Deuterium abundance of natural waters

The deuterium abundance of natural water of various sources has been determined by the use of a deuterium mass spectrometer. The absolute deuterium contents of the reference sample nos. 1 and 1a of the U.S. National Bureau of Standards were found to be 0·0149 and 0·0128 mole % D₂O, respectively, by the comparison of the samples with the standard samples of known deuterium content. Relative enrichment of no. la to no. 1 (R_1a−R₁)/R₁×100 was 14·13 ± 0·23, which agrees perfectly to the value reported by . The variation of deuterium contents of tap waters of Tokyo and Osaka during last 2 years were within ± 1 per cent and any seasonal regularities could not be detected. Marine waters of the West Pacific have almost the same deuterium content as those of the Pacific coast of the United States. Marine waters at various depths of the Antarctic showed relatively large variation of deuterium content (from +0·84 to −1·16 per cent on the SMOW-scale), whereas the samples of Black Current of the Pacific showed little variation. It was found that the deuterium content of spring water suggests the origin of springs in some cases.     

Temperature coefficients of elastic constants of single crystal MgO between 80 and 1,300 K

Elastic constants of single crystal MgO have been measured by the rectangular parallelepiped resonance (RPR) method at temperatures between 80 and 1,300 K. Elastic constants C _ij (Mbar=10³ kbar) and their temperature coefficients (kbar/K) are: $$\begin{gathered} {\text{ }}C_{{\text{11}}} {\text{ }}C_{{\text{12}}} {\text{ }}C_{{\text{44}}} {\text{ }}K_s {\text{ }}C_s \hfill \\ C_{ij} {\text{ 300 K 2}}{\text{.966 0}}{\text{.959 1}}{\text{.562 1}}{\text{.628 1}}{\text{.004}} \hfill \\ \partial C_{ij} {\text{/}}\partial T{\text{100 K }} - {\text{0}}{\text{.259 0}}{\text{.013 }} - {\text{0}}{\text{.072 }} - {\text{0}}{\text{.078 }} - {\text{0}}{\text{.136}} \hfill \\ {\text{ 300K }} - {\text{0}}{\text{.596 0}}{\text{.068 }} - {\text{0}}{\text{.122 }} - {\text{0}}{\text{.153 }} - {\text{0}}{\text{.332}} \hfill \\ {\text{ 800 K }} - {\text{0}}{\text{.619 0}}{\text{.009 }} - {\text{0}}{\text{.152 }} - {\text{0}}{\text{.200 }} - {\text{0}}{\text{.314}} \hfill \\ {\text{ 1,300 K }} - {\text{0}}{\text{.598 0}}{\text{.036 }} - {\text{0}}{\text{.130 }} - {\text{0}}{\text{.223 }} - {\text{0}}{\text{.218}} \hfill \\ \end{gathered} $$ By combining the present results with the previous data on the thermal expansivity and specific heat, the thermodynamic properties of magnesium oxide are presented and discussed. The elastic parameters of MgO at very high temperatures in the earth's lower mantle are also clarified.     

Caledonide development offshore–onshore Svalbard based on ocean bottom seismometer, conventional seismic, and potential field data

The western Barents Sea and the Svalbard archipelago share a common history of Caledonian basement formation and subsequent sedimentary deposition. Rock formations from the period are accessible to field study on Svalbard, but studies of the near offshore areas rely on seismic data and shallowdrilling. Offshore mapping is reliable down to the Permian sequence, but multichannel reflection seismic data do not give a coherent picture of older stratigraphy. A survey of 10 Ocean Bottom Seismometer profiles was collected around Svalbard in 1998. Results show a highly variable thickness of pre-Permian sedimentary strata, and a heterogeneous crystalline crust tied to candidates for continental sutures or major thrust zones. The data shown in this paper establish that the observed gravity in some parts of the platform can be directly related to velocity variations in the crystalline crust, but not necessarily to basement or Moho depth. The results from three new models are incorporated with a previously published profile, to produce depth-to-basement and -Moho maps south of Svalbard. There is a 14 km deep basement located approximately below the gently structured Upper Paleozoic Sørkapp Basin, bordered by a 7 km deep basement high to the west, and 7–9 km depths to the north. Continental Moho-depth range from 28 to 35 km, the thickest crust is found near the island of Hopen, and in a NNW trending narrow crustal root located between 19°E and 20°E, the latter is interpreted as a relic of westward dipping Caledonian continental collision or major thrusting. There is also a basement high on this trend. Across this zone, there is an eastward increase in the V_P, V_P/V_S ratio, and density, indicating a change towards a more mafic average crustal composition. The northward basement/Moho trend projects onto the Billefjorden Fault Zone (BFZ) on Spitsbergen. The eastern side of the BFZ correlates closely with coincident linear positive gravity and magnetic anomalies on western Ny Friesland, apparently originating from an antiform with high-grade metamorphic Caledonian terrane. A double linear magnetic anomaly appears on the BFZ trend south of Spitsbergen, sub-parallel to and located 10–50 km west of the crustal root. Based on this correlation, it is proposed that the suture or major thrust zone seen south of Svalbard correlates to the BFZ. The preservation of the relationship between the crustal suture, the crustal root, and upper mantle reflectivity, challenges the large-offset, post-collision sinistral transcurrent movement on the BFZ and other trends proposed in the literature. In particular, neither the wide-angle seismic data, nor conventional deep seismic reflection data south of Svalbard show clear signs of major lateral offsets, as seen in similar data around the British Isles.     

Excess bottom222Rn profiles and their implications in the northwestern Pacific Ocean

Vertical profiles of excess bottom²²²Rn and potential temperature were measured at 23 stations in the northwestern Pacific Ocean. The Rn profiles were classified into the following three types: quasi-exponential (type E), benthic boundary layer (type B), and horizontally disturbed (type H). The ratio among types E, B and H was approximately 2 : 3 : 1.An apparent vertical eddy diffusivity (K) was calculated by applying a one-dimensional diffusion model to the Rn profiles of types E and B. Type E had K values ranging from 15 to 180 cm² s^?1 (average: 70 cm² s^?1). As to type B, K values for the benthic boundary layer (4.5–260 cm² s^?1, average: 120 cm² s^?1) were always more than an order of magnitude larger than those for the upper layer (0.2–35 cm² s^?1, average: 7 cm² s^?1), indicating more active vertical mixing in the benthic boundary layer than in the upper layer.Rn profiles were measured in regions where the bottom topography is known. It was verified that the occurrence of type H related closely with local bottom topographic features accompanied by lateral transient supply of Rn-rich or Rn-poor water.A couple of Rn profiles at the same location, measured at time intervals of several years, were compared with each other for three locations. The general characteristics of Rn profiles were shown to remain unaltered with time, while the fine structure of Rn profiles may have short-term variations caused by local bottom topography and fluctuations of bottom current as indicated in type H.     

Three‐dimensional microstructure of samples recovered from asteroid 25143 Itokawa: Comparison with LL5 and LL6 chondrite particles

In this study, the three‐dimensional (3‐D) microstructure of 48 Itokawa regolith particles was examined by synchrotron microtomography at SPring‐8 during the preliminary examination of Hayabusa samples. Moreover, the 3‐D microstructure of particles collected from two LL6 chondrites (Ensisheim and Kilabo meteorites) and an LL5 chondrite (Tuxtuac meteorite) was investigated by the same method for comparison. The modal abundances of minerals, especially olivine, bulk density, porosity, and grain size are similar in all samples, including voids and cracks. These results show that the Itokawa particles, which are surface materials from the S‐type asteroid Itokawa, are consistent with the LL chondrite materials in terms of not only elemental and isotopic composition of the minerals but also 3‐D microstructure. However, we could not determine whether the Itokawa particles are purely LL5, LL6, or a mixture of the two. No difference between the particles collected from Rooms A and B of the sample chamber, corresponding to the sampling sequence of the spacecraft's second and first touchdowns, respectively, was detected because of the statistically small amount of particles from Room B.