Twin formation in hematite during dehydration of goethite

Twin formation in hematite during dehydration was investigated using X-ray diffraction, electron diffraction, and high-resolution transmission electron microscopy (TEM). When synthetic goethite was heated at different temperatures between 100 and 800 °C, a phase transformation occurred at temperatures above 250 °C. The electron diffraction patterns showed that the single-crystalline goethite with a growth direction of [001]_G was transformed into hematite with a growth direction of [100]_H. Two non-equivalent structures emerged in hematite after dehydration, with twin boundaries at the interface between the two variants. As the temperature was increased, crystal growth occurred. At 800 °C, the majority of the twin boundaries disappeared; however, some hematite particles remained in the twinned variant. The electron diffraction patterns and high-resolution TEM observations indicated that the twin boundaries consisted of crystallographically equivalent prismatic (100) (010), and (1\(\bar{1}\)0) planes. According to the total energy calculations based on spin-polarized density functional theory, the twin boundary of prismatic (100) screw had small interfacial energy (0.24 J/m²). Owing to this low interfacial energy, the prismatic (100) screw interface remained after higher-temperature treatment at 800 °C.     

Cordilleran-type orogeny and episodic growth of continents: Insights from the circum-Pacific continental margins

A new material migration hypothesis for the plate subduction zone orogeny, so-called ‘the cordilleran-type orogeny’, is proposed on the basis of geological constraints as well as mechanics of accretionary wedges. The major tectonic processes of the hypothesis comprise: (i) episodic, extensive magmatism along the margin of an overriding plate; (ii) supply of voluminous igneous and eroded materials through forearc to trench, with an increase in the net sediment influx into trench; (iii) accelerated accretion of sediments beneath an overriding older accretionary wedge; and (iv) upward material migration within the wedge and resultant exhumation of high-P/T metamorphic rocks near the inland margin of the wedge. This hypothesis was validated by the test using available geo- and thermo-chronological data from two classical types of subduction-related orogens in Southwest Japan and California. The hypothesis, coupled with the thermochronologic point of view, requires the reconsideration of coevality of paired metamorphism. The temporal pairing is to be observed between the beginning of the regional high-T/P metamorphism and that of the uplift and exhumation of high-P/T metamorphism, with some time lag needed for material migration. Where the temporal pairing is examined therefore, the formation age of igneous rocks and related high-T/P metamorphic rocks should be compared to the exhumation age of high-P/T metamorphic rocks. The episodic, extensive magmatism that triggers the cordilleran-type orogeny shows a temporal correlation in the mid-Cretaceous for most circum-Pacific continental margins. The resultant widespread formation of accretionary complexes is also observed in the western part of the circum-Pacific margins. The deduced mid-Cretaceous circum-Pacific orogeny accompanied a gross increase in the continental crust production rate, and was approximately coeval with the Pangea breakup and the Central Pacific superplume episode, implying the orogeny as a part of the mid-Cretaceous pulsation of the Earth.     

哈密盆地北缘活动断裂带微地貌

哈密盆地北线活动断裂带走向北西西,断续长180km。8条剖面的GPS测量结果显示,断坎坡度为15°～18°及31°～33°．单个断崖高3～10m。由年代学资料计算出该断裂带中全新世垂直活动速率为0．65±0．08mm／a,比晚更新世晚期垂直活动速率有所增大。     

Experimental investigation on cohesionless sandy bank failure resulting from water level rising

In the last decade, sediment replenishment forming cohesionless sandy banks below dams has become an increasingly common practice in Japan to compensate for sediment deficits downstream. The erosion process of the placed cohesionless sediment is a combination of lateral toe-erosion and the following mass failure. To explore cohesionless bank failure mechanisms, a series of experiments was done in a soil tank using a compacted sandy soil mass exposed to an increasing water level. Two types of uniform sand(D_(50) = 0.40 mm and 0.17 mm) and two bank heights(50 cm and 25 cm) were used under the condition of a constant bank slope of 75°. The three dimensional(3D) geometry of the bank after failure was measured using a handheld 3D scanner. The motion of bank failure was captured using the particle image velocimetry(PIV) technique, and the matric suction was measured by tensiometers. The compacted sandy soil was eroded by loss of matric suction accompanying the rise in water level which subsequently caused rotational slide and cantilever toppling failure due to destabilization of the bank. The effect of erosion protection resulting from the slumped blocks after these failures is discussed in the light of different failure mechanisms. Tensile strength is analyzed by inverse calculation of cantilever toppling failure events. The tensile strength had non-linear relation with degree of saturation and showed a peak.The findings of the study show that it is important to incorporate the non-linear relation of tensile strength into stability analysis of cantilever toppling failure and prediction of tension crack depth within unsaturated cohesionless banks.     

http://www.sciencedirect.com/science/article/pii/S1674987112000643

Incipient charnockites represent granulite formation on a mesoscopic scale and have received considerable attention in understanding fluid processes in the deep crust.Here we report new petrological data from an incipient charnockite locality at Rajapalaiyam in the Madurai Block,southern India,and discuss the petrogenesis based on mineral phase equilibrium modeling and pseudosection analysis. Rajapalaiyam is a key locality in southern India from where diagnostic mineral assemblages for ultrahigh-temperature（UHT） metamorphism have been reported.Proximal to the UHT rocks are patches and lenses of charnockite（Kfs + Qtz + Pl + Bt + Opx + Grt + Ilm） occurring within Opx-free Grt-Bt gneiss（Kfs + Pl + Qtz + Bt + Grt + Ilm + Mt） which we report in this study.The application of mineral equilibrium modeling on the charnockitic assemblage in NCKFMASHTO system yields a p-T range of～820℃and～9 kbar.Modeling of the charnockite assemblage in the MnNCKFMASHTO system indicates a slight shift of the equilibrium condition toward lower p and T（～760℃and～7.5 kbar）. which is consistent with the results obtained from geothermobarometry（710—760℃,6.7—7.5 kbar）. but significantly lower than the peak temperatures（>1000℃） recorded from the UHT rocks in this locality,suggesting that charnockitization is a post-peak event.The modeling of T versus molar H₂O content in the rock（M（H₂O）） demonstrates that the Opx-bearing assemblage in charnockite and Opxfree assemblage in Grt-Bt gneiss are both stable at M（H₂O） = 0.3 mol%-0.6 mol%.and there is no significant difference in water activity between the two domains.Our finding is in contrast to the previous petrogenetic model of incipient charnockite formation which envisages lowering of water activity and stabilization of orthopyroxene through breakdown of biotite by dehydration caused by the infiltration of CO₂-rich fluid.T-X_Fe³⁺（= Fe₂O₃/（FeO + Fe₂O₃） in mole） pseudosections suggest that the oxidation condition of the rocks played a major role on the stability of orthopyroxene:Opx is stable at X_Fe³⁺ <0.03 in charnockite.while Opx-free assemblage in Grt-Bt gneiss is stabilized at X_Fe³⁺ >0.12.Such low oxygen fugacity conditions of X_Fe³⁺ <0.03 in the charnockite compared to Grt-Bt gneiss might be related to the infiltration of a reduced fluid（e.g.,H₂O + CH₄） during the retrograde stage.     

Geometry of stress function surfaces for an asymmetric continuum

A two-dimensional stress field of dislocation or fault is geometrically studied for an asymmetric continuum. For geometric surfaces of the stress and couple-stress functions, the mean and Gaussian curvatures are derived. The mean curvature of couple-stress function surface is connected with the asymmetric of stress tensor. Moreover, the Gaussian curvature of stress function surface is characterized by both the stress and couple-stress. On the other hand, the mean curvature of stress function surface is not affected by the asymmetry of stress. Based on these geometric expressions, the Coulomb’s failure criterion and the friction coefficient are expressed by the curvatures of couple-stress function surface. Moreover, geometric structures of stress and couple stress function surfaces are shown for edge and wedge dislocations as faults. The curvatures of these surfaces show that the effect of couple-stress is constrained around the dislocations only.     

Validation of TRMM Precipitation Radar satellite data over Indonesian region

Research has been conducted to validate monthly and seasonal rain rates derived from the Tropical Rainfall Measuring Mission Precipitation Radar (PR) using rain gauge data analysis from 2004 to 2008. The study area employed 20 gauges across Indonesia to monitor three Indonesian regional rainfall types. The relationship of PR and rain gauge data statistical analysis included the linear correlation coefficient, the mean bias error (MBE), and the root mean square error (RMSE). Data validation was conducted with point-by-point analysis and spatial average analysis. The general results of point-by-point analysis indicated satellite data values of medium correlation, while values of MBE and RMSE tended to indicate underestimations with high square errors. The spatial average analysis indicated the PR data values are lower than gauge values of monsoonal and semi-monsoonal type rainfall, while anti-monsoonal type rainfall was overestimated. The validation analysis showed very good correlation with the gauge data of monsoonal type rainfall, high correlation for anti-monsoonal type rainfall, but medium correlation for semi-monsoonal type rainfall. In general, the statistical error level of monthly seasonal monsoonal type conditions is more stable compared to other rainfall types. Unstable correlations were observed in months of high rainfall for semi-monsoonal and anti-monsoonal type rainfall.     

Decline in heavy metal contamination in marine sediments in Jakarta Bay,Indonesia due to increasing environmental regulations

The ²¹⁰Pb geochronology, heavy metal concentrations (Zn, Cu, and Pb), and stable Pb isotope ratios (²⁰⁶Pb/²⁰⁷Pb) of three sediment cores collected from Jakarta Bay were analyzed to decipher the history of heavy metal contamination in the period 1900–2006. The chemical and isotopic analyses clearly suggest that anthropogenic metal accumulation in the sediments began in the 1920s and increased greatly from the 1970s until the end of the 1990s. From the end of the 1990s to 2006, accumulation rates were constant or decreased for Zn and Pb near the coastal industrialized area. Comparison of economic data and sociological information suggests that the decline in the concentrations of heavy metals could be attributed to the stricter environmental regulations which were enforced at the end of 1990s. However, metal contamination is currently still an important cause of concern in dealing with environmental preservation and protection in Jakarta Bay.