Study of the structure of silica film by infrared spectroscopy and electron diffraction analyses

Amorphous silicon oxide films have been studied on the basis of electron diffraction (ED) analyses and infrared (IR) spectroscopy in order to elucidate the relationship between the structures. After the heat treatment of the film in air at 300 and 500°C, the ED pattern showed halo rings, and the IR spectra clearly changed. Intensity analysis of the ED pattern provided evidence for the structural change of the amorphous film. It was concluded that the spectral changes in the ranges of 9.2–10.2, 12.5–13.5 and 19.5–22.5 μm were the result of phase transitions of the microcrystallites of α-cristobalite to β-cristobalite, and α- or β-quartz. Astrophysical implications have been discussed.     

The rate of oxidation of ferrous iron in seawater and the partition of elements between iron oxides and seawater

At the Minamichita Beach Land (Mihama-cho, Aichi, Japan), seawater is pumped up from underground and is supplied to aquaria. The underground seawater containsca. 2 ppm of Fe (II), 0.1 ppm of Mn (II) and a little dissolved oxygen. Iron oxide is formed in the seawater when aerated. The oxidation rate of Fe (II) was measured to be 1.4×10¹⁴ mol^–3 l ³ min^–1, which is comparable to the lowest values in the literature. The slow rate of Fe (II) oxidation obtained here can be attributed to the presence of organically bound iron in the seawater. The distribution coefficient of cations between seawater and iron oxide phase was in the order of Cu>Ni>Co>Cd>Mn, which is consistent with that predicted from their hydrolysis constants. The adsorption affinity sequence of oxyanions was phosphate >vanadate> molybdate. The difference in phosphate from the prediction of the adsorption theory was attributed to the formation of ferriphosphate on the oxide surface. On the basis of these data, the limitation and usefulness in the application of the distribution coefficients to marine environments were discussed.     

Errors in sampling procedure for the determination of dissolved oxygen by Winkler method

Sources of systematic error in the sampling procedure by Winkler method were examined. In the laboratory experiment, the dissolution of atmospheric oxygen into oxygenfree sea water during sampling amounts to 0.022 ml/l, and the effect of dissolved oxygen in sea water remaining in oxygen bottle is 0.019 ml/l. The effect of reagents added amounts to 0.017 ml/l. In the sampling procedures aboard, the effect of dissolution became bigger, and the table is presented for the correction to the reported value of dissolved oxygen measured by the “Manual of Oceanographic Observation”. The corrected value of dissolved oxygen in the routine analysis may not be correct within 0.02 ml/l.     

The partition of minor transition metals between manganese oxides and seawater

The behavior of transition metals (Co, Ni, Cu and Zn) on precipitation of manganese oxides from seawater pumped up from a well at the site of the Marine Science Museum, Tokai University, and collected from several tanks along the water supply system to an aquarium was investigated. The distribution coefficients of cobalt and nickel between manganese oxides and seawater were different at different sampling points along the water supply system. At sampling points with high rates of manganese oxide precipitation, the distribution coefficients were about one order of magnitude smaller than those at the points with low precipitation rates, while there were no remarkable differences in the distribution coefficients of copper and zinc among the sampling points. The distribution coefficients of minor transition metals, with the exception of copper, observed at the points with low precipitation rates were comparable to those measured experimentally using manganese dioxides.     

Structure of the strong tidal jet in the naruto strait

In order to clarify the structure of the strong tidal current at the Naruto Strait in the Seto Inland Sea of Japan, the sea-level values were observed in the strait and the current measurements were made with an Acoustic Doppler Current Profiler (ADCP).The tidal volume transports for M₂ and S₂ tides were about 74×10³ and 26×10³ m³ sec^–1, respectively. The horizontal profile of the velocity at the phase of the strong tidal current compares favorably with a theoretical profile of the two-dimensional steady turbulent jet except for the side parts of the profile. Moreover, the entrainment rate of the surrounding water into the strong tidal jet was estimated from the difference of mass flux between two cross-sections at the strait, the entrainment rate and entrainment constant for both the northward and southward flows being about 1.3–2.5×10^–4m^–1 and about 0.03–0.05, respectively.     

Perturbations by the oblateness of the Earth and by the planets in the motion of the Moon

Perturbations in the motion of the Moon are computed for the effect by the oblateness of the Earth and for the indirect effect of planets. Based on Delaunay's analytical solution of the main problem, the computations are performed by a method of Fourier series operation. The effect of the oblateness of the Earth is obtained to the second order, partly adopting an analytical evaluation. Both in longitude and latitude are found a few terms whose coefficient differs from the current lunar ephemeris based on Brown's theory by about 0.01. While, concerning the indirect effect of planets, several periodic terms in the current ephemeris seem to have errors reaching 0.05.As for the secular variations of and due to the figure of the Earth and the indirect effect of planets, the newly-computed values agree within 1/cy with Brown's results reduced to the same values of the parameters. Further, the accelerations in the mean longitude, and caused by the secular changes in the eccentricity of the Earth's orbite and in the obliquity of the ecliptic are obtained. The comparison with Brown shows an agreement within 0.3/cy² for the former cause and 0.02/cy² for the latter. An error is found in the argument of the principal term for the perturbations due to the ecliptic motion in the current ephemeris.Proceedings of the Conference on Analytical Methods and Ephemerides: Theory and Observations of the Moon and Planets. Facultés universitaires Notre Dame de la Paix, Namur, Belgium, 28–31 July, 1980.     

Sulphide and oxide minerals from the Ohmine granitic rocks in Kii Peninsula,central Japan,and their primary paragenetic relations

In the Ohmine granitic rocks of Kii Peninsula, central Japan, ilmenite, rutile, pyrrhotite, pyrite and chalcopyrite commonly occur, but no magnetite is present. Their primary paragenetic relations were confirmed by examining their mode of occurrences as inclusion species in major silicate minerals and the phase relations in the Cu-Fe-S system, though their parageneses changed in cooling of the rocks. This makes it possible to estimate the fugacities of oxygen and sulfur in the granitic rocks based upon their paragenetic relations, and to discuss the nature of volatiles in the granitic rocks. Significant subsolidus reactions for sulfide minerals continued until the rocks cooled below 300° C and took place in two types of mineral grains, in groundmass and as inclusions. The removal of sulfur and copper through the silicate crystals was too easy to preserve the chemistry of sulfides included in silicates.     

Tectonoelectricity

Anomalous earth-current changes in association with an earthquake occurrence have often been reported since the 19th century. Changes reported in classical as well as recent literature are reviewed, although it is hard to say that any physically clear relationship between earth-current changes and earthquakes has been established. Even though a strong correlation between precursory earthcurrent changes and earthquakes has often been reported in the U.S.S.R. and the People's Republic of China in recent years, it appears that a general rule governing the earthquake-related earth-current changes is still very much unknown, partly because of contamination by artificial and natural noise.In contrast to the difficulty in understanding earth-current changes, monitoring of earth-resistivity seems to provide a much clearer means for interpreting geoelectric phenomena in association with tectonic processes in the Earth. Soviet and American work showed that the resistivity decreases to a considerable extent in the focal region prior to an earthquake. Such a change seems to be closely correlated to dilatancy generation in the Earth's crust. This finding doubtless provides an important means for earthquake prediction.An ususual, highly sensitive resistivity variometer, developed by the writer, disclosed that a resistivity change takes place at a teleseismic distance when an earthquake of large and medium magnitude occurs. Many of the resistivity changes thus observed are preceded by a premonitory change, which is supposed to reflect the preliminary rupture at a focal region.