A novel ozone sensor for direct eddy flux measurements

A small, lightweight (1.5 kg) and fast-response ozone sensor for direct eddy flux measurements has been built. The basis for detection is the chemiluminescence of an organic dye adsorbed on dry silica gel in the reaction with ozone. The chemiluminescence is monitored with a cheap and small blue-sensitive photomultiplier. At a flow rate of 100 l min^-1 the ozone sensor has a 90% response time of significantly better than 0.1 s with a detection limit lower than 50 ppt at S/N=3. There are no interferences from other atmospheric trace gases like NO_x, H₂O₂ and PAN. Water vapour and SO₂ enhance the chemiluminescence efficiency of the ozone sensor. Since their response times are 22 seconds and 30 minutes, respectively, no correlation between rapid ozone fluctuations and those of these two trace gases is noticed by the ozone sensor when operating at a frequency of 10 Hz.The ozone sensor was tested for several weeks in continuous measurements of ozone fluxes and deposition velocities over different croplands using the eddy correlation technique. Good agreement was found between ozone dry deposition velocities derived from profile measurements and by eddy correlation.     

Stockwerktektonische Untersuchungen im Ruhrkarbon

Zusammenfassung Nach einer Erläuterung des Begriffes Stockwerktektonik wird über derartige Untersuchungen im südlichen Ruhrkarbon berichtet. Hier lassen sich drei durch fließende Übergänge verbundene tektonische Stockwerke unterscheiden: Das Flözleere ist durch das Vorherrschen tektonischer Formen niederer Größenordnung gekennzeichnet, die sich an bestimmten Stellen summieren. Das nächst höhere Stockwerk zeichnet sich durch eine sanfte Faltung und einige typische Faltenformen aus. Ein weiteres Stockwerk ist in seinem Formenschatz stärker differenziert. Über höhere Stockwerke liegen Untersuchungen vonKukuk, Kienow undSeidel vor. - Der vorliegende Bericht bringt nur Ergebnisse aus dem südlichen Revier; eine Gesamtdarstellung kann damit noch nicht gegeben werden.     

Computation of 5-day temperature normals in western Europe and the Mediterranean area

Summary UsingCraddock's method of representing the annual temperature variation by a two-term harmonic form fitted to monthly means, the harmonic coefficients of 63 stations in western Europe and around the Mediterranean Sea, as well as the 5-day normals for 24 Mediterranean stations, were computed and tabulated. In addition, some of the harmonic coefficients were charted and isoplethed, showing very distinctly the influence of continentality and topography. These charts, together withCraddock's charts for northern and northwestern Europe, provide fairly complete coverage of Europe and the Mediterranean area.This paper was prepared in the offices of the Technical Support Division of the 2d Weather Wing, United States Air Force, as a matter of routine business. The information contained herein was presented at the 5th Meeting of the Italian Society of Geophysics and Meteorology by Dr.Ingrid Weiss (Genoa: 23–25 April 1957). Since the paper is of general interest to all meteorologists of the Mediterranean area, it is published here with the permission of the originating agency as «Mémoire No. 3 du Centre International de Recherches sur la Météorologie de la Méditerranée (CIRMM)».     

Metallogenic provinces in South America

This paper discusses the broadscale distribution of some ore deposit types in South America, trying to discern possible relations with major geotectonic features. It does not cover all ore deposits but rather a selection based on available information, genetic types, geographic distribution, and a representation of deposit types which are either abundant or very rare in South America. Included are porphyry copper, zoned copper-zinc-lead-silver, contact-metasomatic, red-bed copper-uranium-vanadium, lead-zinc (including Mississippi Valley type), mercury, tin, pegmatite, carbonatite and alkalic complex, diamond, nickelcobalt-chromite-asbestos-talc, iron, bauxite, tungsten, titanium, uranium, gold, potash and phosphate deposits. Comparisons are made with the distribution of these deposit types in other continents, especially in North America and Africa. This leads to some speculations bearing on theories of ore genesis. The evidence suggests that upper crustal processes predominate in the formation of the majority of ore deposits considered (excepting carbonatites, alkalic complexes and diamond pipes). Also, the relative level of an orogenic belt exposed by erosion seems to be an important factor bearing on the presently known distribution of many ore deposit types. Furthermore, the fact that ore deposits of given types tend to be aligned along the Cordillera in more or less defined belts with changing chemical composition accross the Andes, which partake in all its inflections, and in patterns which are similar in North and South America, indicates that they are either dependent on the distribution of eugeosynclinal vs miogeosynclinal sediments in the original geosynclinal prism, or that their character is related to distance from the major batholitic masses or to shallow stocks and volcanic activity. The indicated correlation with sediment character and evaporites speaks in favor of modem concepts viewing hydrothermal fluids as mainly meteoric but heated and circulated largely by igneous activity. This study raises more questions than it can answer and calls attention to a number of problems requiring further research. From a practical point of view, this investigation reveals several possibilities for future exploration, as well as opportunities for further development of mineral resources in South America. Several countries could probably improve or diversify their mineral production significantly, thus raising the standard of living of their increasing population. Whereas in North America both Canada and the U.S.A. span from east to west the whole range of geological environments, from cratonic to geosynclinal and orogenic, in South America the distribución of countries is essentially either along the Cordillera or over shield areas, a fact of obvious geopolitical implications with regard to mineral resources.     

Chloritoid stability in manganese rich low-grade metamorphic rocks,Venn-Stavelot Massif,Ardennes

The Southern Venn-Stavelot Massif is characterized by Ordovician and Devonian rocks very rich in manganese and aluminum, which are attacked by a low grade regional metamorphism. The assemblages 1 (phengite, paragonite, chlorite, chloritoid, garnet, quartz, hematite, rutile) and 2 (phengite, paragonite, chlorite, kaolinite (andalusite, pyrophyllite), garnet, quartz, hematite, rutile) are of basic interest for the formation of chloritoid. As the two rock types are isofaciell and quasi-identical in chemistry except for the iron oxides, there is clear evidence for the influence of on the chloritoid formation at its lower p-T stability limit. This can be shown by a discussion of the phase relations of chloritoid, garnet, kaolinite, chlorite and phengite in respect to the oxidation ratio mol 2 Fe₂O₃x 100/2 Fe₂O₃+ FeO of the host rocks. Especially chloritoid and chlorite change their chemistry in a characteristic way with rising oxidation ratio in getting richer and richer in manganese and magnesium (chloritoid) and magnesium (chlorite). A simultaneous increase in trivalent iron in these phases is supposed. At an oxidation ratio of 85–90 the stability limit of chloritoid is reached. The increasing substitution of manganese and magnesium up to this limit should have a stabilizing effect. In a rough estimate the oxygen partial pressure is supposed to be in the order of 10⁻¹⁰ atm at the stability limit of chloritoid assuming a temperature of metamorphism between 360–400° C. Rocks with oxidation ratios between 90 and 100 are characterized by the presence of kaolinite. If the oxidation ratio is still higher (all iron as Fe³⁺, parts of the manganese in the trivalent state), the rocks belong to assemblage 3 (phengite, paragonite, chlorite, viridine, (kaolinite), (garnet), quartz, hematite, braunite, rutile). Dedicated to Prof. Dr. K. Jasmund at his 60. birthday.     

Petrographische Untersuchungen des Suevit aus den Bohrungen Deiningen und Wörnitzostheim im Ries von Nördlingen

Zusammenfassung In den Bohrungen Deiningen (D.) und Wörnitzostheim (W.) im Nördlinger Ries wurde unter tertiären Seesedimenten eine 40 m bzw. 70 m mächtige Suevitabfolge aufgeschlossen. Diese Breccie, bestehend aus zertrümmertem kristallinem Grundgebirge mit verschiedenen Anzeichen einer Stoßwellenmetamorphose und aus Glasbomben, wurde mineralogisch und petrographisch untersucht.Korngrößenanalysen zeigen in beiden Profilen eine allmähliche Zunahme des Mediandurchmessers von oben nach unten (D.: 0,1···0,4 mm; W.: 1···6 mm). Die Kornverteilungskurve von W. ist bimodal; das Hauptmaximum wird überwiegend aus grobkörnigen Gesteinsgläsern gebildet, ein kleineres Maximum liegt bei 0,2–0,6 mm und enthält bevorzugt Grundgebirgseinschlüsse.Das Verhältnis von Gesteinsgläsern: Kristallinkomponenten beträgt in D. etwa 30 70, in W. 60 40. Der Suevit von W. enthält durchschnittlich 28% Porenraum und 1–2% Neubildungen; seine Glassubstanz ist überwiegend frisch. Im Suevit von D. sind die Gläser sekundär zersetzt und bedingen höhere Porenvolumina (34–36%) und eine stärkere Verwitterungsneubildung (6–10%; Montmorillonit, Montmorillonit-Illit-Wechsellagerung, Karbonate und Analcim).Einzelminerale in der Kornfraktion 0,063–0,125 mm verteilen sich bei den Leicht-mineralen (d<2,96 g/cm³; Neubildungen nicht berücksichtigt) auf Feldspäte (D.: 56%; W.: 44%), Quarz (D.: 32%; W.: 28%), Biotit (D.: 5%; W.: <1%), Hornblende (D.: 2%; W.: -) und Gläser (D.: 3%; W.: 27%); der Anteil der Schwerminerale beträgt in D. 3–4% (Biotit, Opakes — Hornblende, Granat, Turmalin), in W. 0,5–0,8% (Opakes, Zirkon — Biotit, Rutil).Die chemische Zusammensetzung der Suevit- und Glasproben von W. ist dem granodioritischen Magmentyp ähnlich; die Suevitproben von D. weisen höhere Alkaligehalte auf.

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Underlying miocene lake sediments, suevite was found in the drill holes of Deiningen (D.) and Wörnitzostheim (W.), 40 meters and 70 meters thick, respectively. This breccia, containing glass and shattered crystalline rocks, in different stages of shock metamorphism, was examined by mineralogical and petrographical methods.In the two suevite profiles medians of grain size distributions gradually increase from top to bottom (D.: 0,1···0,4 mm; W.: 1···6 mm). The grain size distributions of W. are bimodal; the first maximum is mainly formed by coarse grained glass, the second (smaller) maximum (0,2···0,6 mm) contains crystalline components. The ratio of melted rocks: crystalline components is 3070 at D. and 6040 at W. Suevite from the latter locality has a total porosity of 28% (average) and contains 1–2% autigenic minerals; the glasses are mostly fresh. In the D. suevite decomposition of the glass has produced higher porosities (34–36%) and more autigenic minerals (6–10%: montmorillonite, mixed-layer minerals montmorillonite-illite, carbonates, analcime).Mineral composition was determined for the grain sizes from 0,063 to 0,125 mm. The light minerals (d<2,96 g/cm³, without autigenic minerals) comprise: feldspars (D.: 56%; W.: 44%), quartz (D.: 32%; W.: 28%), biotite (D.: 5%; W.: < 1%), hornblende (D.: 2%; W.: -) and glass (D.: 3%; W.: 27%); heavy-mineral content is 3–4% at D. (biotite, opaque minerals — hornblende, garnet, tourmaline) and 0,5–0,8% at W. (opaque minerals, zircon — biotite, rutile).The chemical composition of suevite and glass samples from W. is similar to granodiorite type rock. The suevite of D. contains more potassium and sodium.

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Meinem verehrten Lehrer, Herrn Prof. Dr. W. v. Engelhardt, danke ich für die Überlassung des Themas und alle Förderung meiner Arbeit. Für fördernden Rat danke ich ferner den Herren Dr. F. Lippmann und Dr. D. Stöffler.

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Der Deutschen Erdöl AG, insbesondere Herrn Prof. Dr. F. Hecht, danke ich für die Überlassung der Bohrkerne von Deiningen.

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Der Deutschen Forschungsgemeinschaft danke ich für die finanzielle Unterstützung dieser Arbeit.     

Spectroscopic investigation of the chromosphere

The line profile of H as emanating from the interior of supergranular cells was measured at sin = 0, 0.6, 0.8 and 0.9. The measurements are described and the results presented.Mitteilung aus dem Fraunhofer Institut Nr. 117.