Scattering attenuation and the fractal geometry of fracture systems

Scattering of seismic waves can be shown to have a frequency dependenceQ ^{–1 3–v} if scattering is produced by arrays of inhomogeneities with a 3D power spectrumW _3D(k) k ^–v. In the earth's crust and upper mantle the total attenuation is often dominated by scattering rather than intrinsic absorption, and is found to be frequency dependent according toQ ^–1 , where –1<–0.5. IfD ₁ is the fractal dimension of the surface of the 3D inhomogeneities measured on a 2D section, then this corresponds respectively to 1.5<D ₁1.75, since it can be shown that =2(D ₁–2). Laboratory results show that such a distribution of inhomogeneities, if due to microcracking, can be produced only at low stress intensities and slow crack velocities controlled by stress corrosion reactions. Thus it is likely that the earth's brittle crust is pervaded by tensile microcracks, at least partially filled by a chemically active fluid, and preferentially aligned parallel to the maximum principal compressive stress. The possibility of stress corrosion implies that microcracks may grow under conditions which are very sensitive to pre-existing heterogeneities in material constants, and hence it may be difficult in practice to separate the relative contribution of crack-induced heterogeneity from more permanent geological heterogeneities.By constrast, shear faults formed by dynamic rupture at critical stress intensities produceD ₁=1, consistent with a dynamic rupture criterion for a power law distribution of fault lengths with negative exponentD. The results presented here suggest empirically thatD ₁-1/2(D+1), thereby providing the basis for a possible framework to unify the interpretation of temporal variations in seismicb-value (b-D/2) and the frequency dependence of scattering attenuation ().This is PRIS contribution 046.     

Surface complexation of Cu on birnessite (δ-MnO2): Controls on Cu in the deep ocean

Hexagonal birnessite (δ-MnO₂) is a close analogue to the dominant phase in hydrogenetic marine ferromanganese crusts and nodules. These deposits contain ∼0.25 wt.% Cu which is believed to be scavenged from the overlying water column where Cu concentrations are near 0.1 μg/L. Here, we measured the sorption of Cu on δ-MnO₂ as a function of pH and surface loading. We characterized the nature of the Cu sorption complex at pH 4 and 8 using EXAFS spectroscopy and find that, at pH 4, Cu sorbs to birnessite by inner-sphere complexation on the {0 0 1} surface at sites above Mn vacancies to give a three to fourfold coordinated complex with 6 Mn neighbors at ∼3.4 Å. At pH 8, however, we find that some Cu has become structurally incorporated into the MnO₂ layer by occupying the vacancy sites to give 6 Mn neighbors at ∼2.91 Å. Density functional calculations on and clusters predict a threefold coordinated surface complex and show that the change from surface complexation to structural incorporation is a response to protonation of oxygens surrounding the vacancy site. Consequently, we propose that the transformation between sorption via surface complex and vacancy site occupancy should be reversible. By fitting the Cu sorption as a function of surface loading and pH to the formation of the observed and predicted surface complex, we developed a surface complexation model (in the basic Stern approximation) for the sorption of Cu onto birnessite. Using this model, we demonstrate that the concentration of inorganic Cu in the deep ocean should be several orders of magnitude lower than the observed total dissolved Cu. We propose that the observed total dissolved Cu concentration in the oceans reflects solubilization of Cu by microbially generated ligands.     

Long-term biological effects of petroleum residues on fiddler crabs in salt marshes

In September 1969, the Florida barge spilled 700,000L of No. 2 fuel oil into the salt marsh sediments of Wild Harbor (Buzzards Bay, MA). Today the aboveground environment appears unaffected, but a substantial amount of moderately degraded petroleum still remains 8-20cm below the surface. The salt marsh fiddler crabs, Uca pugnax, burrow into the sediments at depths of 5-25cm, and are chronically exposed to the spilled oil. Behavioral studies conducted with U. pugnax from Wild Harbor and a control site, Great Sippewissett marsh, found that crabs exposed to the oil avoided burrowing into oiled layers, suffered delayed escape responses, lowered feeding rates, and achieved lower densities. The oil residues are therefore biologically active and affect U. pugnax populations. Our results add new knowledge about long-term consequences of spilled oil, a dimension that should be included when assessing oil-impacted areas and developing management plans designed to restore, rehabilitate, or replace impacted areas.     

Possible evidence for on-going volcanism on Mars as suggested by thin, elliptical sheets of low-albedo particulate material around pits and fissures close to Cerberus Fossae

High quality CCD images obtained at two different observatories in North Italy allowed the identification of four morphological structures near the nuclear region of the comet Ikeya-Zhang (I-Z): haloes, jets, shells and spirals. The interpretation of the nature of these structures has been attempted by means of a comparison of different up-to-date image processing techniques, which led to a single common estimate of the rotation period (p=1.48±0.20 days).     

Satellites that see the Earth move

Sheila Peacock summarizes the British Geophysical Association's annual Advances in Geophysics meeting, which took place on 10 and 11 February 2005, on the theme of "The Impact of Satellite Measurements on the Observation and Modelling of Continental Deformation".