Hydrogen-isotopic variability in fatty acids from Yellowstone National Park hot spring microbial communities

We report the abundances and hydrogen-isotopic compositions (D/H ratios) of fatty acids extracted from hot-spring microbial mats in Yellowstone National Park. The terrestrial hydrothermal environment provides a useful system for studying D/H fractionations because the numerous microbial communities in and around the springs are visually distinct, separable, and less complex than those in many other aquatic environments. D/H fractionations between lipids and water ranged from −374‰ to +41‰ and showed systematic variations between different types of microbial communities. Lipids produced by chemoautotrophic hyperthermophilic bacteria, such as icosenoic acid (20:1), generally exhibited the largest and most variable fractionations from water (−374‰ to −165‰). This was in contrast to lipids characteristic of heterotrophs, such as branched, odd chain-length fatty acids, which had the smallest fractionations (−163‰ to +41‰). Mats dominated by photoautotrophs exhibited intermediate fractionations similar in magnitude to those expressed by higher plants. These data support the hypothesis that variations in lipid D/H are strongly influenced by central metabolic pathways. Shifts in the isotopic compositions of individual fatty acids across known ecological boundaries show that the isotopic signature of specific metabolisms can be recognized in modern environmental samples, and potentially recorded in ancient ones. Considering all sampled springs, the total range in D/H ratios is similar to that observed in marine sediments, suggesting that the trends observed here are not exclusive to the hydrothermal environment.     

On the choice of calibration periods and objective functions: A practical guide to model parameter identification

Despite the development of new measuring techniques, monitoring systems and advances in computer technology, rainfall-flow modelling is still a challenge. The reasons are multiple and fairly well known. They include the distributed, heterogeneous nature of the environmental variables affecting flow from the catchment. These are precipitation, evapotranspiration and in some seasons and catchments in Poland, snow melt also. This paper presents a review of work done on the calibration and validation of rainfall-runoff modelling, with a focus on the conceptual HBV model. We give a synthesis of the problems and propose a practical guide to the calibration and validation of rainfall-runoff models.     

Paleomagnetism and magnetic mineralogy of metabasites and granulites from Orlica-Śnieżnik Dome (Central Sudetes)

The results of palaeomagnetic, rock magnetic, and microscopic study of Early Paleozoic metabasites and granulites from the Orlica?nie?nik Dome (OSD, Sudetes) have been combined with geochronological data. In the eastern part of the OSD (?nie?nik Massif, SM) ferrimagnetic pyrrhotite is prevalent, accompanied by various amounts of Fe-oxides. In the western part of the OSD (Orlica-Bystrzyca Massif, OBM) Fe-oxides dominate. All magnetic minerals originated during hydrothermal and weathering processes. The palaeomagnetic study revealed the presence of three secondary components of natural remanence: Late Carboniferous, Late Permian, and Mesozoic. Two Paleozoic components are related to volcanic activity in the Sudetes. They are carried by pyrrhotite and Fe-oxides and were isolated only in SM rocks. The Mesozoic component was determined in both parts of the OSD and is carried by Fe-oxides. It covers a time span, from ～160 to ～40 Ma, corresponding to a long period of alteration.     

Fluctuations of the Fennoscandian Ice Sheet recorded in the anisotropy of magnetic susceptibility of periglacial loess from Ukraine

The azimuth of imbrication of minimum magnetic susceptibility axes in the youngest loess from Ukraine defines prevailing wind directions during aeolian sedimentation. It changes along the studied sections. These changes can be directly correlated with the fluctuations of the Fennoscandian Ice Sheet. The northern and northeastern winds noted in the loess succession separated by a period when southwestern to southeastern winds were predominant may be correlated with two main phases of ice‐sheet advance during the Last Glacial Maximum. The ice‐sheet advances towards the areas of loess deposition generated katabatic winds that influenced aeolian sedimentation in the periglacial zone. A period of relatively stable wind directions during a younger phase of the Last Glacial Maximum was interrupted by periods with more chaotic wind regime most probably caused by fluctuations of the Fennoscandian Ice Sheet during its retreat from the peri‐Baltic part of Europe. These intervals occur where initial soils developed. The distribution of anisotropy of magnetic susceptibility axes defined along the periglacial loess sections from central and eastern Europe can serve to constrain fluctuations of the Fennoscandian Ice Sheet.     

Water vapour mixing ratio profiles over Hornsund, Arctic. Intercomparison of lidar and AIRS results

Since October 2009, a ground-based Raman lidar system has been deployed to perform a regular, night-time, vertical sounding of a water vapour content in the lower and middle troposphere above Polish Polar Station at Hornsund (77.00°N, 15.55°E, 10 m a.s.l.) in the Arctic. The water vapour mixing ratio profiles were obtained for the atmosphere up to 6 km altitude, based on analysis of inelastic Raman backscattering signals from nitrogen molecules (at 387 nm) and water vapour particles (at 407 nm), calibrated with the data from a local Vaisala’s automatic meteorological station. The results obtained for winter seasons in the years 2009–2012 are in a good general agreement with the results obtained from the atmospheric infrared sounder (AIRS) on the Aqua satellite.     

Monazite RW-1: a homogenous natural reference material for SIMS U–Pb and Th–Pb isotopic analysis

Mineralogy and Petrology - Well-characterized matrix-matched natural mineral references of known age are an important prerequisite for SIMS (secondary ion mass spectrometry) U–Th–Pb...     

An ensemble estimation of the variability of upper-ocean heat content over the tropical Atlantic Ocean with multi-ocean reanalysis products

Current ocean reanalysis systems contain considerable uncertainty in estimating the subsurface oceanic state, especially in the tropical Atlantic Ocean. Given this level of uncertainty, it is important to develop useful strategies to identify realistic low-frequency signals optimally from these analyses. In this paper, we present an “ensemble” method to estimate the variability of upper-ocean heat content (HC) in the tropical Atlantic based on multiple-ocean reanalysis products. Six state-of-the-art global ocean reanalaysis products, all of which are widely used in the climate research community, are examined in terms of their HC variability from 1979 to 2007. The conventional empirical orthogonal function (EOF) analysis of the HC anomalies from each individual analysis indicates that their leading modes show significant qualitative differences among analyses, especially for the first modes, although some common characteristics are discernable. Then, the simple arithmetic average (or ensemble mean) is applied to produce an ensemble dataset, i.e., the EM analysis. The leading EOF modes of the EM analysis show quantitatively consistent spatial–temporal patterns with those derived from an alternative EOF technique that maximizes signal-to-noise ratio of the six analyses, which suggests that the ensemble mean generates HC fields with the noise reduced to an acceptable level. The quality of the EM analysis is further validated against AVISO altimetry sea level anomaly (SLA) data and PIRATA mooring station data. A regression analysis with the AVISO SLA data proved that the leading modes in the EM analysis are realistic. It also demonstrated that some reanalysis products might contain higher level of intrinsic noise than others. A quantitative correlation analysis indicates that the HC fields are more realistic in the EM analysis than in individual products, especially over the equatorial regions, with signals contributed from all ensemble members. A direct comparison with the HC anomalies derived from in situ temperature measurements showed that the EM analysis generally gets realistic HC variability at the five chosen PIRATA mooring stations. Overall, these results demonstrate that the EM analysis is a promising alternative for studying physical processes and possibly for initializing climate predictions.     

Anthropogenic changes in the sediment composition of Lake Gości& aogon;ż (central Poland), during the last 330 yrs*

According to historical sources, the development of settlement around Lake Goci& aogon; during the last 330 yrs was intense at two time periods: the second half of the 1700's, and from ca. 1880 until 1944. The small farms were then abandoned, following which the lake surroundings were planted with forest trees. The presented study of human influence on the lake ecosystem and surrounding vegetation has been based on analyses of general sediment composition and its chemistry, pollen, Cyanobacteria, Chlorophyceae, Rotatoria, Cladocera, and a preliminary diatom survey. The history of human impact has been divided into four phases: 1. Phase of small local hamlets (before ca. 1770): The human impact was rather moderate then, but the cultivation of Canabis sativa, Secale cereale and later of Fagopyrum is evidenced from that time. 2. Phase of Hollandii settlement (ca. 1770-1863). Its influence is indicated first by the recession of deciduous wood (Corylus, Carpinus) stands, which triggered drastic drop of calcium in sediments. The development of rural economy in the area, including, an extension of agriculture (Secale and other cereals, crucifers, potatoes), and animal breeding based partly on grazing in the forest, is evidenced only after 1820. 3. Phase of German colonization (1863-1944): In the early periods (before 1910) the pollen spectra do not document any essential change in the type of farming, however, a serious disturbance of the lake ecosystem and sediment chemistry is evidenced by the blooms of Araphidinae diatoms and Tetraedron minimum, a maximum frequency of Bosmina longirostris, disturbances of the regular spring blooms of Chrysophyceae, appearance of vivianite, distinct maxima of organic matter, potassium, and iron concentration in sediments and an increase of the sedimentation rate. An intensification of agricultural activities commenced around 1910; woods, including also pinewoods, were then heavily devastated, and farming extended on poor soils, what was symptomatic for the general poverty of population. Coincidently in the lake, Centriceae showed blooms, Araphidinae diatoms and Tetraedron minimum developed, and the content of potassium, iron and phosphorus increased substantially, indicating altogether rising eutrophication. 4. Phase of restoration of the natural landscape (after 1945): The farm degradation from ca. 1944 is very weakly expressed in pollen data, which show a substantial fall of farming indicators from 1953/6 only, when the whole area was used for forest plantation. It was accompanied by a certainly spontaneous development of Betula and Alnus woods, this process progressing till recent time. The gradual extinction of farming activity near Lake Goci was accompanied by abrupt changes in the lake ecosystem, expressed by the restored blooms of Chrysophyceae expansion of planktonic Cladocera, rapid decline of phosphorus and extinction of vivianite from sediments. As documented by the drop of Cu/Zn ratio, lake hypolimnion has been weakly oxidized since 1949, what was probably responsible for the drop of Fe and Mn content in sediments. Increasing strength of overturns affected preservation of laminae in sediments, which almost completely disappeared after 1966.