coral was carried out with inductively coupled plasma mass spectrometry (ICP-MS) after meticulous washing of coral samples, digestion with acetic acid and preconcentration of REE. The concentrations of REE in the two ambient seawaters were quite different, being ten-times higher in the bay area and enriched in light REE. However, the average distribution coefficients (D’s) were almost identical in the two areas. Substantial distribution coefficient differences were observed among the four coral species and the magnitude of inter-species variation in D was also species-dependent. Theoretical calculations imply that pH variation could cause variations in D large enough to account for the small differences between the two areas.     

3-D Modelling of Plate Interfaces and Numerical Simulation of Long-term Crustal Deformation in and around Japan

— We developed a 3-D simulation model for long-term crustal deformation due to steady plate subduction in and around Japan by incorporating viscoelastic slip-response functions into a realistic 3-D plate interface model, constructed on the basis of the topography of ocean floors and hypocenter distributions of earthquakes. The lithosphere-asthenosphere system is modelled by an elastic surface layer overlying a Maxwellian viscoelastic half-space. Kinematic interaction at plate interfaces is rationally represented by the increase of tangential displacement discontinuity (fault slip) across the interfaces. With this model, giving the steady slip rates at plate interfaces calculated from NUVEL-1A, we simulated long-term crustal deformation due to steady plate subduction in and around Japan. The simulated crustal deformation pattern is characterized by steep uplift at island arcs, sharp subsidence at ocean trenches and gentle uplift at outer rises. The numerical results show the strong dependence of the deformation pattern on the 3-D geometry of plate interfaces.     

The characterization and distribution of aerosol and gaseous species in the winter monsoon over the western pacific ocean

During the winters of 1981 and 1982, measurements were taken on two Japanese islands of the aerosol and gaseous species which had been carried by northwesterly monsoons over the Pacific Ocean. The aerosols were characterized as sea-salt particles; soil particles, and as particles of sulfate, nitrate, organics and elemental carbon. At Chichi-jima island, which is about 800 km away from the main islands of Japan, it was found that the level of the anthropogenic components of the aerosols was considerably higher than their background level. The mean concentrations of the species on the islands are given in tabular forms. According to a survey made on board a ferry boat, the aerosol and gaseous species were fairly uniformly distributed along the southern coast of the main Japanese islands.     

Citrate sorption and biodegradation in acid soils with implications for aluminum rhizotoxicity

Citrate and other organic acids play an important role in the rhizosphere and pedogenic processes. Although secreting citrate from roots in response to Al and heavy metal stress has been recognized as a central mechanism for plants to avoid toxicity, the efficiency of root citrate on metal detoxification is still contradictory in acid soil with abundant oxide minerals that serve as a potential sorption site for citrate. The objective of this study was to investigate sorption and biodegradation of citrate in subtropical acid soils with different mineralogical properties. A batch experiment was conducted to assess the possible fates (adsorption and biodegradation) of citrate in the three acid soils (Cecil, Creedmoor and Norfolk) under microbial-active and inactive conditions. Citrate adsorption isotherms for all soils were adequately described by the Freundlich equation with the R² value being over 0.90. The Cecil soil had the highest affinity for citrate adsorption among the soils with 99% adsorption observed throughout the citrate concentration range, which was due primarily to the abundant Al and Fe oxides. Citrate sorption to the mineral phase significantly reduced its biodegradation by 56%, 65% and 99% for the Creedmoor, Norfolk and Cecil soils, respectively. The results suggest the efficiency of rhizosphere processes for Al detoxification by root-secreted citrate would be significantly reduced in acid soil with abundant Al and Fe oxides.     

Onboard experiment investigating metal leaching of fresh hydrothermal sulfide cores into seawater

We observed the initial release rate of metals from four fresh (i.e., without long time exposure to the atmosphere) hydrothermal sulfide cores into artificial seawater. The sulfide samples were collected by seafloor drilling from the Okinawa Trough by D/V Chikyu, powdered under inert gas, and immediately subjected to onboard metal-leaching experiments at different temperatures (5 °C and 20 °C), and under different redox conditions (oxic and anoxic), for 1–30 h. Zinc and Pb were preferentially released from sulfide samples containing various metals (i.e., Mn, Fe, Cu, Zn, Cd, and Pb) into seawater. Under oxic experimental conditions, Zn and Pb dissolution rates from two sulfide samples composed mainly of iron disulfide minerals (pyrite and marcasite) were higher than those from two other sulfide samples with abundant sphalerite, galena, and/or silicate minerals. Scanning electron microscopy confirmed that the high metal-releasing sample contained several galvanic couples of iron disulfide with other sulfide minerals, whereas the low metal-releasing sample contained fewer galvanic couples or were coated by a silicate mineral. The experiments overall confirmed that the galvanic effects with iron disulfide minerals greatly induce the initial release of Zn and Pb from hydrothermal sulfides into seawater, especially under warm oxic conditions.