Determination of the complex refractive indices of Titan haze analogs using photothermal deflection spectroscopy

The spectrometers of the Cassini mission to the Saturn system have detected haze layers reaching up to 800 km in Titan’s atmosphere. Knowledge of the complex refractive index (k) of the haze is important for modeling the surface and atmosphere of Titan and retrieving some information about the functional groups present in the aerosols. Plasma discharges or ultraviolet radiation are commonly used to drive the formation of solid organics assumed to be good analogs of the Titan aerosols. [Tran, B.N., Ferris, J.P., Chera, J.J., 2003a. The photochemical formation of a Titan haze analog. Structural analysis by X-ray photoelectron and infrared spectroscopy. Icarus 162, 114-124; Tran, B.N., Force, M., Briggs, R., Ferris J.P., Persans, P., Chera, J.J., 2008. Photochemical processes on Titan: Irradiation of mixtures of gases that simulate Titan’s atmosphere. Icarus 177, 106-115] reported the index of refraction of analogs synthesized by far ultraviolet irradiation of various gas mixtures. k was determined in the 200-800 nm wavelength range from transmission and reflection spectroscopy. However, this technique is limited by (i) uncertainties in the absorption values because of the small amounts of organics available, (ii) light scattering by the surface roughness and particulates in the sample. These limitations prompted us to perform new measurements using photothermal deflection spectroscopy (PDS), a technique based on the conversion of absorbed light into heat in the material of interest. By combining traditional spectroscopy (λ < 500 nm) and PDS (λ > 500 nm), we determined values of k over the 375-1550 nm range. k values as low as 10⁻⁴ above 1000 nm were determined. This is one order of magnitude lower than the measurements generally used as a reference for Titan’s aerosols analogs [Khare, B.N., Sagan, C., Arakawa, E.T., Suits, F., Callicott, T.A., Williams, M.W., 1984. Optical-constants of organic Tholins produced in a simulated Titanian atmosphere—from soft-X-ray to microwave-frequencies. Icarus 60(1), 127-137]. We recommend that these results were used in models to describe the optical properties of the aerosols produced in Titan’s stratosphere.     

Use of comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry for the characterization of biodegradation and unresolved complex mixtures in petroleum

A comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry (GC × GC/TOFMS) method has been developed for separation of a series of petroleum samples using a polar/non-polar column set configuration. Groups of oils were selected to provide samples from the same oil family to assist in comparison of compositional changes during biodegradation. The groups also represented different sources and ages to allow an assessment of the application of GC × GC for the differentiation of oil source, as well as fluid history. The increased resolution and separation afforded by the GC × GC technique provides more complete compositional information on complex biodegraded oil samples than one-dimensional GC, and improves the ability to study biodegradation trends. Among the components identified, it is proposed that alkyl-decahydronaphthalenes constitute a significant contribution to the UCM.     

Stanniferrous granites of Vietnam: Rb-Sr and Ar-Ar isotope age,composition, sources,and geodynamic formation conditions

Doklady Earth Sciences - Stanniferrous granite-leucogranite massifs in Vietnam to which the bedrock and placer commercial deposits of cassiterite are associated (Timtuc etc.) are of late Cretaceous...     

Onset of the summer monsoon over the southern Vietnam and its predictability

The summer monsoon onset over southern Vietnam is determined through a new criterion based on both in situ daily rainfall at six selected stations provided by the Institute of Meteorology and Hydrology, Vietnam, and the zonal component of the wind at 1,000 hPa from the National Center for Environmental Prediction/Department of Energy Reanalysis 2. Over the period 1979–2004, the summer monsoon onset mean date is on 12 May, with a standard deviation of 11.6 days. The temporal and spatial structures of the atmospheric conditions prevailing during the onset period are detailed. Clear changes are seen in the zonal wind (strengthened over the Bay of Bengal and changed from negative to positive over South Vietnam) and in convection (deeper), in association with an intensification of the meridional gradients of sea level pressure at 1,000 hPa and of moist static energy at 2 m over Southeast Asia. The predictability of onset dates is then assessed. Cross-validated hindcasts based upon four predictors linked to robust signals in the atmospheric dynamics are then provided. They are highly significant when compared to observations (56% of common variance). Basically, late (early) onsets are preceded in March–April by higher (lower) sea level pressure over the East China Sea, stronger (weaker) southeasterly winds over southern Vietnam, decreasing (increasing) deep convection over the Bay of Bengal, and the reverse situation over Indonesia (120–140°E, 0–10°S).     

Defining a Sea Ice Flag for Envisat Altimetry Mission

This letter presents the development of a sea ice flag algorithm for the Envisat altimetry mission to detect sea ice corrupted sea surface height data within quality control processing. The algorithm takes advantage of having both passive and active microwave sensors on the same platform with coregistered measurements. Its performances have been evaluated based on collocations between the along-track Envisat data with reference maps built from combination of daily grids of sea ice concentration from SSM/I sensors and backscatter cross section from SeaWinds scatterometer on QuikSCAT satellite.     

Experimental and numerical behaviour of reinforced mortar plates subjected to accelerated corrosion

Most reinforced concrete structures are damaged due to corrosion of reinforcements in concrete. In normal conditions the pH near the reinforcements is around 12–13 which means that steel is in a passive state. But aggressive species, such as chloride ions or carbon dioxide, may penetrate into concrete and promote active corrosion. As a consequence (hydro)oxides are produced leading to degradation of concrete structures. For instance cracking of the concrete is generated due to the pressure induced by rust. In this paper, we study the inception and the propagation of cracking on reinforced mortar plates with rebars located either in the middle or at the corner. Additional experiments have been performed on cylindrical specimens to determine the local effect of rust pressure at the interface rust/mortar. The specimens have been subjected to imposed current density in order to enhance the corrosion and digital image intercorrelation has been used to determine displacement fields. The experiments have been compared to numerical modelling. Copyright © 2010 John Wiley & Sons, Ltd.     

Assessing optical earth observation systems for mapping and monitoring temporary ponds in arid areas

Remote sensing methods for locating and monitoring temporary ponds over large areas in arid lands were tested on a study site in Northern Senegal. Three main results are presented, validated with field data and intended to highlight different spectral, spatial and temporal characteristics of the methods: (1) Among several water indices tested, two Middle Infrared-based indices (MNDWI—Modified Normalized Difference Water Index and NDWI₁—Normalized Difference Water Index) are found to be most efficient; (2) an objective method is given prescribing the necessary sensor spatial resolution in terms of minimal detected pond area; and (3) the potential of multi-temporal MODIS imagery for tracking the filling phases of small ponds is illustrated. These results should assist in epidemiological studies of vector-borne diseases that develop around these ponds, but also more generally for land and water management and preservation of threatened ecosystems in arid areas.     

ISO Spectroscopy of Ultraluminous Infrared Galaxies

Spectroscopy from the Infrared Space Observatory ISO has for the first timeprovided the sensitivity to exploit the diagnostic power ofmid-infrared fine structure lines and PAH features for the study ofultraluminous infrared galaxies (L_IR >10¹² L ). We report on observations obtainedwith SWS, ISOPHOT-S, and the CVF option of ISOCAM. From both fine structure lines and PAH features, we find that the majority of ULIRGs is predominantlypowered by star formation. Our total sample of about 75 ULIRGs allows tosearch for trends within the class of ULIRGs: The fraction of AGNs increaseswith luminosity above 3 × 10¹²L but there is no obvioustrend for ULIRGs to be more AGN-like with more advanced merger phase.     

The subsurface transport of heat and moisture and its effect on the environment: A numerical model

A numerical model was developed to study the transport of heat and vapor under the surface of bare soil and soil covered by some materials such as asphalt and concrete under no rainfall conditions. The computational results provide a good match with the experimental data. The results show that the transport of water vapor inside the soil has an important effect on the subsurface distribution of temperature, especially for bare soil. Because of evaporation, the temperature of bare soil is much lower than that under covered surfaces throughout the day and the temperature of the surface covered by asphalt is extremely high-higher than the atmospheric temperature even at night. An increase of thickness of the covering material further increases the temperature and heat stored under surfaces. The stored heat is released to the atmosphere at night, contributing to environmental effects such as the urban heat island.     

Nitrogen and xenon in acid residues of iron meteorites

Total nitrogen, measured by neutron activation analysis, is highly enriched in residues from iron meteorites obtained by dissolution of the metal in dilute H₂SO₄, relative to the bulk value. On the average, the residues, representing 3% mass, contain 22% of total N. Group IA has more dissolved N than IIIA. Lithium and Ir show a distribution pattern parallel to N. Total Xe has been measured in several residues and its isotopic composition is, similar to atmospheric Xe for mass numbers 131 to 136 but not for ¹²⁴Xe and ¹²⁶Xe which are strongly depleted in the non-magnetic residues. It is suggested that iron meteorites have trapped in their micro-inclusions, some pre-solar nebular matter which is isotopically heterogeneous.