A dynamo model with double diffusive convection for Mercury's core

A recent dynamo model for Mercury assumes that the upper part of the planet's fluid core is thermally stably stratified because the temperature gradient at the core–mantle boundary is subadiabatic. Vigorous convection driven by a superadiabatic temperature gradient at the boundary of a growing solid inner core and by the associated release of light constituents takes place in a deep sub-layer and powers a dynamo. These models have been successful at explaining the observed weak global magnetic field at Mercury's surface. They have been based on the concept of codensity, which combines thermal and compositional sources of buoyancy into a single variable by assuming the same diffusivity for both components. Actual diffusivities in planetary cores differ by a large factor. To overcome the limitation of the codensity model, we solve two separate transport equations with different diffusivities in a double diffusive dynamo model for Mercury. When temperature and composition contribute comparable amounts to the buoyancy force, we find significant differences to the codensity model. In the double diffusive case convection penetrates the upper layer with a net stable density stratification in the form of finger convection. Compared to the codensity model, this enhances the poloidal magnetic field in the nominally stable layer and outside the core, where it becomes too strong compared to observation. Intense azimuthal flow in the stable layer generates a strong axisymmetric toroidal field. We find in double diffusive models a surface magnetic field of the observed strength when compositional buoyancy plays an inferior role for driving the dynamo, which is the case when the sulphur concentration in Mercury's core is only a fraction of a percent.     

On the impact of salinity observations on state estimates in Ems Estuary

The hydrodynamics of Ems Estuary are dominated by tides and their interaction with buoyancy forcing. Such an environment is challenging for any effort to bring together observations and model results. In this study, we investigate how salinity measurements in the Ems Estuary affect the reconstruction of the salinity field. Similar to the traditional observing system experiments, the impact of specific observational arrays is simulated in the framework of statistical experiments. The experimental algorithm mainly relies on the model covariance matrix. Each experiment results in an estimate of the reconstruction error. The analysed observation configurations involve single and multiple, as well as stationary and non-stationary observing arrays. Generally, the reconstruction of the ocean state improves with increasing the density of observations. It appears that certain locations are more favourable for reconstruction than others. In fact, the regions separating the main dynamical realms resist strongest to the reconstruction effort. Extending the covariance matrix by the temporal cross-covariances between the model grid points enables to evaluate the impact of observations taken from a moving platform. This approach further improves the outcome of the experiments, resulting in reconstruction errors near zero with the exception of the tidal river. The cross-covariance information is able to tackle even the irregular dynamics arising on the border between the different physical regimes.     

Quartz as indicator mineral in the Central Swiss Alps: the quartz recrystallization isograd in the rock series of the northern Aar massif

Earlier observations on the deformation of rock-forming quartz during Alpine metamorphism that were made by Voll (1976) along a traverse following the Reuss valley (Aar massif, Central Swiss Alps) are still relevant but can be explained in more modern term. Voll found that a few kilometres south of the contact between the Aar massif and its sedimentary cover quartz has partly undergone a combination of dynamic recrystallization and nucleation along grain boundaries and fractures at the expense of the deformed parent grains. Further to the south, increasing grain growth of quartz under nearly static conditions is observed, with polygonal grain shapes typical of annealed microfabrics. Comparable stages of recrystallization could be found in several N–S traverses through the Aar massif so that “points of first occurrence” of newly formed quartz could be connected to define a quartz recrystallization isograd. This isograd extents over 90 km through the northern Aar massif, following a course parallel to the sanidine/microcline isograd but at a distance of 10–15 km further to the north. The evolution of the quartz microfabric is discussed with respect to recent estimates of the T-t path of the Aar massif.     

Modelling forest snow processes with a new version of WaSiM

ABSTRACT

We present a new model extension for the Water balance Simulation Model, WaSiM, which features (i) snow interception and (ii) modified meteorological conditions under coniferous forest canopies, complementing recently developed model extensions for particular mountain hydrological processes. Two study areas in Austria and Germany are considered in this study. To supplement and constrain the modelling experiments with on-site observations, a network of terrestrial time-lapse cameras was set up in one of these catchments. The spatiotemporal patterns of snow depth inside the forest and at the adjacent open field sites were recorded along with snow interception dynamics. Comparison of observed and modelled snow cover and canopy interception indicates that the new version of WaSiM reliably reconstructs the variability of snow accumulation for both the forest and the open field. The Nash-Sutcliffe efficiency computed for selected runoff events in spring increases from ?0.68 to 0.71 and 0.21 to 0.87, respectively.     

Shear velocity estimates in rough‐bed open‐channel flow

Shear velocity u_* is an important parameter in geophysical flows, in particular with respect to sediment transport dynamics. In this study, we investigate the feasibility of applying five standard methods [the logarithmic mean velocity profile, the Reynolds stress profile, the turbulent kinetic energy (TKE) profile, the wall similarity and spectral methods] that were initially developed to estimate shear velocity in smooth bed flow to turbulent flow over a loose bed of coarse gravel (D₅₀ = 1·5 cm) under sub‐threshold conditions. The analysis is based on quasi‐instantaneous three‐dimensional (3D) full depth velocity profiles with high spatial and temporal resolution that were measured with an Acoustic Doppler Velocity Profiler (ADVP) in an open channel. The results of the analysis confirm the importance of detailed velocity profile measurements for the determination of shear velocity in rough‐bed flows. Results from all methods fall into a range of ± 20% variability and no systematic trend between methods was observed. Local and temporal variation in the loose bed roughness may contribute to the variability of the logarithmic profile method results. Estimates obtained from the TKE and Reynolds stress methods reasonably agree. Most results from the wall similarity method are within 10% of those obtained by the TKE and Reynolds stress methods. The spectral method was difficult to use since the spectral energy of the vertical velocity component strongly increased with distance from the bed in the inner layer. This made the choice of the reference level problematic. Mean shear stress for all experiments follows a quadratic relationship with the mean velocity in the flow. The wall similarity method appears to be a promising tool for estimating shear velocity under rough‐bed flow conditions and in field studies where other methods may be difficult to apply. This method allows for the determination of u_* from a single point measurement at one level in the intermediate range (0·3 < h < 0·6). Copyright © 2013 John Wiley & Sons, Ltd.     

Catalyzed Reactions on Mineral Plaster Materials Used for Indoor Air Purification

Zeolites have been used for a long time for purification and catalytical purposes. Recently, first products appeared on the market using zeolites also for improving the indoor air quality so far volatile organic compounds (VOC) are concerned. However, porous compounds like zeolites can be found also in plaster material. Therefore, it was manifest to evaluate the capability of plaster with regard to air cleaning. In this article, the contribution of plaster compounds toward adsorption and catalytical decomposition of VOCs is evaluated using α‐pinene, chlorobenzene, 2‐ethoxyethylacetate, and pentanal as target substances under standard conditions (23°C, 50% r.H.). These compounds were chosen because of their VOC typical physicochemical properties like molecular dimensions, density, boiling point, vapor pressure, and octanol–water distribution coefficient (logk_ow). Hydrated lime and metakaolin were found out to have good adsorption properties under these circumstances. Also natural zeolites showed good results especially on pentanal. By investigations in environmental chambers the reduction potential of test plasters on chlorobenzene and 2‐ethoxyethylacetate concentrations could be shown. Application of coatings had no or only temporary influence on the performance of the plaster. Additional tests in small chambers demonstrated the possibility to improve the properties of plasters with help of FAU‐ or MFI‐type zeolites but the experiments also showed that α‐pinene and pentanal undergo chemical reactions. Further effort should be made on investigations also toward other compounds, especially more volatile ones like formaldehyde. Also additional building materials like insulation material or boards should be taken into account.     

Fluid inclusion study of the Wunugetu Cu–Mo deposit,Inner Mongolia,China

Hydrothermal alteration and mineralization at the Wunugetu porphyry Cu–Mo deposit, China, include four stages, i.e., the early stage characterized by quartz, K-feldspar and minor mineralization, followed by a molybdenum mineralization stage associated with potassic alteration, copper mineralization associated with sericitization, and the last Pb–Zn mineralization stage associated with carbonation. Hydrothermal quartz contains three types of fluid inclusions, namely aqueous (W-type), daughter mineral-bearing (S-type) and CO₂-rich (C-type) inclusion, with the latter two types absent in the late stage. Fluid inclusions in the early stage display homogenization temperatures above 510°C, with salinities up to 75.8 wt.% NaCl equivalent. The presence of S-type inclusions containing anhydrite and hematite daughter minerals and C-type inclusions indicates an oxidizing, CO₂-bearing environment. Fluid inclusions in the Mo- and Cu-mineralization stages yield homogenization temperatures of 342–508°C and 241–336°C, and salinities of 8.6–49.4 and 6.3–35.7 wt.% NaCl equivalent, respectively. The presence of chalcopyrite instead of hematite and anhydrite daughter minerals in S-type inclusions indicates a decreasing of oxygen fugacity. In the late stage, fluid inclusions yield homogenization temperatures of 115–234°C and salinities lower than 12.4 wt.% NaCl equivalent. It is concluded that the early stage fluids were CO₂ bearing, magmatic in origin, and characterized by high temperature, high salinity, and high oxygen fugacity. Phase separation occurred during the Mo- and Cu-mineralization stages, resulting in CO₂ release, oxygen fugacity decrease and rapid precipitation of sulfides. The late-stage fluids were meteoric in origin and characterized by low temperature, low salinity, and CO₂ poor.     

A hypothesis of the Senoumi submarine megaslide in Suruga Bay in Japan—based on the undrained dynamic-loading ring shear tests and computer simulation

The distinctive bathymetric feature exists in the Suruga Bay, Japan. It has been called as Senoumi (Stone flower sea) from old times. Senoumi is a 30?km wide and 20?km long concave feature. Its origin has not been explained yet; however, the feature might be a combined consequence of intensive tectonic activity in the plate border, landslides, and a submarine flow coming from the Oi River. If the Senoumi was caused by a landslide, the latter would be larger than any on-land landslide in Japan. The downshelf “exit” from this feature is much narrower than its central part. This is not usual shape of landslides, but it is similar to the liquefied landslides such as those in quick clays which mobilize great strength reduction after failure. To study Senoumi as a landslide, the shear behaviors of the following three soil samples were investigated by the cyclic and seismic undrained stress control ring shear tests. One sample is volcanic ash taken from the base of landslide deposits (mass transport deposits), from 130 to 190?m deep layer below the submarine floor which was drilled and cored by the Integrated Ocean Drilling Program Expedition 333. Another two samples are the Neogene silty–sand and silt taken from the Omaezaki hill adjacent to the Senoumi, because the shear zone might have been formed in Neogene layers extending from on-land to the continental shelf. The largest strength reduction from peak to steady-state shear resistance in the undrained cyclic loading test was found in volcanic ash. The strength reduction in Neogene silty–sand was smaller than volcanic ash, while the Neogene silt mobilized the least post-failure strength reduction. An integrated model simulating the initiation and motion of earthquake-induced rapid landslides (landslide simulation (LS)-RAPID, Sassa et al. Landslides 7–3:219–236, 2010) was applied to this study. The steady-state shear resistance and other geotechnical parameters measured by the undrained ring shear tests and the greatest strong motion record in the 2011 off-the-Pacific Coast of Tohoku earthquake (M _w 9.0), also known as “2011 Tohoku Earthquake” at the observation point MYG004 (2,933?gal) were input to this model. As the result, it was found that landslides would be triggered by 0.30–1.0 times of MYG004 in volcanic ash, 0.4–1.0 times of MYG004 in Neogene silty–sand and Neogene silt, though the depth and area of triggered landslides were different in soils and intensity of shaking. Feature, created by LS-RAPID using the parameters of volcanic ash, was most similar to the Senoumi in depth and extent. The result obtained from this study includes a hypothesis to be proved, but presents the strong need to investigate the risk of the large-scale submarine landslides which could enhance tsunami wave and possibly enlarge the submarine landslide retrogressively into the adjacent coastal plain by the upcoming mega earthquake in the Nankai Trough.     

A strong-motion database from the Peru–Chile subduction zone

Earthquake hazard along the Peru–Chile subduction zone is amongst the highest in the world. The development of a database of subduction-zone strong-motion recordings is, therefore, of great importance for ground-motion prediction in this region. Accelerograms recorded by the different networks operators in Peru and Chile have been compiled and processed in a uniform manner, and information on the source parameters of the causative earthquakes, fault-plane geometries and local site conditions at the recording stations has been collected and reviewed to obtain high-quality metadata. The compiled database consists of 98 triaxial ground-motion recordings from 15 subduction-type events with moment magnitudes ranging from 6.3 to 8.4, recorded at 59 different sites in Peru and Chile, between 1966 and 2007. While the database presented in this study is not sufficient for the derivation of a new predictive equation for ground motions from subduction events in the Peru–Chile region, it significantly expands the global database of strong-motion data and associated metadata that can be used in the derivation of predictive equations for subduction environments. Additionally, the compiled database will allow the assessment of existing predictive models for subduction-type events in terms of their suitability for the Peru–Chile region, which directly influences seismic hazard assessment in this region.