Dissolved and labile particulate Zr,Hf, Nb,Ta, Mo and W in the western North Pacific Ocean

Dissolved and labile particulate Zr, Hf, Nb, Ta, Mo and W were determined at stations K1 (51°N, 165°E), K2 (47°N, 160°E), KNOT (44°N, 155°E) and 35N (35°N, 160°E) in the western North Pacific Ocean. A portion of seawater for dissolved species (D) was passed through a 0.2 μm Nuclepore filter and acidified to pH 2.2 with HCl and HF. A portion of seawater for acid-dissolvable species (AD) was acidified without filtration. Labile particulate (LP) species is defined as AD minus D, which represents a chemically labile fraction of particulate species. D-Zr, Hf and Ta increase with depth, Nb shows a slight depletion in surface water, whereas Mo and W have a conservative vertical profile. The concentration range of D-Zr, Hf, Nb, Ta and W is 31–275, 0.14–0.95, 4.0–7.2, 0.08–0.29 and 40–51 pmol kg⁻¹, respectively, whereas that of Mo is 97–105 nmol kg⁻¹. LP-species of Zr, Hf and Ta account for 10–14% of AD in average and increase up to 25% below 4000 m, whereas those for Mo and W are negligible. In contrast, LP-Nb shows maxima (up to 27%) in surface water. We also found that D-Zr/Hf, Nb/Ta and Mo/W mole ratios generally increase in the order continental crust < river water < coastal sea < open ocean.     

Palynological evidence for late Holocene environmental change on the Gimhae fluvial plain,Southern Korean peninsula: Reconstructing the rise and fall of Golden Crown Gaya State

This paper presents the results of detailed studies of palynomorphs recovered from two cores collected near the Yeanri burial mound on the Gimhae fluvial plain. Two local pollen zones were recognized on the basis of variations in the palynofloral assemblage: a lower Pollen Zone I, dominated by a Pinus‐Quercus assemblage, and an upper Pollen Zone II, dominated by a Pinus‐Quercus‐Gramineae assemblage. The palynological and molluscan analyses indicate that the depositional environments changed from a lower intertidal flat of a shallow bay environment to an upper intertidal flat in a shallow bay (before 1280 ± 110 ¹⁴C yr B.P.), and finally to a fluvial plain similar to that of today. This environmental change may have resulted from uplift along the Yangsan Fault. Afterward, the exposed area was modified by human activities, as indicated by a sudden increase in grassland herbaceous pollen grains. The loss of this bay likely had a dramatic effect on the Golden Crown Gaya State (3rd–7th centuries A.D.), which used it as a major port for regional trade, and may explain why it eventually merged with the Shilla State. © 2003 Wiley Periodicals, Inc.