亚洲500毫巴候平均环流与我国候平均气温之关系的时空结构

本文从分析亚洲500毫巴候平均环流得到的前五项自然正交函数的时间系数出发,利用互谱分析方法,研究了候平均环流演变与我国大范围候平均温度的关系在频率域上的特征,得到了凝聚函数显著的主要频带;初步探讨了这种关系的时空结构。这对于深入认识长期天气过程和以环流演变为因子的候平均温度的预报提供了依据和途径。     

TOTAL LIPID AND FATTY ACID COMPOSITION OF EIGHT STRAINS OF MARINE DIATOMS

Fatty acid composition and total lipid content of 8 strains of marine diatoms (Nitzschia frustrula, Nitzschia closterium, Nitzschia incerta, Navicula pelliculosa, Phaeodactylum tricornutum, Synedra fragilaroides) were examined. The microalgae were grown under defined conditions and harvested at the late exponential phase. The major fatty acids in most strains were 14∶0 (1.0%–6.3%), 16∶0 (13.5–26.4%), 16∶1n−7 (21.1%–46.3%) and 20∶5n−3 (6.5%–19.5%). The polyunsaturated fatty acids 16∶2n−4, 16∶3n−4, 16∶4n−1 and 20∶4n−6 also comprised a significant proportion of the total fatty acids in some strains. The characteristic fatty acid composition of diatoms is readily distinguishable from those of other microalgal groups. Significant concentration of the polyunsaturated fatty acid 20∶5n−3 (eicosapentaenoic acid) was present in each strain, with the highest proportion in B222 (19.5%). Project supported by the Hi-Tech “863” Programs of the China Ministry of Science and Technology (863-819-02-01).     

An Estimation of Internal Soliton Forces on a Pile in the Ocean

Internal soliton forces on oil-platform piles in the ocean are estimated with the Morison Formula. Different from sur- face wave forces, which change only in magnitude along a pile, internal soliton forces can be distributed over the entire pile in the water and they change not only in magnitude but also in direction with depth. Our calculations show that the maximum total force caused by a soliton with its associated current of 2.1 m s-1 is nearly equal to the maximum total force exerted by a surface wave with a wavelength of 300 m and a wave-height of 18 m. The total internal soliton force is large enough to affect the operations of marine oil platforms and other facilities. Therefore, the influence of internal solitons should not be neglected in the design of oil platforms.     

三维空间中简单线与体之间的拓扑关系研究

三维空间对象的拓扑关系对于研究三维空间对象的操作及其算法至关重要。本文在详细研究拓扑关系的9-交和4-交模型的基础上,指出了它们在表达简单线与体拓扑关系上的局限性,9-交模型的线性相关性以及4-交模型的不完备性。进而提出简单线与体拓扑关系表达的扩展4-交模型,运用扩展4-交模型详细分析了简单线与体的拓扑关系,并给出图示。接着对所提扩展4-交模型线性无关性及完备性进行了论证。最后对所提出的扩展4-交模型进行了总结性说明。     

Ga和Sb纳米线声子结构和电子-声子相互作用的第一性原理研究

基于密度泛函理论的第一性原理方法,系统研究了Ga和Sb纳米线的电子能带结构和声子结构以及电子-声子耦合(EPC)作用.通过对声子的完整Brillouin区分析来研究纳米线的结构稳定性.结果表明,所考察的纳米线显示出不稳定性,不稳定声子波矢远离Brillouin区中心.与通常的Peierls变形机理相比,不稳定的横向声子模会导致一种无开口带隙的相变.Sb比Ga纳米线的EPC要强很多,并且横向变形导致的锯齿形结构使纳米线中的电子-声子相互作用增加了几个数量级.     

boldmath Investigation of inter-molecular hydrogen bonding in the binary mixture (acetone + water) by concentration dependent Raman study and ab initio calculations

This paper reports that vibrational spectroscopic analysis on hydrogen-bonding between acetone and water comprises both experimental Raman spectra and ab initio calculations on structures of various acetone/water complexes with changing water concentrations. The optimised geometries and wavenumbers of the neat acetone molecule and its complexes are calculated by using ab initio method at the MP2 level with 6-311+G(d,p) basis set. Changes in wavenumber position and linewidth (fullwidth at half maximum) have been explained for neat as well as binary mixtures with different mole fractions of the reference system, acetone, in terms of intermolecular hydrogen bonding. The combination of experimental Raman data with ab initio calculation leads to a better knowledge of the concentration dependent changes in the spectral features in terms of hydrogen bonding.     

折射/谐衍射红外双波段成像光谱仪系统研究

为了获取足够的目标信息,充分利用中波红外和长波红外的光谱信息,建立了谐衍射中、长波红外超光谱成像系统.利用谐衍射元件独特的色散特性,将谐衍射透镜应用于中、长波红外超光谱成像系统中,使系统在中波红外3.7—4.8 μm和长波红外8—12 μm的2个红外大气窗口内获取数百个光谱图像.设计结果表明,中波红外波段,在18对线/mm处光学系统的调制传递函数(MTF)大于0.55;长波红外波段,在13对线/mm处光学系统的MTF大于0.5;光学系统的衍射环绕能,在中波红外波段30 μm半径范围内大于85%,在长波红外     

Nature and role of CO2 in some hot and cold HCO3/Na/CO2-rich Portuguese mineral waters: a review and reinterpretation

 At the northern part of the Portuguese mainland, the upflow zone of several hot and cold HCO₃/Na/CO₂-rich mineral waters is mainly associated with important NNE–SSW faults. Several geochemical studies have been carried out on thermal and non-thermal hydromineral manifestations that occur along or near these long tectonic alignments. The slight chemical differences that exist between these meteoric hot and cold HCO₃/Na/CO₂-rich mineral waters seem to be mainly caused by CO₂. δ¹³C_(TIDC) values observed in these groundwaters range between –6.00 and –1.00‰ versus V-PDB (V denotes Vienna, the site of the International Atomic Energy Agency; PDB originates from the CaCO₃ of the rostrum of a Cretaceous belemnite, Belemnitella americana, collected in the Peedee formation of South Carolina, USA) indicating a deep-seated (mantle) origin for most of the CO₂. Nevertheless, in the case of the heavier δ¹³C_(TIDC) values, the contribution of metamorphic CO₂ or the dissolution of carbonate rock levels at depth cannot be excluded. Concerning the hot waters, the lack of a positive ¹⁸O-shift should be attributed to water-rock interaction in a low temperature environment, rather than to the isotopic influence of CO₂ on the δ¹⁸O-value of the waters. Received: 9 August 1999 · Accepted: 8 March 2000     

ELECTROCHEMICAL CORROSION BEHAVIOR OF HOT DIP COATING IN ARTIFICIAL SEAWATER

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A new soil freeze/thaw discriminant algorithm using AMSR‐E passive microwave imagery

The soil freeze–thaw controls the hydrological and carbon cycling and thus affects water and energy exchanges at land surface. This article reported a newly developed algorithm for distinguishing the freeze/thaw status of surface soil. The algorithm was based on information from Advanced Microwave Scanning Radiometer Enhanced (AMSR‐E) which records brightness temperature (Tb) in the afternoon and after midnight. The criteria and discriminant functions were obtained from both radiometer observations and model simulations. First of all, the microwave radiation from freeze–thaw soil was examined by carrying out experimental measurements at 18·7 and 36·5 GHz using a Truck‐mounted Multi‐frequency Microwave Radiometer (TMMR) in the Heihe River of China. The experimental results showed that the soil moisture is a key component that differentiates the microwave radiation behaviours during the freeze–thaw process, and the differences in soil temperature and emissivity between frozen and thawed soils were found to be the most important criteria. Secondly, a combined model was developed to consider the impacts of complex ground surface conditions on the discrimination. The model simulations quite followed the trend of in situ observations with an overall relation coefficient (R) of approximately 0·88. Finally, the ratio of Tb18·7H (horizontally polarized Tb at 18·7 GHz) to Tb36·5V was considered primarily as the quasi‐emissivity, which is more reasonable and explicit in measuring the microwave radiation changes in soil freezing and thawing than the spectral gradient. By combining Tb36·5V to indicate the soil temperature variety, a Fisher linear discrimination analysis was used to establish the discriminant functions. After being corrected by TMMR measurements, the new discriminant algorithm had an overall accuracy of 86% when validated by 4‐cm soil temperature. The multi‐year discriminant results also provided a good agreement with the classification map of frozen ground in China. Copyright © 2011 John Wiley & Sons, Ltd.