Tannery Effluents: Current Practices,Environmental Consequences,Human Health Risks,and Treatment Options

The tannery industry influences the gross domestic product/economic activity of any country, but the uncontrolled release of tannery effluents causes environmental degradation and increases health risks to human. The reason for the toxicity of tannery effluents is the presence of high concentrations of organic and inorganic chemicals used in the production of leather goods. Untreated or partially treated effluents discharged into surface water results in an increase in both chemical and biological oxygen demand as well as in an increase in the levels of total suspended solids, dissolved solids, and toxic metals in environmental bodies, especially in soil, water bodies, and water sediments. Various treatment techniques, such as physicochemical, biological, and advanced oxidation methods, which include chemical precipitation, electrocoagulation, aerobic or anaerobic treatment, wetland construction, and Fenton, electro-Fenton, and photo-Fenton processes are also described. This review also discusses the technical appropriateness and economic feasibility of reducing the effluent pollution load and solid waste emanating from the tannery industry. Considering the enhanced health risks in the tannery waste treatment and management regime, some green and advanced technologies should be explored. A sustainable green technology that avoids the use of toxic chemicals in the tanning process is seen well for ecological health.     

Estimation of model parameter of Sumatra earthquake using empirical Green’s function technique and generation of hypothetical earthquake scenario for Andaman Island, India

Empirical Green??s function (EGF) technique is considered to be most effective technique for simulation of ground motions due to a finite earthquake source. In the present paper, this technique has been used to simulate ground motion due to a great earthquake. The coastal region of Sumatra Island has been visited by a great earthquake on December 26, 2004. This earthquake has been recorded at several broadband stations including a nearest broadband station PSI in Indonesia. The shear wave contributions in both horizontal components have been simulated at PSI station using EGF technique. The comparison of simulated and observed waveform has been made for various possibilities of rupture parameters in terms of root mean square error. The final rupture model supports rupture velocity of 3.0?km/s with nucleation point supporting northward propagating rupture that coincide with high-slip asperity defined by Sorensen et al. (Bull Seism Soc Am 97:S139?CS151, 2007). The final modeling parameters have been used to simulate record at MDRS station in coastal state of Tamilnadu, India. In an attempt to model a scenario of great earthquake in the Andaman Island, a hypothetical rupture plane is modeled in this region. The event occurred on August 10, 2008 of magnitude 6.2 (M _w ) recorded on strong motion array at Port Blair has been used as EGF to simulate records due to the hypothetical great earthquake. Possibilities of earthquake due to the oblique strike-slip and thrust mechanism have been modeled in the present paper. Several possibilities of nucleation point for both cases has been considered, and it is seen that variation of peak ground acceleration at Port Blair station for strike-slip and thrust mechanism is 126?C738 gals and 647?C2,571 gals, respectively, which indicate high seismic hazard potential of Andaman Island.     

Modeling of strong motion generation area of the Uttarkashi earthquake using modified semiempirical approach

The semiempirical approach based on envelope summation method given by Midorikawa (Tectonophysics 218:287–295, 1993) has been modified in this paper for modeling of strong motion generation areas (SMGAs). Horizontal components of strong ground motion have been simulated using modifications in the semiempirical approach given by Joshi et al. (Nat Hazard 71:587–609, 2014). Various modifications in the technique account for finite rupture source, layering of earth, componentwise division of energy and frequency-dependent radiation pattern. In this paper, SMGAs of the Uttarkashi earthquake have been modeled. Two different isolated wave packets in the recorded accelerogram have been identified from recorded ground motion, which accounts for two different SMGAs in the entire rupture plane. The approximate locations of SMGAs within the rupture plane were estimated using spatio-temporal variation of 77 aftershocks. Source parameters of each SMGA were calculated from theoretical and observed source displacement spectra computed from two different wave packets in the record. The final model of rupture plane responsible for the Uttarkashi earthquake consists of two SMGAs, and the same has been used to simulate horizontal components of acceleration records at different station using modified semiempirical technique. Comparison of the observed and simulated acceleration records in terms of root mean square error confirms the suitability of the final source model for the Uttarkashi earthquake.     

Stability regions of equilibrium points in restricted four-body problem with oblateness effects

In this paper, we extend the basic model of the restricted four-body problem introducing two bigger dominant primaries m ₁ and m ₂ as oblate spheroids when masses of the two primary bodies (m ₂ and m ₃) are equal. The aim of this study is to investigate the use of zero velocity surfaces and the Poincaré surfaces of section to determine the possible allowed boundary regions and the stability orbit of the equilibrium points. According to different values of Jacobi constant C, we can determine boundary region where the particle can move in possible permitted zones. The stability regions of the equilibrium points expanded due to presence of oblateness coefficient and various values of C, whereas for certain range of t (100≤t≤200), orbits form a shape of cote’s spiral. For different values of oblateness parameters A ₁ (0<A ₁<1) and A ₂ (0<A ₂<1), we obtain two collinear and six non-collinear equilibrium points. The non-collinear equilibrium points are stable when the mass parameter μ lies in the interval (0.0190637,0.647603). However, basins of attraction are constructed with the help of Newton Raphson method to demonstrate the convergence as well as divergence region of the equilibrium points. The nature of basins of attraction of the equilibrium points are less effected in presence and absence of oblateness coefficients A ₁ and A ₂ respectively in the proposed model.     

Sensitivity of the GCM driven summer monsoon simulations to cumulus parameterization schemes in nested RegCM3

The regional climate model (RegCM3) from the Abdus Salam International Centre for Theoretical Physics has been used to simulate the Indian summer monsoon for three different monsoon seasons such as deficit (1987), excess (1988) and normal (1989). Sensitivity to various cumulus parameterization and closure schemes of RegCM3 driven by the National Centre for Medium Range Weather Forecasting global spectral model products has been tested. The model integration of the nested RegCM3 is conducted using 90 and 30-km horizontal resolutions for outer and inner domains, respectively. The India Meteorological Department gridded rainfall (1° × 1°) and National Centre for Environment Prediction (NCEP)–Department of Energy (DOE) reanalysis-2 of 2.5° × 2.5° horizontal resolution data has been used for verification. The RegCM3 forced by NCEP–DOE reanalysis-2 data simulates monsoon seasons of 1987 and 1988 reasonably well, but the monsoon season of 1989 is not represented well in the model simulations. The RegCM3 runs driven by the global model are able to bring out seasonal mean rainfall and circulations well with the use of the Grell and Anthes–Kuo cumulus scheme at 90-km resolution. While the rainfall intensity and distribution is brought out well with the Anthes–Kuo scheme, upper air circulation features are brought out better by the Grell scheme. The simulated rainfall distribution is better with RegCM3 using the MIT-Emanuel cumulus scheme for 30-km resolution. Several statistical analyses, such as correlation coefficient, root mean square error, equitable threat score, confirm that the performance of MIT-Emanuel scheme at 30-km resolution is better in simulating all-India summer monsoon rainfall. The RegCM3 simulated rainfall amount is more and closer to observations than that from the global model. The RegCM3 has corrected its driven GCM in terms of rainfall distribution and magnitude over some parts of India during extreme years. This study brings out several weaknesses of the RegCM model which are documented in this paper.     

The role of amphiboles in the metamorphic evolution of the UHP rocks: a case study from the Tso Morari Complex, northwest Himalayas

Amphiboles represent a crucial phase of the ultra-high-pressure (UHP) metamorphic rocks as their solid solution behavior reflects both bulk compositional and P–T changes. Three different types of amphibole have been reported from the UHP metamafic rocks of the Tso Morari Crystalline Complex, NW Himalayas: Na-rich (glaucophane); Na–Ca-rich (barroisite, taramite, winchite) and Ca-rich (tremolite, magnesio-hornblende, pargasite). The Na-amphibole is presented as a core of the zoned amphibole with Na–Ca-rich rim; Na–Ca-amphibole is presented as inclusion in garnets as well as in matrix, and Ca-amphibole is generally found in the matrix. The Na–Ca-amphibole is observed at two different stages of metamorphism. The first is pre-UHP, and the second is post-garnet–omphacite assemblage though with a significant difference in composition. The pressure–temperature estimations of the formation of these two sets of Na–Ca-amphiboles corroborate their textural associations. Ca-rich amphiboles are generally present in the matrix either as symplectite with plagioclase or as a pseudomorph after garnet along with other secondary minerals like chlorite and biotite. Two different types of zoning have been observed in the amphibole grains: (1) core is Na-rich followed by Na–Ca rim and (2) core of Na–Ca-amphibole is followed by Ca-rich rim. The pre-UHP (or the prograde P–T path) and post-UHP stages (or the retrograde P–T path) of Tso Morari eclogites are defined by characteristic amphibole compositions, viz. Na/Na–Ca-amphibole, Na–Ca-amphibole and Ca-amphibole and thus indicate their utility in inferring crustal evolution of this UHP terrain.     

Equilibrium points and zero velocity surfaces in the restricted four-body problem with solar wind drag

We have analyzed the motion of an infinitesimal mass in the restricted four-body problem with solar wind drag. It is assumed that the forces which govern the motion are mutual gravitational attractions of the primaries, radiation pressure force and solar wind drag. We have derived the equations of motion and found the Jacobi integral, zero velocity surfaces, and particular solutions of the system. It is found that three collinear points are real when the radiation factor 0<β<0.1 whereas only one real point is obtained when 0.125<β<0.2. The stability property of the system is examined with the help of Poincaré surface of section (PSS) and Lyapunov characteristic exponents (LCEs). It is found that in presence of drag forces LCE is negative for a specific initial condition, hence the corresponding trajectory is regular whereas regular islands in the PSS are expanded.     

Kaluza-Klein radiating model in a general scalar-tensor theory

A five dimensional Kaluza-Klein space-time is considered in the presence of prefect fluid source in the general scalar-tensor theory of gravitation proposed by Nordtvedt (Astrophys. J. 161:1069, 1970) with the help of special law of variation for Hubble’s parameter given by Bermann (Nuovo Cimento 74B:182, 1983). A cosmological model with a negative constant deceleration parameter is obtained in this theory. Some physical properties of the model are also discussed.