The activities of potassium chloride and of water in Dead Sea brine

The activities of KCl and of H₂O in Dead Sea water were estimated according to several approaches dealing with multicomponent electrolyte solutions. The activity of H₂O, both measured directly via its vapor pressure and calculated theoretically, is 0.754 ± 0.004 for brine of density 1.207 ± 0.003gcm^?3 at 25°C. The mean ionic activity of KCl in this brine ranges from 0.876 to 1.199 according to various treatments. These correspond to binary aqueous solutions 8.6–12.1 times richer than the brine. The brine cannot be simultaneously in equilibrium with respect to both H₂O and KCl with such binary solutions, so a hypothetically perfect semipermeable membrane cannot lead to a state of equilibrium between the brine and aqueous KCl of any concentration.     

Provenance of deep-water reservoir sandstones from the Jubarte oil field,Campos Basin,Eastern Brazilian Margin

The provenance of the Maastrichtian deep-water reservoir sandstones from the Jubarte oil field (Campos Basin, eastern Brazil), was studied using an integrated approach that included quantitative petrography, conventional heavy mineral analysis, garnet mineral chemistry and zircon geochronology. The reservoirs are predominantly coarse, poorly-sorted sandstones with feldspathic composition derived from uplifted basement terrains. The fourth- and fifth-order depositional sequences analyzed show no major variations in composition or in provenance through time. However, variations in apatite:tourmaline presents potential to be used as a parameter for sandstone correlation within the field. The composition of heavy minerals indicates derivation from high temperature and low-to-medium pressure aluminous metapelitic rocks, from granites and subordinate mafic rocks, derived from the Cabo Frio Tectonic Domain and the Oriental terrain of Ribeira orogen, characterizing a supply route from SW to NE. The low ZTR index, as well as the absence of low-grade stable heavy minerals and of metasedimentary rock fragments, suggest that by the end of Cretaceous all supracrustal, low-grade terrains had already been totally eroded, and that plutonic, infracrustal rocks were exposed, similarly to the present situation.     

Spreading of Antarctic Bottom Water and its effects on the floor of the Indian Ocean inferred from bottom-water potential temperature,turbidity, and sea-floor photography

Data on bottom-water potential temperature, turbidity and current indications show that in the Southern Ocean west of the Kerguelen Plateau, Antarctic Bottom Water (AABW) of Weddell Sea origin spreads northwards from the Atlantic—Indian Basin in two directions: (1) AABW enters the Agulhas Basin through relatively deep areas in the Mid-Indian Ridge at 20–25°E and possibly at 35°E, and flows northwards into the Mozambique Basin as far as its northern limits; (2) a more easterly spreading path extends from the Atlantic—Indian Basin through the Crozet into the Madagascar, Mascarene, Somali and Arabian Basins. The passage in the western branch of the Indian Ridge for the AABW spreading from the Crozet into the Madagascar Basin appears to be at 29-26°S and 60–64°E.East of the Kerguelen Plateau in the South Indian Basin, the bottom water formed mainly along the Adélie Coast and Ross Sea travels west towards the Kerguelen Plateau and then parallel to it. This water finally flows eastwards hugging the Southeast Indian Ridge. Significant deviations from this general circulation pattern occur due to local topographic effects. Some AABW in the South Indian Basin exits through a passage at 120–125°E in the region of the Australian—Antarctic discordance in the Southeast Indian Ridge and enters the South Australian Basin and subsequently the Wharton Basin. This passage is clearly indicated by the northward extension of a cold, bottom-water tongue as shown by the temperature distribution in the region; the bottom-water effects in the passage are reflected in the high turbidity and current lineations on the sea floor.In the Southern Ocean basins, bottom-water turbidity is generally high, reflecting in part the strong bottom-water activity. The effects of AABW circulation on the sea floor—in the form of well-developed small- or large-scale current ripples and erosional/depositional features, manganese-nodule formations, and unconformities and reworking of sediments observed in cores — are also marked in these basins. Even though the AABW in the Wharton Basin is cold, its spreading effects on the sea floor are minimal in this basin in contrast to the basins west of the Mid-Indian Ridge at comparable latitudes.     

Diapycnal heat flux and mixed layer heat budget within the Atlantic Cold Tongue

Sea surface temperatures (SSTs) in the eastern tropical Atlantic are crucial for climate variability within the tropical belt. Despite this importance, state-of-the-art climate models show a large SST warm bias in this region. Knowledge about the seasonal mixed layer (ML) heat budget is a prerequisite for understanding SST mean state and its variability. Within this study all contributions to the seasonal ML heat budget are estimated at four locations within the Atlantic cold tongue (ACT) that are representative for the western (0°N, 23°W), central (0°N, 10°W) and eastern (0°N, 0°E) equatorial as well as the southern (10°S, 10°W) ACT. To estimate the contribution of the diapycnal heat flux due to turbulence an extensive data set of microstructure observations collected during ten research cruises between 2005 and 2012 is analyzed. The results for the equatorial ACT indicate that with the inclusion of the diapycnal heat flux the seasonal ML heat budget is balanced. Within the equatorial region, the diapycnal heat flux is essential for the development of the ACT. It dominates over all other cooling terms in the central and eastern equatorial ACT, while it is of similar size as the zonal advection in the western equatorial ACT. In contrast, the SST evolution in the southern ACT region can be explained entirely by air-sea heat fluxes.     

Towards a climate event stratigraphy for New Zealand over the past 30 000 years (NZ‐INTIMATE project)

It is widely recognised that the acquisition of high‐resolution palaeoclimate records from southern mid‐latitude sites is essential for establishing a coherent picture of inter‐hemispheric climate change and for better understanding of the role of Antarctic climate dynamics in the global climate system. New Zealand is considered to be a sensitive monitor of climate change because it is one of a few sizeable landmasses in the Southern Hemisphere westerly circulation zone, a critical transition zone between subtropical and Antarctic influences. New Zealand has mountainous axial ranges that amplify the climate signals and, consequently, the environmental gradients are highly sensitive to subtle changes in atmospheric and oceanic conditions. Since 1995, INTIMATE has, through a series of international workshops, sought ways to improve procedures for establishing the precise ages of climate events, and to correlate them with high precision, for the last 30 000 calendar years. The NZ‐INTIMATE project commenced in late 2003, and has involved virtually the entire New Zealand palaeoclimate community. Its aim is to develop an event stratigraphy for the New Zealand region over the past 30 000 years, and to reconcile these events against the established climatostratigraphy of the last glacial cycle which has largely been developed from Northern Hemisphere records (e.g. Last Glacial Maximum (LGM), Termination I, Younger Dryas). An initial outcome of NZ‐INTIMATE has been the identification of a series of well‐dated, high‐resolution onshore and offshore proxy records from a variety of latitudes and elevations on a common calendar timescale from 30 000 cal. yr BP to the present day. High‐resolution records for the last glacial coldest period (LGCP) (including the LGM sensu stricto) and last glacial–interglacial transition (LGIT) from Auckland maars, Kaipo and Otamangakau wetlands on eastern and central North Island, marine core MD97‐2121 east of southern North Island, speleothems on northwest South Island, Okarito wetland on southwestern South Island, are presented. Discontinuous (fragmentary) records comprising compilations of glacial sequences, fluvial sequences, loess accumulation, and aeolian quartz accumulation in an andesitic terrain are described. Comparisons with ice‐core records from Antarctica (EPICA Dome C) and Greenland (GISP2) are discussed. A major advantage immediately evident from these records apart from the speleothem record, is that they are linked precisely by one or more tephra layers. Based on these New Zealand terrestrial and marine records, a reasonably coherent, regionally applicable, sequence of climatically linked stratigraphic events over the past 30 000 cal. yr is emerging. Three major climate events are recognised: (1) LGCP beginning at ca. 28 000 cal. yr BP, ending at Termination I, ca. 18 000 cal. yr BP, and including a warmer and more variable phase between ca. 27 000 and 21 000 cal. yr BP, (2) LGIT between ca. 18 000 and 11 600 cal. yr BP, including a Lateglacial warm period from ca. 14 800 to 13 500 cal. yr BP and a Lateglacial climate reversal between ca. 13 500 and 11 600 cal. yr BP, and (3) Holocene interglacial conditions, with two phases of greatest warmth between ca. 11 600 and 10 800 cal. yr BP and from ca. 6 800 to 6 500 cal. yr BP. Some key boundaries coincide with volcanic tephras. Copyright © 2007 John Wiley & Sons, Ltd.     

Reconstruction of past methane availability in an Arctic Alaska wetland indicates climate influenced methane release during the past ~12,000?years

Atmospheric contributions of methane from Arctic wetlands during the Holocene are dynamic and linked to climate oscillations. However, long-term records linking climate variability to methane availability in Arctic wetlands are lacking. We present a multi-proxy ~12,000?year paleoecological reconstruction of intermittent methane availability from a radiocarbon-dated sediment core (LQ-West) taken from a shallow tundra lake (Qalluuraq Lake) in Arctic Alaska. Specifically, stable carbon isotopic values of photosynthetic biomarkers and methane are utilized to estimate the proportional contribution of methane-derived carbon to lake-sediment-preserved benthic (chironomids) and pelagic (cladocerans) components over the last ~12,000?years. These results were compared to temperature, hydrologic, and habitat reconstructions from the same site using chironomid assemblage data, oxygen isotopes of chironomid head capsules, and radiocarbon ages of plant macrofossils. Cladoceran ephippia from ~4,000?cal?year BP sediments have ??¹³C values that range from ~?39 to ?31??, suggesting peak methane carbon assimilation at that time. These low ??¹³C values coincide with an apparent decrease in effective moisture and development of a wetland that included Sphagnum subsecundum. Incorporation of methane-derived carbon by chironomids and cladocerans decreased from ~2,500 to 1,500?cal?year BP, coinciding with a temperature decrease. Live-collected chironomids with a radiocarbon age of 1,640?cal?year BP, and fossil chironomids from 1,500?cal?year BP in the core illustrate that ??old?? carbon has also contributed to the development of the aquatic ecosystem since ~1,500?cal?year BP. The relatively low ??¹³C values of aquatic invertebrates (as low as ?40.5??) provide evidence of methane incorporation by lake invertebrates, and suggest intermittent climate-linked methane release from the lake throughout the Holocene.     

Eemian tropical and subtropical African moisture transport: an isotope modelling study

During the last interglacial insolation maximum (Eemian, MIS 5e) the tropical and subtropical African hydrological cycle was enhanced during boreal summer months. The climate anomalies are examined with a General Circulation Model (ECHAM4) that is equipped with a module for the direct simulation of ¹⁸O and deuterium (H ₂ ¹⁸ O and HDO, respectively) in all components of the hydrological cycle. A mechanism is proposed to explain the physical processes that lead to the modelled anomalies. Differential surface heating due to anomalies in orbital insolation forcing induce a zonal flow which results in enhanced moisture advection and precipitation. Increased cloud cover reduces incoming short wave radiation and induces a cooling between 10°N and 20°N. The isotopic composition of rainfall at these latitudes is therefore significantly altered. Increased amount of precipitation and stronger advection of moisture from the Atlantic result in isotopically more depleted rainfall in the Eemian East African subtropics compared to pre-industrial climate. The East–West gradient of the isotopic rainfall composition reverses in the Eemian simulation towards depleted values in the east, compared to more depleted western African rainfall in the pre-industrial simulation. The modelled re-distribution of δ¹⁸O and δD is the result of a change in the forcing of the zonal flow anomaly. We conclude that the orbitally induced forcing for African monsoon maxima extends further eastward over the continent and leaves a distinct isotopic signal that can be tested against proxy archives, such as lake sediment cores from the Ethiopian region.     

Jupiter’s shrinking Great Red Spot and steady Oval BA: Velocity measurements with the ‘Advection Corrected Correlation Image Velocimetry’ automated cloud-tracking method

We show that between 1996 and 2006, the area circumscribed by the high-speed collar of the Great Red Spot (GRS) shrunk by 15%, while the peak velocities within its collar remained constant. This shrinkage indicates a dynamical change in the GRS because the region circumscribed by the collar is nearly coincident with the location of the potential vorticity anomaly of the GRS. It was previously observed that the area of the clouds associated with the GRS has been shrinking. However, the cloud cover of the GRS is not coincident with the location of its potential vorticity anomaly or any other of its known dynamical features. We show that the peak velocities of the Oval BA were nearly the same in 2000, when the Oval was white, and in 2006, when it was red, as were all of the other features of the two velocities fields. To measure temporal changes in the GRS and Oval, we extracted velocities from images taken with Galileo, Cassini, and the Hubble Space Telescope using a new iterative method called Advection Corrected Correlation Image Velocimetry (ACCIV). ACCIV finds correlations over image pairs with 10-h time separations when other automated velocity-extraction methods are limited to time separations of 2 h or less. Typically, ACCIV velocities produced from images separated by 10 h had errors that are 3-6 times smaller than similar velocities extracted from images separated by 2 h or less. ACCIV produces velocity fields containing hundreds of thousands of independent correlation vectors (tie-points). Dense velocity fields are needed to locate the loci of peak velocities and other features.     

The Commonwealth, ‘development’ and post-colonial responsibility

One important (though often neglected) part of the ‘development business’ committed to principles of partnership is the Commonwealth, a voluntary association of 54 independent countries, almost all of which were formerly under British rule. This paper focuses on the Commonwealth’s contemporary sense of ‘responsibility’ for shaping African development through ‘partnership’ and by promoting ‘good governance’ and examines the particular example of Mozambique, which joined the Commonwealth in 1995. In exploring exactly what membership of this post-colonial ‘family’ has meant for Mozambique the paper explores the neocolonial paternalism and sense of trusteeship that the Commonwealth has articulated in its often very apolitical vision of African development which seems to lock the continent into a permanent stage of tutelage and to repetitively reduce Africa to a set of core deficiencies for which externally generated ‘solutions’ must be devised. More generally, the paper also examines the wider context of the Commonwealth’s involvement in Africa by looking at the connections it has made to British industry, British charities and the British Department for International Development (DFID). The paper concludes with an assessment of the ‘showcase’ potential of Mozambique and its importance to Commonwealth and DFID narrations of an African ‘success’ story of peace, stability and growth since the end of the country’s devastating civil war in 1992.