The relationships between drastic changes in Sr isotope ratios of magma sources beneath the NE Japan arc and the spreading of the Japan sea back-arc basin

Summary Based on Sr isotopic data for Tertiary and Quaternary basaltic rocks from the NE Japan arc, relationships are discussed between the temporal variation of magma source characteristics and the opening of the Japan Sea. The basaltic rocks from the trench side and from the transitional zone show initial⁸⁷Sr/⁸⁶Sr ratios (Sr_i ratios) in the range of 0.70411–0.70546 but no temporal variation in Sr_i ratios. The back-arc side basaltic rocks with ages of 29.8 to 15 Ma have Sr_i ratios similar to those of the trench side and the transitional zone, and these values also show no temporal change. In contrast, the basaltic rocks from the back-arc side, with ages younger than 15 Ma, show significantly lower Sri ratios (0.70396 to 0.70290), which are slightly higher than those of N-type MORB. These Sr isotopic features may imply that at least before 15 Ma the magma source regions (the sub-continental mantle) beneath the NE Japan arc had an enriched chemical character and that after 15 Ma, the magma sources for volcanic rocks from the back-arc side show a drastic change in Sr isotopic character, from an enriched nature to a depleted one. The depleted magmas may have been formed as a result of injection of depleted asthenosphere (or of a depleted mantle diapir) into the subcontinental mantle under the back-arc side of the NE Japan arc, during the spreading of the Japan Sea back-arc basin. The middle Miocene basaltic rocks from the back-arc side are characterized by lower contents of LIL elements such as K₂O and Rb compared with those from the trench side, suggesting that during the middle Miocene (syn-opening stage of the Japan Sea) the degree of partial melting may have been higher in the back-arc side mantle than in the trench side mantle. High degree of partial melting in the back-arc side mantle can be attributed to an increasing geothermal gradient in the mantle due to the injection of hot asthenosphere. This injection might also have caused the melting of the lower crust from which the voluminous middle Miocene acidic volcanics in the back-arc side and transitional zone may have been produced.

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Drastische Veränderungen der Sr-Isotopenverhältnisse von Magmenquellen unterhalb des NE japanischen Vulkanbogens und ihre Beziehung zum Spreading des japanischen Back-Arc-Beckens

Zusammenfassung Die Beziehungen zwischen der zeitlichen Veränderung der Charakteristika von Magmenquellen und der Öffnung des Japanischen Meeres werden anhand von Sr-Isotopendaten tertiärer und quartärer basaltischer Gesteine diskutiert. Basaltische Gesteine von der Grabenseite und aus der Übergangszone ergaben initiale⁸⁷Sr/⁸⁶Sr Verhältnisse (Sr_i-Verhältnisse) von 0.70411–0.70546 und lassen keine zeitabhängige Änderung erkennen. Basaltische Besteine aus dem Back-Arc-Bereich mit Altern zwischen 29.8 und ca. 15 Ma zeigen ähnliche Sr_i-Verhältnisse und ebenfalls keine zeitliche Veränderung. Im Gegensatz dazu sind basaltische Gesteine aus dem Back-Arc-Bereich, die jünger als ca. 15 Ma sind, signifikant in ihren Sr_i-Verhältnissen (0.70396–0.70290) erniedrigt. Diese Verhältnisse liegen etwas höher als die von N-MORB. Die Sr-Isotopenergebnisse lassen vermuten, daß zumindest vor ca. 15 Ma der Herkunftsbereich der Magmen (subkontinentaler Mantel) unter dem NE japanischen Vulkanbogen chemisch angereichert war, während die Magmenquellen der jüngeren vulkanischen Gesteine des Back-Arc-Bereiches durch eine drastische Abreicherung charakterisiert sind. Die abgereicherten Magmen könnten, während der Öffnung des japanischen Back-Arc-Beckens, als Folge der Injektion abgereicherter Asthenosphäre (oder eines abgereicherten Manteldiapirs) in subkontinentalen Mantel unterhalb des Back-Arcs des NE japanischen Vulkanbogens, gebildet worden sein. Die miozänen basaltischen Gesteine des Back-Arc-Bereiches sind außerdem durch niedrigere Gehalte an LIL-Elementen, wie z.B. K₂O und Rb charakterisiert. Dies wird als Hinweis auf eine erhöhte Aufschmelzungsrate in diesem Bereich im mittleren Miozän (im Zuge der gleichzeitigen Öffnung des japanischen Meeres) verstanden. Die erhöhte Aufschmelzrate im Mantel des Back-Arc-Breiches wird auf einer Erhöhung des geothermischen Gradienten infolge der Injektion von heißer Asthenosphäre zurückgeführt. Diese Injektion von Asthenosphäre könnte auch der Grund für die Aufschmelzung von Unterkruste und für die Produktion weitverbreiteter saurer miozäner Vulkanite im Back-Arc-Bereich und der Übergangszone sein.

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With 6 Figures     

Blueschist-facies metamorphism during Paleozoic orogeny in southwestern Japan: Phengite K–Ar ages of blueschist-facies tectonic blocks in a serpentinite melange beneath early Paleozoic Oeyama ophiolite

Blueschist-bearing Osayama serpentinite melange develops beneath a peridotite body of the Oeyama ophiolite which occupies the highest position structurally in the central Chugoku Mountains. The blueschist-facies tectonic blocks within the serpentinite melange are divided into the lawsonite–pumpellyite grade, lower epidote grade and higher epidote grade by the mineral assemblages of basic schists. The higher epidote-grade block is a garnet–glaucophane schist including eclogite-facies relic minerals and retrogressive lawsonite–pumpellyite-grade minerals. Gabbroic blocks derived from the Oeyama ophiolite are also enclosed as tectonic blocks in the serpentinite matrix and have experienced a blueschist metamorphism together with the other blueschist blocks. The mineralogic and paragenetic features of the Osayama blueschists are compatible with a hypothesis that they were derived from a coherent blueschist-facies metamorphic sequence, formed in a subduction zone with a low geothermal gradient (~ 10°C/km). Phengite K–Ar ages of 16 pelitic and one basic schists yield 289–327 Ma and concentrate around 320 Ma regardless of protolith and metamorphic grade, suggesting quick exhumation of the schists at ca 320 Ma. These petrologic and geochronologic features suggest that the Osayama blueschists comprise a low-grade portion of the Carboniferous Renge metamorphic belt. The Osayama blueschists indicate that the 'cold' subduction type (Franciscan type) metamorphism to reach eclogite-facies and subsequent quick exhumation took place in the northwestern Pacific margin in Carboniferous time, like some other circum-Pacific orogenic belts (western USA and eastern Australia), where such subduction metamorphism already started as early as the Ordovician.     

Geochemistry and geochronology of the mafic lavas from the southeastern Ethiopian rift (the East African Rift System): assessment of models on magma sources,plume–lithosphere interaction and plume evolution

Major and trace element and isotopic ratios (Sr, Nd and Pb) are presented for mafic lavas (MgO > 4 wt%) from the southwestern Yabello region (southern Ethiopia) in the vicinity of the East African Rift System (EARS). New K/Ar dating results confirm three magmatic periods of activity in the region: (1) Miocene (12.3–10.5 Ma) alkali basalts and hawaiites, (2) Pliocene (4.7–3.6 Ma) tholeiitic basalts, and (3) Recent (1.9–0.3 Ma) basanite-dominant alkaline lavas. Trace element and isotopic characteristics of the Miocene and Quaternary lavas bear a close similarity to ocean island basalts that derived from HIMU-type sublithospheric source. The Pliocene basalts have higher Ba/Nb, La/Nb, Zr/Nb and ⁸⁷Sr/⁸⁶Sr (0.70395–0.70417) and less radiogenic Pb isotopic ratios (²⁰⁶Pb/²⁰⁴Pb = 18.12–18.27) relative to the Miocene and Quaternary lavas, indicative of significant contribution from enriched subcontinental lithospheric mantle in their sources. Intermittent upwelling of hot mantle plume in at least two cycles can explain the magmatic evolution in the southern Ethiopian region. Although plumes have been originated from a common and deeper superplume extending from the core–mantle boundary, the diversity of plume components during the Miocene and Quaternary reflects heterogeneity of secondary plumes at shallower levels connected to the African superplume, which have evolved to more homogeneous source.     

Radiometric ages of Alpine metamorphic rocks in the western and central Alps

Abstract The chronological characteristics of Alpine metamorphic rocks are described and Alpine metamorphic events are reinterpreted on the basis of chronological data for the western and central Alps from 1960 to 1992. Metamorphic rocks of the Lepontine, Gran San Bernardo, Piemonte, Internal Crystalline Massifs and Sesia-Lanzo mostly date Alpine metamorphic events, but some (along with granitoids and gneisses from the Helvetic and Southern Alps) result from the Variscan, Caledonian or older events and thus predate the Alpine events. Radiometric age data from the Lepontine area show systematic age relations: U-Pb monazite (23-29 Ma), Rb-Sr muscovite (15–40 Ma) and biotite (15–30 Ma), K-Ar biotite (10-30 Ma), muscovite (15–25 Ma) and hornblende (25-35 Ma), and FT zircon (10-20 Ma) and apatite (5-15 Ma), which can be explained by the different closure temperatures of the isotopic systems. A 121 Ma U-Pb zircon age for a coesite-bearing whiteschist (metaquartzite) from the Dora-Maira represents the peak of ultra-high pressure metamorphism. Coesite-free eclogites and blueschists related to ultra-high pressure rocks in the Penninic crystalline massifs yield an ⁴⁰Ar-³⁹Ar plateau age of about 100 Ma for phengites, interpreted as the cooling age. From about 50 Ma, eclogites and glaucophane schists have also been reported from the Piemonte ophiolites and calcschists, suggesting the existence of a second high P/T metamorphic event. Alpine rocks therefore record three major metamorphic events: (i) ultra-high and related high P/T metamorphism in the early Cretaceous, which is well preserved in continental material such as the Sesia-Lanzo and the Penninic Internal Crystalline Massifs; (ii) a second high P/T metamorphic event in the Eocene, which is recognized in the ophiolites and calcschists of the Mesozoic Tethys; and (iii) medium P/T metamorphism, in which both types of high P/T metamorphic rocks were variably reset by Oligocene thermal events. Due to the mixture of minerals formed in the three metamorphic events, there is a possibility that almost all geochronological data reported from the Alpine metamorphic belt show mixed ages. Early Cretaceous subduction of a Tethyan mid-ocean ridge and Eocene continental collision triggered off the exhumation of the high pressure rocks.     

Phengite K-Ar ages of schists from the Sanbagawa southern marginal belt, central Shikoku, southwest Japan: Influence of detrital mica and deformation on age

Abstract K–Ar age determinations were carried out on phengite separates from pelitic schists collected systematically from the Sanbagawa southern marginal belt and the associated area. The petrography and phengite chemistry by electron probe micro-analyzer (EPMA) revealed the existence of detrital white micas in the schist that have an extremely older age (108 Ma) in comparison with the neighboring schists (88 Ma) without any detrital mica. The ages become gradually older from the north ( ca 78 Ma) to the south ( ca 90 Ma) except for some samples that contain detrital micas and/or have been reactivated thermally by intrusives. The age is interpreted as an exhumation-cooling age that has been controlled by the ductile deformation of the host rocks that have never experienced a culmination temperature higher than 350°C which corresponds to the closure temperature of the K–Ar phengite system. The southward aging of the recorded ages in the extensive chlorite zone of the central Shikoku, from the Dozan river area of the north ( ca 65 Ma) to the study area of the south ( ca 85 Ma) through the Asemi river area ( ca 75 Ma), is explained in terms of increasing exhumation/cooling rates of the host rocks from north to south. The phengite K–Ar ages in the pelitic schists from the Kyomizu tectonic zone, which is classically considered as a remarkable thrusting shear zone, have no significant difference in comparison with that of the neighboring schists. This fact suggests that the latest stage of brittle deformation during exhumation/uplift has not significantly affected the ages of phengite in the schists.     

White mica K-Ar ages of blueschist-facies rocks from the Piemonte 'calc-schists' of the western Italian Alps

Abstract Fifty calc-schists have been systematically collected from the Piemonte zone of the western Italian Alps and examined in terms of petrology, X-ray powder diffractometer (XRD) analysis of carbonaceous materials, and K-Ar ages of white mica separates. The petrological study and XRD analysis of carbonaceous materials have shown that calc-schists have suffered blueschist-facies metamorphism in the subduction zone of the convergent margin between the Apulian (African) continental and Tethyan oceanic plates. The metamorphic sequence is divided into three mineral zones based on increasing metamorphic temperature: chlorite (lower than 300°C), chloritoid, and rutile (higher than 450°C). The chlorite zone has dispersed ages of white mica separates, ranging from 115 to 44 Ma, whereas the rutile zone has a comparatively uniform age distribution from 60 to 40 Ma. The chloritoid zone has an intermediate age variation. The large variation in the chlorite zone is attributed to mixing of variable amounts of detrital mica derived from older high temperature metamorphic rocks in the separates, which have not been completely reset during Alpine metamorphism. The uniform age (average ca 50 Ma) in the rutile zone is the cooling age of blueschist-facies calc-schists, which have been episodically exhumed at the collision event of the European and Apulian continents in the Paleocene-Eocene.     

Noble gas isotopic composition of deep underground water in Osaka plain, central Japan: Evidence for mantle He and model for new volcanism

Abstract Elemental and isotopic compositions of noble gases extracted from the bore hole water in Osaka plain, central Japan were examined. The water samples were collected from four shallow bore holes (180-450 m) and seven deep bore holes (600-1370 m) which have been used for an urban resort hot spring zone. The water temperatures of the deep bore holes were 22-50°C and that of the shallow bore holes, 13-23°C. The elemental abundance patterns show the progressive enrichment of the heavier noble gases compared with the atmospheric noble gas composition except for He, which is heavily enriched in deep bore hole water samples. ³He/⁴He ratios from the bore holes reaching the Ryoke granitic basement were higher than the atmospheric value (1.4 × 10⁻⁶), indicating a release of mantle He through the basement. The highest value of 8.2 × 10⁻⁶ is in the range of arc volcanism. On the other hand, the bore holes in sedimentary rocks overlying the basement release He enriched in radiogenic ⁴He, resulted in a low ³He/⁴He ratio of 0.5 × 10⁻⁶. ⁴He/²⁰Ne and ⁴⁰Ar/³⁶Ar ratios indicate that the air contamination is generally larger in shallow bore holes than in deep ones from each site. The helium enriched in mantle He is compatible with the previous work which suggested up-rising magma in 'Kinki Spot', the area of Osaka and western Wakayama, in spite of no volcanic activity in the area. A model to explain an initiation of magma generation beneath this area is presented.     

Carbonaceous material in pelitic schists of the Sanbagawa metamorphic belt in central Shikoku,Japan

Carbonaceous material in pelitic schists of the Sanbagawa metamorphic belt in central Shikoku, Japan, was separated from the host rocks and its X-ray diffraction and chemical composition were studied. Its crystal structure and chemistry change continously with increasing metamorphic grade and approach those of well-ordered graphite near the biotite isograd. As graphitization is a rate process, the temperature of complete graphitization differs from one metamorphic terrain to another as a function of the duration of metamorphism. In an individual metamorphic terraan, however, the degree of graphitization is a useful indicator of relative metamorphic temperature in lower-grade rocks.     

Asymmetric X-ray diffraction peak of metamorphosed carbonaceous material

Abstract It was revealed that the asymmetric X-ray diffraction peak of metamorphosed carbonaceous material was a combination of two types of symmetric peaks from the coaly material and graphite crystallite. Numerical synthesis using the two symmetric peaks shows the graphitization process observed in a metamorphic sequence is accompanied by a continuous change of the peak shape and apparent interplanar spacing. Based on the analytical results and geological observations, it is suggested that graphitization of carbonaceous material consists of two processes: (i) the formation of graphite crystallites at the expense of the coaly material through the formation of transitional material and the increasing abundance of crystallites which is observed in the chlorite zone; and (ii) growth of crystallites forming well-ordered graphite, which occurs in the higher-grade zone.