Evolution of polycyclic alkanes in the Espirito Santo Basin

The distributions of polycyclic alkanes were monitored in a Neocomian sequence (well 1-ESS-34) from the Espirito Santo Basin, southeast Brazil. The profiles included, apart from regular hopanes, significant concentrations of 18α(H), 28,30-bisnorhopane and subordinate amounts of gammacerane. Sterane concentrations, normally with hopane/sterane <5, were compatible with other geochemical data indicating a predominantly planktonic/microbial source of the deposited organic matter. Sample maturities ranged from very immature to the onset of oil generation, allowing biomarker distributions to be followed along a broad maturation range. The ability of certain molecular ratios (e.g. C₂₇ 17α(H)/17β(H)hopanes) to reflect a maturity sequence with depth in the closely-spaced strata of the immature upper levels (Jiquiá Stage) showed the value of molecular techniques over classical geochemical methods (e.g. vitrinite reflectance) for the study of immature sequences. The presence in the oils of southern Espirito Santo of 28,30-bisnorhopane, gammacerane and methyl steranes in similar concentrations as in extracts of the deepest levels of the 1-ESS-34 well qualify the Jiquia Stage as the probable source rock of oils accumulated in the basin.     

Morphology of the Itapeva to Tramandai transgressive dunefield barrier system and mid‐ to late Holocene sea level change

The surface morphology of the transgressive dunefield barrier extending from Itapeva to Tramandai along the northern littoral of Rio Grande do Sul, is examined and an attempt is presented to link morphological changes across the barrier to Holocene sea level changes. The 4·5 km wide Holocene barrier displays two typical morphologies: an inner part dominated by large‐scale, continuous alongshore, overlapping dunefield phases comprising sand sheets, dunes, deflation plains and precipitation ridges; and an outer part dominated by discontinuous, medium‐ to small‐scale, triangular to lobate transgressive dunefield phases, cut by both active and relict (palaeo‐) creeks or washouts. Holocene sea level in the region rose to c. +1 to +3 m above present reaching a maximum around 5100 years bp and then progressively fell to the present level. We argue that the effect on barrier development was to suppress the development of a drainage system during the rising and maximum stages, and encourage the development of an organized drainage system in the form of regularly spaced washouts during the falling period, and that this change in sea level from rising to falling therefore produced the large‐scale differences in barrier morphology. Copyright © 2006 John Wiley & Sons, Ltd.     

The Present, Past, and Future Contributions to Global Warming of CO2 Emissions from Fuels

The objective of this paper is to emphasize theresponsibility of developed countries to implement the Climate Convention, as well as the role ofdeveloping countries in CO₂ emissions controlwhile sustaining their rights to increase energyconsumption per capita during the development process. Itis shown that the growth in CO₂$ emissions fromfossil fuel consumption in North America, excludingMexico, from 1990 to 1996 was 3.7 times higherthan that of Latin America in absolute terms. Thecumulative contribution to global warming, expressedas the mass of the gas multiplied by time (GtCy), can becalculated as the integration of the atmosphericconcentration of the emitted gas along time, witha weight function in the integrand to simulate theclimate response. To simulate climate response,we used the superposition of exponential decay functions with different decay constants. Thehistorical contributions of the OECD countries,the Eastern European countries and theex-Soviet Union, and from all developingcountries are considered. The future contributionsare computed in three scenarios. All of them showthat emissions from Non-Annex I countrieswill become higher than those of Annex I countriessoon after 2010, while the curves of atmosphericconcentration will cross one another later, not muchbefore 2050, and the respective contributions toglobal temperature increase will cross about 2090.     

Occurrence and Resistance of Pathogenic Bacteria Along the Tietê River Downstream of São Paulo in Brazil

The load of pathogenic bacteria, their fate and their dangerousness in the Tietê River were assessed along 100 km starting from the city of São Paulo, Brazil. The data were compared with those from two German rivers. High loads of pathogens were found in the Tietê River near the city of São Paulo (Escherichia coli O157:H7, Shigella flexneri, and Shigella boydii), which were absent 30 km downstream of São Paulo. The antibiotic resistances observed in the Tietê river were rather low and decreased after the major input in São Paulo to significantly lower levels about 30 km downstream. While the Brazilian isolates were more susceptible for ampicillin than the German ones, the reverse was observed for gentamycin. For optimal control of infections in humans critical areas where these bacteria survived longer and their elimination mechanisms should be identified as well as the extent and the origin of antibiotic resistance should be determined.     

Comparison of the SFI peculiar velocities with the IRAS 1.2-Jy gravity field

We present a comparison between the peculiar velocity fields measured from a recently completed l -band Tully–Fisher survey of field spirals (SFI) and that derived from the IRAS 1.2-Jy redshift survey galaxy distribution. The analysis is based on the expansion of these data in redshift space using smooth orthonormal functions, and is performed using low- and high-resolution expansions, with an effective smoothing scale which increases almost linearly with redshift. The effective smoothing scales at 3000 km s⁻¹ are 1500 and 1000 km s⁻¹ for the low- and high-resolution filters. The agreement between the high- and low-resolution SFI velocity maps is excellent. The general features in the filtered SFI and IRAS velocity fields agree remarkably well within 6000 km s⁻¹. This good agreement between the fields allows us to determine the parameter β = Ω^0.6 / b , where Ω is the cosmological density parameter, and b is the linear biasing factor. From a likelihood analysis on the SFI and IRAS modes we find that β = 0.6 ± 0.1, independently of the resolution of the modal expansion. For this value of β, the residual fields for the two filters show no systematic variations within 6000 km s⁻¹. Most remarkable is the lack of any coherent, redshift-dependent dipole flow in the residual field.     

Provenance of deep-water reservoir sandstones from the Jubarte oil field,Campos Basin,Eastern Brazilian Margin

The provenance of the Maastrichtian deep-water reservoir sandstones from the Jubarte oil field (Campos Basin, eastern Brazil), was studied using an integrated approach that included quantitative petrography, conventional heavy mineral analysis, garnet mineral chemistry and zircon geochronology. The reservoirs are predominantly coarse, poorly-sorted sandstones with feldspathic composition derived from uplifted basement terrains. The fourth- and fifth-order depositional sequences analyzed show no major variations in composition or in provenance through time. However, variations in apatite:tourmaline presents potential to be used as a parameter for sandstone correlation within the field. The composition of heavy minerals indicates derivation from high temperature and low-to-medium pressure aluminous metapelitic rocks, from granites and subordinate mafic rocks, derived from the Cabo Frio Tectonic Domain and the Oriental terrain of Ribeira orogen, characterizing a supply route from SW to NE. The low ZTR index, as well as the absence of low-grade stable heavy minerals and of metasedimentary rock fragments, suggest that by the end of Cretaceous all supracrustal, low-grade terrains had already been totally eroded, and that plutonic, infracrustal rocks were exposed, similarly to the present situation.     

Land use dynamics in Brazilian La Plata Basin and anthropogenic climate change

The La Plata Basin (LPB) is one of the most important regions for agriculture and livestock production in South America, playing a central role in the world food production and food security. Within its borders is also located the whole Brazilian Pantanal region. Identifying the most important land use sectors in LPB as well as the changes observed in the past years is fundamental to recognize which areas of the basin might be more vulnerable to climate change in order to design adaptation strategies. A general characterization of land use and livestock production of Brazilian LPB was done by using the System of Automatic Retrieving (SIDRA) of Brazilian Institute of Geography and Statistics (IBGE) platform as the major source of data. It was observed expressive increases in land areas used for temporary crops, such as soybean, sugarcane, and maize, as well as increases in poultry and swine production. These important changes in agricultural land use and livestock production are currently associated to non-climatic drivers, but this dynamic might be strongly affected by the consequences of climate change and variability, with negative socio-economic impacts for the whole region.