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Boron isotopic composition of subduction-zone metamorphic rocks   总被引:1,自引:0,他引:1  
Many arc lavas contain material derived from subducted oceanic crust and sediments, but it remains unresolved whether this distinctive geochemical signature is transferred from the subducting slab by aqueous fluids, silicate melts, or both. Boron isotopic measurements have the potential to distinguish between slab transfer mechanisms because 11B fractionates preferentially into aqueous fluids whereas little fractionation may occur during partial melting. Previous studies have shown that δ11B values of island arc lavas (−6 to +7) overlap the range of δ11B values for altered oceanic crust (−5 to +25) and pelagic sediments and turbidites (−7 to +11). Secondary ion mass spectrometry (SIMS) analyses of minerals in subduction-zone metamorphic rocks yield δ11B=−11 to −3 suggesting that slab dehydration reactions significantly lower the δ11B values of subducted oceanic crust and sediments. In order to explain the higher δ11B values reported for arc lavas as compared to subduction-zone metamorphic rocks, the B-bearing component derived from the metamorphosed slab must be enriched in 11B relative to the slab, favoring an aqueous fluid as the slab transfer mechanism.  相似文献   
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To understand the spatial variation in concentrations and compositions of organic micropollutants in marine plastic debris and their sources, we analyzed plastic fragments (∼10 mm) from the open ocean and from remote and urban beaches. Polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), dichloro-diphenyl-trichloroethane and its metabolites (DDTs), polybrominated diphenyl ethers (PBDEs), alkylphenols and bisphenol A were detected in the fragments at concentrations from 1 to 10,000 ng/g. Concentrations showed large piece-to-piece variability. Hydrophobic organic compounds such as PCBs and PAHs were sorbed from seawater to the plastic fragments. PCBs are most probably derived from legacy pollution. PAHs showed a petrogenic signature, suggesting the sorption of PAHs from oil slicks. Nonylphenol, bisphenol A, and PBDEs came mainly from additives and were detected at high concentrations in some fragments both from remote and urban beaches and the open ocean.  相似文献   
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We use very large cosmological N -body simulations to obtain accurate predictions for the two-point correlations and power spectra of mass-limited samples of galaxy clusters. We consider two currently popular cold dark matter (CDM) cosmogonies, a critical density model ( τ CDM) and a flat low density model with a cosmological constant (ΛCDM). Our simulations each use 109 particles to follow the mass distribution within cubes of side 2  h −1 Gpc ( τ CDM) and 3  h −1 Gpc (ΛCDM) with a force resolution better than 10−4 of the cube side. We investigate how the predicted cluster correlations increase for samples of increasing mass and decreasing abundance. Very similar behaviour is found in the two cases. The correlation length increases from     for samples with mean separation     to     for samples with     The lower value here corresponds to τ CDM and the upper to ΛCDM. The power spectra of these cluster samples are accurately parallel to those of the mass over more than a decade in scale. Both correlation lengths and power spectrum biases can be predicted to better than 10 per cent using the simple model of Sheth, Mo & Tormen. This prediction requires only the linear mass power spectrum and has no adjustable parameters. We compare our predictions with published results for the automated plate measurement (APM) cluster sample. The observed variation of correlation length with richness agrees well with the models, particularly for ΛCDM. The observed power spectrum (for a cluster sample of mean separation     ) lies significantly above the predictions of both models.  相似文献   
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The results are presented of an extensive programme of optical and infrared imaging of radio sources in a complete subsample of the Leiden–Berkeley Deep Survey. The LBDS Hercules sample consists of 72 sources observed at 1.4 GHz, with flux densities S 1.41.0 mJy, in a 1.2 deg2 region of Hercules. This sample is almost completely identified in the g , r , i and K bands, with some additional data available at J and H . The magnitude distributions peak at r ≃22 mag, K ≃16 mag and extend down to r ≃26 mag, K ≃21 mag. The K -band magnitude distributions for the radio galaxies and quasars are compared with those of other radio surveys. At S 1.4 GHz≲1 Jy, the K -band distribution does not change significantly with radio flux density. The sources span a broad range of colours, with several being extremely red ( r − K ≳6). Though small, this is the most optically complete sample of mJy radio sources available at 1.4 GHz, and is ideally suited for studying the evolution of the radio luminosity function out to high redshifts.  相似文献   
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Three field examples are presented which show changes in fault patterns at different scales. Normal faults in Jurassic limestones in Somerset consist of zones of sub-parallel segments at the exposure-scale, but contain complex zones of brecciation at the decimetre-scale. Normal faults in chalk at Flamborough Head consist of a complex network of small faults which accommodate strain between a set of large faults. The different-sized faults at Flamborough Head have different geometries and histories, with the larger faults showing a phase of reverse reactivation. The faulting in the Sydney Basin, Australia, can be explained in terms of the evolution and reactivation of transfer zones between overstepping faults. These transfer zones can cause the deformation to appear to be more complex as the analysis becomes more detailed.
Much recent work on the scaling relationslups of faults assumes that self-similar fault patterns occur over a wide range of scales. The data presented in this paper, however, suggest that there are problems in using the deformation pattern at one scale to infer deformation at other scales. Ideally, any analysis should involve the study of a wide range of scales to overcome these problems.  相似文献   
29.
Petroleum hydrocarbons persist in salt marsh sediments in Winsor Cove (Buzzards Bay, Massachusetts) impacted from the 1974 spill of No. 2 fuel oil by the barge Bouchard 65. Intertidal sediment cores were collected from 2001 to 2005 and analyzed for total petroleum hydrocarbons (TPHs). TPHs content was greatest (as high as 8.7 mg g(-1) dry weight) in the surface sediments and decreased with distance landward. Select samples were analyzed for polycyclic aromatic hydrocarbons (PAHs) with values as high as 16.7 microg g(-1) for total naphthalenes and phenanthrenes/anthracenes. These remaining PAHs are mainly C(4)-naphthalenes and C(1)-, C(2)-, and C(3)-phenanthrenes/anthracenes revealing preferential loss of almost all of the naphthalenes and the parent compound phenanthrene. Inspection of the data indicates that biodegradation, water-washing and evaporation were major removal processes for many of the petroleum hydrocarbons in the marsh sediments. In addition, historical data and photographs combined with their recent counterparts indicate that erosion has physically removed these contaminants from this site.  相似文献   
30.
Sheila Peacock reports on the conference held on 15 September 2000 at the University of Birmingham, that united speakers tackling technological, scientific and social problems.  相似文献   
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