Experimental Designs Applied to Desorption of Dichromate Ions after Separation and Preconcentration from Natural and Industrial Water by Modified Nano‐Alumina

Nano‐alumina modified by 9‐aminoacridine was used as a sorbent for separation and determination of dichromate ions from water. Statistical method, based on surface response design, has been used for the optimization of dichromate ions elution from 9‐aminoacridine nano‐alumina. The adsorbed dichromate ions were found to be eluted quantitatively with 0.8 mol L^?1 KCl in 1.6 mol L^?1 NaOH which optimized by response surface design. Under optimum conditions, the accuracy, precision (relative standard deviation, RSD%) and R‐square of the method were calculated as >98, <3, and >94%, respectively. Remarkable agreement between experimental and theoretical data was confirmed the predicted assumption. The method was applied to the simultaneous determination of dichromate in natural and industrial water samples. We also examined the retention of dichromate anions in the presence of Cl^?, , and anions at pH 3.     

Temporal and bathymetric variation of epiphyte cover and leaf biomass in a southern Posidonia oceanica (L.) meadow: the case of Mahdia coast,Tunisia

The aim of this research was to study spatial and temporal variation in epiphyte cover and leaf biomass of Posidonia oceanica in Eastern Tunisia. Sampling was conducted at four stations on the Mahdia coast during October and December 2010, and April and August 2011, which correspond respectively to autumn, winter, spring and summer in this area. Posidonia oceanica shoots were collected at two depths (5 and 10 m). Cover of macroinvertebrates and macroalgae was estimated on adult leaves. The results showed that leaf and epiphyte biomasses vary significantly according to sampling date, with the highest values recorded in August. We found a high diversity of epiphytic assemblages on the leaves of P. oceanica with clear qualitative and quantitative dominance of Rhodophyceae compared to other groups, followed by Phaeophyceae. Most epiphyte species on the leaves of P. oceanica in Eastern Tunisia are the same as those in other parts of the Mediterranean Sea. No bathymetrical variation in the epiphytic community was found in our study area, which can be explained by the high levels of water clarity in Mahdia.     

Interactions between Cd,Cu, Pb,and Zn and four different mine soils

The chemical associations of Cd, Cu, Pb, and Zn in four mine soil samples from the Amizour-Bejaia Pb/Zn mine (Algeria) have been investigated by a five-step sequential extraction procedure. Although Cd preferentially binds to carbonates, Cu, Pb, and Zn are mainly associated with the organic and reducible fractions. Batch adsorption experiments with either mono- or multi-metallic solutions are described with the Freundlich isotherm model. Whatever the nature of the soil sample, the sorption behavior for each given metal except Pb is very similar, indicating that the binding sites at the soil surface are progressively occupied by the metal from the solution. On each soil sample, the decreasing order of sorption can be established as Pb >> Cu > Cd > Zn. When the four metals are simultaneously applied to each soil sample, their specific behavior is strongly affected by their interactions and/or competition for the available surface sites: we generally observed isotherm curves with a slight maximum before the plateau at higher solution concentration. Although Cu is only slightly affected by the other metals, in the case of Pb, Cd, and Zn, the sorbed amounts strongly decreased.     

Modeling of forest soil and litter health using disturbance and landscape heterogeneity indicators in northern Iran

This paper focuses on the indicators of soil and litter health, disturbance, and landscape heterogeneity as a tool for prediction of ecosystem sustainability in the northern forests of Iran. The study area was divided into spatial homogenous sites using slope, aspect, and soil humidity classes. Then a range of sites along the disturbance gradient was selected for sampling. Chemical and physical indicators of soil and litter health were measured at random points within these sites. Structural equation modeling (SEM) was applied to link six constructs of landscape heterogeneity, three constructs of disturbance (harvest, livestock, and human accessibility), and soil and litter health. The results showed that with decreasing accessibility, the total N and organic matter content of soil increased and effective bulk density decreased. Harvesting activities increased soil organic matter. Therefore, it is concluded that disturbances through harvesting and accessibility inversely affect the soil health. Unexpectedly, it was found that the litter total C and C:N ratio improved with an increase in the harvest and accessibility disturbances, whereas litter bulk density decreased. Investigation of tree composition revealed that in the climax communities, which are normally affected more by harvesting activities, some species like Fagus orientalis Lipsky with low decomposition rate are dominant. The research results showed that changes in disturbance intensity are reflected in litter and soil indicators, whereas the SEM indicated that landscape heterogeneity has a moderator effect on the disturbance to both litter and soil paths.     

Investigation of land use changes on soil erosion process using geographical information system

Land use change quantified for the last 50 years within and near a fast growing agricultural land in Neka River Basin, using geographic information systems. Land cover and land use change was projected for the next decade using topography, geology, land use maps and remote sensing data of the study area. The study explored the relationships between agricultural land growth and landscape changes. The land use changes assessed among the different land cover classes. It is important to mention that conducting of the present study a very severe land cover changes taken place as the result of agricultural land development. These changes in land cover led to the forest degradation of the study area. Relationship between land-use changes and agricultural growth offered a more robust prediction of soil erosion in Neka watershed. This study aims to find the relationships between land use pattern, erosion and the sediment yield in the study area. The land use coefficient has applied in the model of erosion potential method to forecast the effect of the land type to reduce the erosion. The results of this study indicated that the total sediment yield of the study area has notably decreased to 89.24 % after an appropriate land use/cover alteration. The estimated special erosion for the southern Neka Basin is about 144465.1 m³/km² where after management policy is predicted 15542.9 m³/km²/y. Therefore, the total difference for the study area has estimated about 128922.2 m3/km2/y.     

Optimizing the dataset size of a topo-bathymetric survey for Hammam Debagh Dam,Algeria

The capacity of water reservoirs may be considerably reduced by sediment transport and accumulation. This phenomenon may occur quickly in regions prone to erosion, such as Hammam Debagh Dam region in Algeria. For better management of water resources, it is important to estimate the volume of a reservoir by regular and frequent topo-bathymetric surveys. Topo-bathymetric surveys with a high point measurement density are expensive and time-consuming. To reduce this expense and to increase the frequency of topo-bathymetric surveys, it is required to optimize their size and density. The complete survey of the reservoir created by the Hammam Debagh Dam in Algeria was examined in comparison with 19 reduction subsets using geostatistics. The study showed that the complete dataset of 32,164 points, corresponding to a density of 42 points ha^-1 could be reduced to 10,000 points, i.e. 13 points ha^-1, without affecting the estimation of the water volume in the reservoir. This reduction could considerably simplify the work load, reduce the expenses to do these surveys, and, therefore, allow for an increased frequency of topo-bathymetric surveys.     

Effects of foundation rocking and uplifting on displacement amplification factor

Prediction of displacement demand to assess seismic performance of structures is a necessary step where nonlinear static procedures are followed. While such predictions have been well established in literature for fixed-base structures, fewer bodies of researches have been carried out on the effect of rocking and uplifting of shallow foundations supported by soil, on such prediction. This paper aimed to investigate the effect of soil structure interaction on displacement amplification factor C1 using the beam on nonlinear Winkler foundation concept. A practical range of natural period, force reduction factors, and wide range of anticipated behavior from rocking, uplifting and hinging are considered and using thousands nonlinear time history analysis, displacement amplification factors are evaluated. The results indicate that the suggested equations in current rehabilitation documents underestimate displacement demands in the presence of foundation rocking and uplift. Finally, using regression analyses, new equations are proposed to estimate mean values of C₁.     

Small-scale multi-axial hybrid simulation of a shear-critical reinforced concrete frame

This study presents a numerical multi-scale simulation framework which is extended to accommodate hybrid simulation (numerical-experimental integration). The framework is enhanced with a standardized data exchange format and connected to a generalized controller interface program which facilitates communication with various types of laboratory equipment and testing configurations. A small-scale experimental program was conducted using a six degree-of-freedom hydraulic testing equipment to verify the proposed framework and provide additional data for small-scale testing of shearcritical reinforced concrete structures. The specimens were tested in a multi-axial hybrid simulation manner under a reversed cyclic loading condition simulating earthquake forces. The physical models were 1/3.23-scale representations of a beam and two columns. A mixed-type modelling technique was employed to analyze the remainder of the structures. The hybrid simulation results were compared against those obtained from a large-scale test and finite element analyses. The study found that if precautions are taken in preparing model materials and if the shear-related mechanisms are accurately considered in the numerical model, small-scale hybrid simulations can adequately simulate the behaviour of shear-critical structures. Although the findings of the study are promising, to draw general conclusions additional test data are required.