Investigation of natural and anthropogenic hydrocarbon inputs in sediments using geochemical markers. II. Sao Sebastião, SP--Brazil

The S?o Sebasti?o Channel, NE S?o Paulo State, Brazil, is an area of environmental interest of that state not only because of the tourism, but also because of the presence of the most important oil terminal of Brazil, the PETROBRAS Maritime Terminal (DTCS). Sediment samples were collected at 15 sites in the channel, extracted and analyzed by GC/FID and GC/MS for composition and levels of the following organic geochemical markers: aliphatic hydrocarbons (normal and isoprenoid alkanes), petroleum biomarkers, linear alkylbenzenes (LABs) and polycyclic aromatic hydrocarbons (PAHs). The total concentrations varied from 0.04 to 8.53 micorg g(-1) for aliphatics, from 51.1 to 422.0 ng g(-1) for petroleum biomarkers, from 12.6 to 27.7 ng g(-1) for LABs and from 20.4 to 200.3 ng g(-1) for PAHs. The PETROBRAS Maritime Terminal (DTCS), Sao Sebasti?o Harbor and sewage outfalls along the area had clear influences on the geochemical marker concentrations, especially at locales in the central and north parts of the channel.     

Removal of ammonia toxicity in marine sediment TIEs: a comparison of Ulva lactuca,zeolite and aeration methods

Toxicity Identification Evaluations (TIEs) can be used to determine the specific toxicant(s), including ammonia, causing toxicity observed in marine sediments. Two primary TIE manipulations are available for characterizing and identifying ammonia in marine sediments: Ulva lactuca addition and zeolite addition. In this study, we compared the efficacy of these methods to (1) remove NH(x) and NH(3) from overlying and interstitial waters and (2) reduce toxicity to the amphipod Ampelisca abdita and mysid Americamysis bahia using both spiked and environmentally contaminated sediments. The utility of aeration for removing NH(x) and NH(3) during a marine sediment TIE was also evaluated preliminarily. In general, the U. lactuca and zeolite addition methods performed similarly well at removing spiked NH(x) and NH(3) from overlying and interstitial waters compared to an unmanipulated sediment. Toxicity to the amphipod was reduced approximately the same by both methods. However, toxicity to the mysid was most effectively reduced by the U. lactuca addition indicating this method functions best with epibenthic species exposed to ammonia in the water column. Aeration removed NH(x) and NH(3) from seawater when the pH was adjusted to 10; however, very little ammonia was removed at ambient pHs ( approximately 8.0). This comparison demonstrates both U. lactuca and zeolite addition methods are effective TIE tools for reducing the concentrations and toxicity of ammonia in whole sediment toxicity tests.     

影响张道口-1井数字化水位观测内在质量的因素

采用“水位调和分析(M2波计算)”程序,对天津张道口地震台张道口-1井模拟、数字化水位内在质量变化进行了对比研究。从高频干扰、周围井孔的地下水开采、仪器零漂、探头位置与观测精度变化的关系、仪器自身原因5个方面分析了影响张道口-1井数字化水位内在质量的因素,并提出了数字化水位在日常观测中的注意事项。     

Influence of algal farming on fish assemblages

We examined the influence of algal farming on fish assemblages in two shallow coastal lagoons in Zanzibar, Tanzania. Fish assemblages were visually investigated using a belt transect method and the line-intercept technique was used to examine the substrate composition. 101 species of fish belonging to 31 families were recorded. Algal farming affected the associated fish fauna in terms of abundance, species richness, trophic identity and fish community composition. However, the impact differed between the lagoons. Algal farms in one lagoon hosted a more abundant and diversified fish fauna than controls, whereas farms in the other lagoon exhibited lower fish densities and similar species diversity compared to controls. The discrepancies between lagoons may be an effect of differences in farming intensity and character of the substratum.     

我国地震地下流体前兆台站现状的调查与分析

系统介绍了我国地震地下流体前兆台站的产权与管理权关系,观测点的井泉类型、观测井深度,观测层类型与地下水物理化学特征,观测项目及仪器类型与运行现状,井房及其供电与通讯条件,观测人员的学历与专业结构、年龄与工龄结构等,为“十五”台站优化与建设方案的制定提供依据。     

Calculation of ground water ages--a comparative analysis

Ground water age is a fundamental, yet complex, concept in ground water hydrology. Discrepancies between results obtained through different modeling approaches for ground water age calculation have been reported, in particular, between ground water ages modeled by advection and direct simulation of ground water ages (e.g., age-mass approach), which includes effects of advection and dispersion. Here, through a series of two-dimensional (2D) simulations, the impact of water mixing through advection and dispersion on modeled 14C and directly simulated ground water ages is assessed. Impact of dispersion on modeled ages is systematically stronger in areas where water velocities are smaller and far more pronounced on 14C ages. This effect is also observed in one-dimensional models. 2D simulations show that longitudinal dispersion generally acts as a "source" of 14C, while vertical dispersion acts as a "sink," leading to apparent younger or older modeled 14C ages as compared to advective and directly simulated ground water ages. The presence of permeable and impermeable faults provides an equally important source for discrepancies, leading to major differences in modeled ages among the three methods considered. Overall, our results show that a 14C modeling approach using a solute transport model for calculating ground water age appears to be more reliable in ground water systems without faults and where water velocities are relatively high than in systems that are relatively more heterogeneous and those where faults are present. Among the three modeling approaches considered here, direct simulation of ground water age seems to yield the most consistent results in complex, heterogeneous ground water flow systems, giving a vertical age structure consistent with ages expected from consideration of the flow system.     

应用Arc/Info建立湖北省区域稳定性评价空间数据库

GIS是获取、检索、分析、处理空间数据的数据库管理系统，是研究空间对象的有力工具，本文利用GIS软件Arc/Info为基本工具，以遥感数据作为获取，更新数据库数据的重要信息源，结合前人的地学资料，建立了湖北省区域稳定性评价空间数据库，阐述了该空间数据库的内容，功能，应用和意义。     

电场产生的赤道扩展F的时空演变

利用计算机模拟研究了非均匀电场产生的赤道扩展Ｆ的时空演变。非均匀电场能在赤道电离层Ｆ区底部触发Ｒａｙｌｅｉｇｈ－Ｔａｙｌｏｒ不稳定性，导致等离子体泡形态。计算中非均匀电场的幅度取为０．２５－１．００ｍＶ／ｍ，所产生的等离子体泡在２０００ｓ以内就能穿过Ｆ峰达到５４０ｋｍ的高度。所得结果阐明了非均匀电场在赤道扩展Ｆ中的作用，指出了产生等离子体泡一种可能的扰动源。由于Ｅ区和Ｆ区电场是相互影响的，从而揭示了Ｅ区和Ｆ区扰动的相互联系。     

水动力弥散与水化学前兆信息传递特征初步研究

在分析大量监测资料的基础上，将水化前兆异常变化归结为３种基本曲线类型，将这些基本曲线与水动力弥散曲线进行对比分析，进而提出了水化前兆信息传递机制实质是一种水动力弥散的新观点，并就水动力弥散理论在水化前兆信息机制研究中的应用进行了讨     

Experimental simulation of Titan's organic chemistry at low temperature

A wide range of experiments has already been carried out to simulate the chemical evolution of Titan. Such experiments can provide useful information on the possible nature of minor constituents, mostly organic, likely to be present in Titan's atmosphere. Indeed, all but one of the organic compounds already detected in Titan's atmosphere have been identified in simulation experiments. The exception, C4N2, as well as other compounds expected in Titan from theoretical modeling, such as other N-organics, mainly CH2N2, and polyynes, namely C6H2, have never been detected in experimental simulation. It turned out that these compounds were thermally unstable, and the temperature conditions used during the simulation experiments (including conditions used for chemical analysis) were not appropriate. We have recently started a new program of simulation experiments using temperature conditions close to those of Titan's environment, more compatible with the build-up and detection of organics only stable at low temperature. Spark discharge of N2-CH4 gas mixtures was carried out at low temperature in the range of 100-150 K. The analysis of the obtained products was performed through FTIR, GC and GC-MS techniques. GC-peak identification was done owing to its mass spectrum and, in most cases, by comparison of the retention time and of the mass spectrum with standards. We report here the first detection in Titan's simulation experiments of C6H2. Its abundance is a few 10(-2) relative to C4H2. We also report a tentative identification of HC5N (to be confirmed by use of standard) with an abundance of a few 10(-2) relative to HC3N. The possible presence of HC5N suggested by our work provides the occurrence of very novel pathways in the formation of Titan's organic aerosols, involving not only C and H but also N atoms.