盆地岩石圈结构与油气成藏及分布

本文综述了大陆岩石圈研究现状和克拉通盆地、裂谷盆地和前陆盆地的岩石圈结构特征,指出在古裂谷、褶皱带或区域性深断裂等陆壳构造薄弱带上发育起来的多期叠合盆地,具有很好的含油气前景。大型含油气盆地往往存在地幔上隆、地壳减薄和地壳内低速层,盆地基底沉降与盖层沉积厚度较大。适度的后期构造活动改造和岩浆活动有利于沉积盆地内油气生成与保存。     

Initiation of Subduction Zones as a Consequence of Lateral Compositional Buoyancy Contrast within the Lithosphere: a Petrological Perspective

Tonga and Mariana fore-arc peridotites, inferred to representtheir respective sub-arc mantle lithospheres, are compositionallyhighly depleted (low Fe/Mg) and thus physically buoyant relativeto abyssal peridotites representing normal oceanic lithosphere(high Fe/Mg) formed at ocean ridges. The observation that thedepletion of these fore-arc lithospheres is unrelated to, andpre-dates, the inception of present-day western Pacific subductionzones demonstrates the pre-existence of compositional buoyancycontrast at the sites of these subduction zones. These observationsallow us to suggest that lateral compositional buoyancy contrastwithin the oceanic lithosphere creates the favoured and necessarycondition for subduction initiation. Edges of buoyant oceanicplateaux, for example, mark a compositional buoyancy contrastwithin the oceanic lithosphere. These edges under deviatoriccompression (e.g. ridge push) could develop reverse faults withcombined forces in excess of the oceanic lithosphere strength,allowing the dense normal oceanic lithosphere to sink into theasthenosphere beneath the buoyant overriding oceanic plateaux,i.e. the initiation of subduction zones. We term this conceptthe ‘oceanic plateau model’. This model explainsmany other observations and offers testable hypotheses on importantgeodynamic problems on a global scale. These include (1) theorigin of the 43 Ma bend along the Hawaii–Emperor SeamountChain in the Pacific, (2) mechanisms of ophiolite emplacement,(3) continental accretion, etc. Subduction initiation is notunique to oceanic plateaux, but the plateau model well illustratesthe importance of the compositional buoyancy contrast withinthe lithosphere for subduction initiation. Most portions ofpassive continental margins, such as in the Atlantic where largecompositional buoyancy contrast exists, are the loci of futuresubduction zones. KEY WORDS: subduction initiation; compositional buoyancy contrast; oceanic lithosphere; plate tectonics; mantle plumes; hotspots; oceanic plateaux; passive continental margins; continental accretion; mantle peridotites; ophiolites     

Evidence for fullerenes in solid bitumen from pillow lavas of Proterozoic age from Mítov (Bohemian Massif, Czech Republic)

Andesitic pillow lavas containing biogenic, solid bitumen (SB) are a constituent of a Neoproterozoic volcanosedimentary sequence (Teplá-Barrandian unit, Bohemian Massif) in the Mítov area of the Czech Republic. A black shale formation that is crosscut by these andesitic basalts is 565 Ma old. Carbon disulfide extracts of two powdered samples of SB contain 0.2 and 0.3 ppm of C₆₀, respectively, as determined by high-pressure liquid chromatography. The peak assignment based on retention time is fully supported by high-resolution electron ionization mass spectrometry (EI-MS). No C₇₀ was detected, nor was C₆₀ found in two other SB samples from this locality. Other investigated carbonaceous samples from Bohemia (coals and anthracites of Upper Paleozoic age and anthraxolite, graphitoids, and graphite of Upper Proterozoic age) did not contain fullerenes at concentrations above the detection limit of 0.01 ppm. The absence of C₆₀ in these samples was confirmed by EI-MS. The proposed mechanism of fullerene formation involves a primary algal phase, generation of a hydrocarbonaceous mixture in the course of thermal evolution of the sedimentary series, and their high-temperature transformation related to the extrusion of basalt. An important feature for fullerene conservation was the enclosure of fullerenes in SB with a structure similar to glasslike carbon, where the fullerene was protected against oxidation.     

渤海海域辽东南洼斜坡带旅大29油田原油地球化学特征与油源对比

辽东凹陷南洼斜坡带旅大29油田在沙河街组二段获得了高产轻质原油和天然气，展现了良好的勘探潜力。为了进一 步明确其原油母质来源、沉积环境和烃源岩层位，对原油、油砂样品和围区烃源岩样品进行了系统的地球化学分析和油源 对比。研究结果表明，原油为低硫（0.0733%）、高蜡（20.77%） 的轻质成熟原油。原油样品饱和烃色谱完整，主峰碳为 C19，显示未遭受明显生物降解作用。油砂样品埋藏较浅，部分遭受生物降解等的影响，饱和烃色谱基线呈现明显的 “UCM”鼓包现象。原油和油砂样品具有低C19 三环萜烷/C23 三环萜烷（0.10~0.18）、低C24 四环萜烷/C26 三环萜烷（0.49~ 0.53）、低C27重排甾烷/C27甾烷（0.30~0.43）、中等伽马蜡烷指数（0.14~0.17） 和中等-高4-甲基甾烷参数（0.30~0.36），且 具有相对较重的全油碳同位素值（-27.1‰）。原油母质形成于淡水—微咸水的湖泊沉积环境，母源有机质以藻类等低等水 生生物为主，陆源有机质输入较少。旅大29油田原油主要来源于辽中凹陷和辽东凹陷沙三段烃源岩，同时有少量辽中凹陷 沙四段烃源岩的贡献。研究区高蜡轻质原油的形成主要受控于烃源岩母质来源，藻类等低等水生生物是高蜡轻质原油形成 的重要母质。     

Simulation of normal distributed smooth fields by Karhunen-Loéve expansion in combination with kriging

Simulation of multigaussian stochastic fields can be made after a Karhunen-Loéve expansion of a given covariance function. This method is also called simulation by Empirical Orthogonal Functions. The simulations are made by drawing stochastic coefficients from a random generator. These numbers are multiplied with eigenfunctions and eigenvalues derived from the predefined covariance model. The number of eigenfunctions necessary to reproduce the stochastic process within a predefined variance error, turns out to be a cardinal question. Some ordinary analytical covariance functions are used to evaluate how quickly the series of eigenfunctions can be truncated. This analysis demonstrates extremely quick convergence to 99.5% of total variance for the 2nd order exponential (‘gaussian’) covariance function, while the opposite is true for the 1st order exponential covariance function. Due to these convergence characteristics, the Karhunen-Loéve method is most suitable for simulating smooth fields with ‘gaussian’ shaped covariance functions. Practical applications of Karhunen-Loéve simulations can be improved by spatial interpolation of the eigenfunctions. In this paper, we suggest interpolation by kriging and limits for reproduction of the predefined covariance functions are evaluated.     

新疆北部晚古生代埃达克岩、富铌玄武岩组合：古亚洲洋板块南向俯冲的证据

地球化学研究结果表明，新疆北部富蕴县境内的晚古生代下泥盆统托让格库都克组的安山质岩石具有与埃达克岩非常相似的地球化学特征，它们具有较高的Al2O3，Na2O和Sr含量以及Sr/Y比值；明显亏损重稀土和Y，它们的MORB标准化微量元素蛛网图表现为明显的Nb，Ta负异常和Sr正异常，同时强烈亏损高场强元素。与埃达克岩共生的玄武岩的地球化学特征则与富铌玄武岩一致，表现为Si过饱和及富Na的特征，同时具有较高的Nb，TiO2和P2O5含量，并富集高场强元素。由于埃达克岩和富铌玄武岩的形成均与板块俯冲有关，因此，它们的存在表明，古亚洲洋在早-中泥盆世向南(哈萨克斯坦-准噶尔板块)发生了一次洋壳俯冲作用。     

长江源雀莫错-带上二叠统那益雄组火山岩特征及其构造环境

雀莫错一带那益雄组火山岩是由玄武岩组成的基性熔岩,岩石化学表现为低TiO2(<1％)和Al2O3,Na2O>K2O,属钙碱性系列。地球化学特征表现为轻稀土富集,Eu平坦或轻微负异常,富集大离子亲石元素(Rb,Sr,Ba,K)和高强场元素Th,亏损高强场元素Nb和Ta,反映了岛弧构造环境。上二叠统那益雄组岛弧型火山岩的发现,说明长江源地区晚古生代有岛弧存在,且该岛弧应为晚古生代特提斯洋向东俯冲在中北段形成的多岛-弧盆系统的一部分。     

云南省白竹箐-阳文山NE向构造带铅锌矿成矿地质条件及找矿方向

重点分析构造带的成矿地质条件，总结地层、构造、岩浆岩与矿床的关系，认为该地区具有寻找层控及热液改造型铅锌矿的远景，并指明找矿方向，根据化探异常及矿点分布的规律，圈定了找矿靶区。